摘要:Recent progress in the research of alicyclic polyimides was reviewed.The classification and synthesis of the alicyclic monomers were discussed.At the same time,the synthesis chemistry and characterization of the part-and whole-alicyclic polyimides were described.Especially,the particularity in the synthesis of the whole-alicyclic was presented.As an important material used widely in the alignment of the liquid crystals,alicyclic polyimides were paid more and more attention in recent years.Therefore,the emphasis was placed on the applications of the alicyclic polyimides as liquid crystal display (LCD) alignment films.
关键词:Polyimide;Alicyclic monomers;Liquid crystal display;Alignment film
摘要:The research and development of polymer-polymer complex in solution was reviewed.On one hand,the experimental methods to study polymer-polymer complex in solution were summarized;on the other hand,the complex systems were classified according to the different driving forces:Coulomb attraction,Van der Waals attraction,Hydrogen bond interaction,antigen-antibody interaction,ion interaction.And the influencing factors of each kind of complex system were discussed.
摘要:Polybenzazoles (PBZs) stand for a series of aromatic stiff chain liquid crystalline polymers, which have outstanding properties characterized as high-strength,high-modulus,high thermal resistance and good environment stability.In this part,the recent studies on such polymers were reviewed mainly on their general structures,properties and chemical modification.
摘要:In this paper,the principle of Resin Transfer Molding (RTM) technology for composite processing is introduced,and the requirement of the resins for RTM is discussed.Advanced polymers developed for RTM are reviewed with the emphasis on their performance and commercial applications.
关键词:Composite material;Resin transfer molding;Advanced polymers
摘要:Three representative activity coefficient models were compared for the calculation of the thermodynamic factor relating self-to mutual-diffusion coefficients of polymer solutions using the experimental data of40polymer solution systems.The calculated results show that the three models have similar accuracy,and the AADs are around20%.This work shows a potential problem in the calculation of mutual-diffusion coefficients from self-diffusion coefficients,that is,the big uncertainty caused by the calculation of the thermodynamic factor with an activity coefficient model.
摘要:The preparations and the structures and the properties of chitin and chitosan are introduced, and the applications in immobilization and flocculant and drug delivery system and so on are discussed.
摘要:The progress of study on syndiotactic polypropylene (sPP) was reviewed, including syndiospecific metallocene catalyst, properties and application of sPP .The effect of metallocene catalyst on the syndiotactity and crystalization was discussed .The analytical results showed that the application perspective of sPP was good becuause of its execllent properties in transmittance and impact stress .It was emphasized that study on supporting metallocene and processability of sPP was necessary for commerical production of sPP .
摘要:Nanofiltration (NF) is a novel type of pressure-driven filtration process with membranes whose molecular weight cut-off (MWCO) lie between reverse osmosis membranes and ultrafiltration membranes,i.e. range between200and 1000g/mol,and NF membranes have nanopore radius (10-9m), so the selection of membranes material and preparation technique become the key to manufacture NF membranes with high properties. In this paper,several of main preparation techniques of polymeric NF membranes including L-S phase separation way,transition way,co-blending way,charging way and composite way were introduced,the research on the material,preparation methods of polymeric nanofiltration membranes and its performance and application in recent years were also reviewed.
摘要:The homopolymer and the copolymer of acrylic acid and acrylamide is very useful and important. Some main properties,such as:rheological property and degradation,and the development of the research of this copolymer are reviewed here.Further more,the methods of their synthesis using mainly four techniques: hydrolization,aqueous solution polymerization,inverse emulsion polymerization and inverse suspension polymerition
摘要:Factors and relation of skin melt formation under isothermal condition have been analyzed during gas-assisted injection molding in a tube.This research shows that thickness ratio of skin melt is about0.3 which is close to the experimental values 0.34~0.37,and that the ratio value (<0.3) of non-Newtonian fluid is less than the value0.38of gas-assisted injection molding.The difference factors are analyzed under nonisothermal condition,which shows that shear stress at the gas/melt interface and the pressure gradients existing at the gas and melt fronts are two very important contributing factors forming skin melt thickness in addition to melt temperature,mold temperature and gas delay time,which were recognized as the important influence parameters on the skin melt formation.