Research Advances in Functionalized Rubber Constructed <italic style="font-style: italic">via in situ</italic> Polymerization

PENG Shuo-li; TANG Jian; LIU Yu-dong; LIU Kai; HUA Jing

doi:10.14028/j.cnki.1003-3726.2026.26.084

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Research Advances in Functionalized Rubber Constructed via in situ Polymerization

更新时间：2026-07-27

- Research Advances in Functionalized Rubber Constructed via in situ Polymerization
- Polymer Bulletin Vol. 39, Issue 8, Pages: 1269-1278(2026)
- 作者机构：
  
  青岛科技大学高分子科学与工程学院　青岛 266042
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2026.26.084
  CLC：
- Received：25 February 2026，
  
  Accepted：06 May 2026，
  
  Online First：26 June 2026，
  
  Published：20 August 2026
- 稿件说明：
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彭铄荔, 汤健, 刘玉冬, 刘凯, 华静. 原位聚合构筑功能化橡胶研究进展. 高分子通报, 2026, 39(8), 1269–1278.

Peng, S. L.; Tang, J.; Liu, Y. D.; Liu, K.; Hua, J. Research advances in functionalized rubber constructed via in situ polymerization. Polym. Bull. (in Chinese), 2026, 39(8), 1269–1278.
彭铄荔, 汤健, 刘玉冬, 刘凯, 华静. 原位聚合构筑功能化橡胶研究进展. 高分子通报, 2026, 39(8), 1269–1278. DOI： 10.14028/j.cnki.1003-3726.2026.26.084.

Peng, S. L.; Tang, J.; Liu, Y. D.; Liu, K.; Hua, J. Research advances in functionalized rubber constructed via in situ polymerization. Polym. Bull. (in Chinese), 2026, 39(8), 1269–1278. DOI： 10.14028/j.cnki.1003-3726.2026.26.084.

摘要

随着应用领域的不断拓展，橡胶材料的性能要求已由传统的力学与耐久性能，逐步发展为对结构与功能并重的综合性能需求。利用原位聚合技术，在橡胶基体中引入功能填料，以同时实现高力学性能与导电、导热、智能响应等多功能集成，已成为橡胶材料性能升级的重要技术路径。本综述系统总结了原位聚合技术在橡胶功能化领域的三大核心策略：原位构筑聚合物纳米增强相、填料与橡胶的原位共聚合和原位聚合的表界面修饰。首先，概述了原位聚合的起源及其相较于传统物理共混在填料分散与界面结合方面的优势。然后，逐一阐述各策略的作用机理、技术特点和典型实例。目前这些技术在反应控制及减少副反应干扰方面仍面临挑战，未来可能的发展方向包括开发绿色聚合工艺、实现精准结构调控、拓展生物医疗等高端领域，实现多功能集成，以实现橡胶材料向高性能、多功能化与智能化持续发展。

Abstract

As application fields continue to expand

the performance requirements for rubber materials have gradually evolved from traditional mechanical and durability properties to comprehensive demands that equally emphasize structure and function of the rubber materials. Utilizing

in situ

polymerization technology to introduce functional fillers into the rubber matrix

thereby achieving both high mechanical performance and multifunctional integration

such as electrical conductivity

thermal conductivity

and intelligent responsiveness

has become a key technological pathway for upgrading rubber materials. This review systematically summarizes three core strategies of

in situ

polymerization in the field of rubber functionalization:

in situ

construction of polymer nanoreinforcement phases

in situ

copolymerization of fillers and rubber and surface and interface modification

via

in situ

polymerization. First

the origin of

in situ

polymerization and its advantages over traditional physical blending in terms of filler dispersion and interfacial bonding are outlined. The mechanisms

technical characteristics

and representative examples of each strategy are then elaborated. The current challenges in these technologies include reaction control and minimization of side reaction interference. Future development directions may involve the development of green polymerization processes

achieving precise structural regulation

expanding into high-end fields such as biomedicine

and realizing multifunctional integration

thereby promoting the continuous evolution of rubber materials toward high performance

multifunctionality

and intelligence.

关键词

Keywords

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⁰

Research Advances in Functionalized Rubber Constructed via in situ Polymerization

DOI：10.14028/j.cnki.1003-3726.2026.26.084

摘要

Abstract

关键词

Keywords

references