摘要:In this review the relation between biocompatibility of biomaterials and conformation of proteins was expounded.The elaboration includes four propositions as follows:1.The natural conformation of protein is the basis of its biofunctions,2.The sysnergistic effect of peptide chain-lataral group is the driving source for both the foundation of natural conformation and the accomplishment of biofunction of proteins,3.Protein adsorption of biomaterials,4.Relation between biocompatibility of biomaterials and conformation of proteins. It is concluded that one of the best way improving biocompatibility of biomaterials is to maintain the natural conformation of proteins and cells contacted,in that both "Maintaining Normal Conformation" hypothesis and "Chemical Amplification" principle will play a positive role.
摘要:The application of polymers in the preparation of nanoparticles has been reviewed here.Polymers can be used as dispersion medium or stabilizer for nanoparticles in the sol-gel system. Several methods containing polymers of preparing supermicroparticles have been mentioned. The practicability of polar polymer used as dispersive medium is analyzed,and the universality of preparing nanoparticles by complex transformation is discussed.
关键词:Nanoparticles;Preparation;Application of polymers
摘要:This paper introduces analytical pyrolysis methods,including simultaneous pyrolysis derivatization and direct injection probe pyrolysis-mass spectrometry.The new research and development of analytical pyrolysis on polymers characterization,thermal decomposition mechanism and polymer processing are reviewed.
摘要:The studies on in-situ composite in recent years are reviewed in this paper.The fiber-forming mechanism is discussed concisely.It is presented in the paper that how the fibrillation influences the rheology property,mechanical properties,morphology,morphology distribution, crystallization and melting behavior.
摘要:The topic of this review concentrates on polymer bound Schiff base complexes during the last decade with 38references.The synthetic procedures so far adopted include:(a) Polymerization of ligand or metal complexed monomer moieties;(b) Anchoring of small molecules ligand or metal complexes on preformed polymers.Binding of dioxygen and catalytic activity are the promising properties.
关键词:Schiff base complex;Polymer bound complex;Synthesis;Catalytic oxidation;Adsorbed oxygen
摘要:Since the synthesis of soluble polysilane,the research of polysilanes has been a hot subject.The recent development of synthesis and application of polysilanes is summarized in this paper.
摘要:In this paper,the studies over the decades on polymers containing rare earth metal are reviewed on the basis of spetroscopy.The discussion focuses on how to improve fluorescence property of this kind of polymer.So the relationship between the fluorescent intensity and preparing method,structure of polymer is investigated in details.
摘要:The main research direction of optical plastics at present is summarized according to the relationship between structure and properties.The new kinds materials which have the properties of high refractive index,high heat-resisting or other function are introduced in detail. The significance of balance on properties to application is pointed out.
关键词:Optical plastics;Research direction;Balance on properties
摘要:This review article summarizes the polymer preparation and processing that have been carried out in supercritical carbon dioxide.As will be shown,a number of polymerization reactions, such as the homogeneous freeradical polymerization of flourinated monomers,the dispersion polymerization of methyl methacrylate,the precipitation polymerization of acrylic acid,the inverse emulsion polymerization of acrylamide and the cationic polymerization of isobutyl vinyl ether,can be conducted in supercritical carbon dioxide.Polymerization in supercritical carbon dioxide-swollen polymers can be used to prepare polymer blends with composition gradients. Moreover,supercritical carbon dioxide have been applied in the fractionation of polymers,the formation of porous polymers,and the preparation of polymer submicron fibers and particles.These reports strongly indicate that there is great potential for preparing a wide range of polymers in this enviromentally sound and enexpensive reaction medium.
关键词:Supercritical carbon dioxide;Free-radical polymerization;Cationic polymerization;Polymerization in swollen polymers;Gradient polymer blends;Fractionation;Polymeric submicron fibers and particles
摘要:Research progress and experimental methods on the phase behavior of polymer blends under shear flow,which has been one of the rapid devloping fields in polymer science since 1980′,are reviewed with 33references,especially the newest Rheo-Optical method,which combines a two-dimensional small-angle light scanner(SALS) and rheometer,and In Situ Optical Microscopy method,which combines a light micrograph and rheometer,to study the miscibility of polymer blends.
摘要:Study on polyether-Inorganic salt complex has been presented.The effect of salt concentration and structure on conductivity of polyether-salt complex is described.Methods to improve the conductivity of polyether-salt complex are also reviewed.
摘要:The synthesis of oligosaccharides are reviewed.The effect of polymer on the coupling and its mechanism are described.Methods used for protecting hydroxyl group,including solid- phase protection,and the sterospecific control in the coupling are also described.