Research Progress on Modification of Separators for Li–S Batteries

WANG Lu-kuan; CUI Yang-yang; JIANG Shao-yu; BI Qiao-ling; WU Chun-jie; SONG Peng-hao; HE Ai-hua; WANG Cun-guo

doi:10.14028/j.cnki.1003-3726.2026.26.120

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Research Progress on Modification of Separators for Li–S Batteries

更新时间：2026-07-27

- Research Progress on Modification of Separators for Li–S Batteries
- Polymer Bulletin Vol. 39, Issue 8, Pages: 1331-1344(2026)
- 作者机构：
  
  青岛科技大学高分子科学与工程学院高性能有机光学聚合物与先进制造技术全国重点实验室橡塑材料与工程教育部重点实验室山东省高性能烯烃材料与循环利用重点实验室　青岛 266042
  亿恩科天润新能源材料(山东)有限公司　枣庄 277800
  中国科学院苏州纳米技术与纳米仿生研究所　苏州 215123
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2026.26.120
  CLC：
- Received：03 March 2026，
  
  Accepted：15 April 2026，
  
  Online First：23 June 2026，
  
  Published：20 August 2026
- 稿件说明：
移动端阅览
王路宽, 崔洋洋, 姜绍宇, 毕巧玲, 吴春杰, 宋鹏豪, 贺爱华, 王存国. Li–S电池隔膜改性研究进展. 高分子通报, 2026, 39(8), 1331–1344.

Wang, L. K.; Cui, Y. Y.; Jiang, S. Y.; Bi Q. L.; Wu, C. J.; Song, P. H.; He, A. H.; Wang, C. G. Research progress on modification of separators for Li–S batteries. Polym. Bull. (in Chinese), 2026, 39(8), 1331–1344.
王路宽, 崔洋洋, 姜绍宇, 毕巧玲, 吴春杰, 宋鹏豪, 贺爱华, 王存国. Li–S电池隔膜改性研究进展. 高分子通报, 2026, 39(8), 1331–1344. DOI： 10.14028/j.cnki.1003-3726.2026.26.120.

Wang, L. K.; Cui, Y. Y.; Jiang, S. Y.; Bi Q. L.; Wu, C. J.; Song, P. H.; He, A. H.; Wang, C. G. Research progress on modification of separators for Li–S batteries. Polym. Bull. (in Chinese), 2026, 39(8), 1331–1344. DOI： 10.14028/j.cnki.1003-3726.2026.26.120.

摘要

由于硫元素具有在地壳中储量丰富、成本低廉、环境友好等特点，组装成锂–硫电池后具有较高的理论比容量和能量密度，因而成为下一代极具潜力的高能化学电源之一。然而，由于硫单质电导率较低，且在电池充放电过程中产生的多硫化锂具有“穿梭效应”，从而影响了锂–硫电池的循环寿命。大量研究证明，通过对隔膜进行改性研究，可以抑制锂–硫电池的“穿梭效应”。本综述介绍了锂–硫电池隔膜的设计原理及制备方法，详细阐述了石墨烯、碳纳米管等碳基材料，以及金属氧化物、硫化物、氮化物等无机化合物和聚合物材料对隔膜的改性研究，尤其是近年来新兴的金属有机框架材料(MOFs)、共轭有机低分子材料(COFs)等对隔膜的改性研究进展，并对上述不同改性策略的作用机理与效果进行了综述与展望。

Abstract

Owing to the advantages of sulfur

such as its abundant reserves in the earth’s crust

low cost

and environmental friendliness

lithium-sulfur batteries exhibit high theoretical specific capacity and energy density

making them one of the most promising high-energy chemical power sources for the next generation. However

the low electrical conductivity of elemental sulfur and the “shuttle effect” of lithium polysulfides generated during the charge-discharge processes impair the cycle life of lithium-sulfur batteries. Numerous studies have demonstrated that separator modification can effectively suppress the “shuttle effect” in lithium-sulfur batteries. This review introduces the design principles and preparation methods of lithium/sulfur battery separators. It elaborates on the research progress of separator modification using carbon materials (graphene

carbon nanotubes

etc

inorganic compounds (metal oxides

sulfides

nitrides

etc

and polymer materials. In particular

recent advances in separator modification using emerging materials

including metal-organic frameworks (MOFs) and covalent organic frameworks (COFs)

are summarized. The mechanisms and effects of different modification strategies are reviewed.

关键词

Keywords

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