最新刊期

    卷 0 , 期 0 , 2020
    • Jin-lan JU,Qing-chao GU
      Vol. 15, Issue 2, Pages: 1-8(2002) DOI: 10.14028/j.cnki.1003-3726.2002.02.001
      摘要:Solid polymer electrolytes are expected to play an critical role in the development of zero-emission energy source.This paper presents some new results and concepts for designing polymer electrolytes.Polymer gel electrolytes,dual-phase polymer electrolytes,polymer-in-salt,organic/inorganic nanocomposite polymer electrolytes,network polymer electrolytes with short ether side chains are reviewed with 56 references.  
      关键词:Solid polymer electrolytes;Ionic conductivity   
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      发布时间:2022-09-18
    • Jian-jun YUAN,Shi-yuan CHENG,Lin-xian FENG
      Vol. 15, Issue 2, Pages: 9-17,28(2002) DOI: 10.14028/j.cnki.1003-3726.2002.02.002
      摘要:In this paper,fabricating several kinds of nanomaterials and Photonic crystals based on the self-assemble properties of block copolymer was reviewed.  
      关键词:Block copolymer;Nanomaterials;Photonic crystals;Self-assembly   
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      发布时间:2022-09-18
    • Xue LI,Yan-chun HAN,Li-jia AN,Zhe WANG
      Vol. 15, Issue 2, Pages: 18-28(2002) DOI: 10.14028/j.cnki.1003-3726.2002.02.003
      摘要:The paper reviewed the recent development in phase separation behavior of thin polymer mixture films.The mechanisms of phase separation,scaling law of domain coarsening in hydrodynamic regime at late stage,the factors influencing the formation of phase morphology in polymer mixture thin films were discussed in detail.The paper ended with a summary of possible future directions in the field.  
      关键词:Polymer mixture;Phase separation;Thin films   
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      发布时间:2022-09-18
    • Yuan-xia LIU,Yi-qun FANG,Ju-wei SONG,Wei LI,You-liang HU
      Vol. 15, Issue 2, Pages: 29-37(2002) DOI: 10.14028/j.cnki.1003-3726.2002.02.004
      摘要:In this Paper, recent advances of the chromium-based catalysts developed, at home and abroad, were reviewed .From the incisive analysis based on the documents collected, and a longstanding debate over questions about chemical nature of the active site( s) , the oxidation state of active chromium, and the mechanism of initiation has been resoluted, it was concluded that chromium-based catalysts would continue to play an important role in ethylene industry and take up some fields in nanocomposite materials in coming years .  
      关键词:Chromium based catalyst;Ethylene;Oligomerization;Polymerization   
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      发布时间:2022-09-18
    • Lai-xing PANG,Jian-wen YANG,Zhao-hua ZENG,Yong-lie CHEN
      Vol. 15, Issue 2, Pages: 38-42,8(2002) DOI: 10.14028/j.cnki.1003-3726.2002.02.005
      摘要:Powder coatings curable by ultraviolet light is a new coating technology which combines many of the advantages of conventional thermosetting powder coatings with liquid UV cured coating technology.This article reviewed the preparation,handling,and potential applications of UV curable powder coatings,and its recent development.  
      关键词:Powder coatings;Irradiation curable coatings;UV-Curable   
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      发布时间:2022-09-18
    • Ying CAI,Qi WU,Xing-tao XUE,Chen-guo FENG,De-shui LV,Xian-fu LIN
      Vol. 15, Issue 2, Pages: 43-48(2002) DOI: 10.14028/j.cnki.1003-3726.2002.02.006
      摘要:This article provides a review of enzymatic synthisis of sugar-containing polymers concluding sugar-containing linear polyesters,linear polymers with pendent saccharides which are called glycopolymers and others.Most of the sugar-containing linear polyesters can be synthesized with enzyme as the catalyst,while the glycopolymers must be synthesized by two steps:enzymatic synthesis of sugar-containing monomers and chemically polymerization of the monomers.  
      关键词:Enzymatic synthesis;Sugar ester;Sugar-containing polymers;Synthesis   
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      发布时间:2022-09-18
    • Hong-dong DUAN,Wan-guo HOU,Lu-shan WANG,Xi-ming LI,Bo-geng LI
      Vol. 15, Issue 2, Pages: 49-55(2002) DOI: 10.14028/j.cnki.1003-3726.2002.02.007
      摘要:Water based gels, comprising partially hydrolyzed polyacrylamide ( HPAM) cross-linked with chromium ( Ⅲ) , are now finding widespread use for near well-bore water and gas shut-off in the oil industry . The study on the mechanism and kinetics of the cross-linking reaction is very important to understand and improve the in-situ application of the gels technology .This paper reviewed several researchmethods on the mechanism and kinetics of the crosslinking reaction between HPAM and chromium ( Ⅲ) , such as Uv-visible spectroscopy, atomic force microspectrocopy ( AFM) , laser light scattering method, and focused on the rheological measurements.  
      关键词:Gelation;Rheological measurement;Uv-visible spectroscopy;Atomic force microspectrocopy (AFM);Laser light scattering method   
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      发布时间:2022-09-18
    • Zhen-li WEI,Yong-zhong BAO,Zhi-xue WENG,Zhi-ming HUANG
      Vol. 15, Issue 2, Pages: 56-60,78(2002) DOI: 10.14028/j.cnki.1003-3726.2002.02.008
      摘要:The development of studies on a new polymerization process,suspended emulsion polymerization (SEP),was reviewed in this paper.The unique characteristics of SEP are showed by comparing it with suspension polymerization and emulsion polymerization.The mechanism of SEP and influences of suspending agent,surfactant and water/oil ratio on the particle morphology are also reviewed.  
      关键词:Suspended emulsion polymerization;Vinyl chloride;Acrylonitrile;Methylacrylate;Particle morphology   
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      发布时间:2022-09-18
    • Guang-xin CHEN,Guang-jie HAO,Tian-ying GUO,Mou-dao SONG,Bang-hua ZHANG
      Vol. 15, Issue 2, Pages: 61-66(2002) DOI: 10.14028/j.cnki.1003-3726.2002.02.009
      摘要:Polymer layered silicate nanocomposites are of a novel type of advanced composites,which have been studied for about 10 years.This new family of material exhibits enhanced properties at very low filler level,usually inferior to 5%(wt),such as increased Yong’s modulus and storage modulus,increase in thermal stability and gas barries properties and good flame retardancy.In this paper,the recent developments in properties of polymer/layered silicate nanocomposites are reviewed.  
      关键词:Nanocomposites;Layered silicates;Properties   
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      发布时间:2022-09-18
    • Yun-chuan XIE,Xiao-dong FAN
      Vol. 15, Issue 2, Pages: 67-74(2002) DOI: 10.14028/j.cnki.1003-3726.2002.02.010
      摘要:A novel thermal analysis technology---Modulated Differential Scanning Calorimetry(MDSC) was introduced.The basic theory and advantages including its applications in polymer material science were also discussed in detail.  
      关键词:Modulated DSC;Reversing heat flow;Non-reversing heat flow;Thermal analysis in polymers   
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      发布时间:2022-09-18
    • Ping-sheng HE
      Vol. 15, Issue 2, Pages: 75-78(2002) DOI: 10.14028/j.cnki.1003-3726.2002.02.011
      摘要:WLF equation is the special temperature dependence of motion of segment---the special motion unit in polymer.The change of energy is not important in the motion of segment.The most important,alternatively ,is the change of entropy.The reason is "giant" of macromolecule only,which causes a new parameter of structure---flexibility,its special temperature dependence of motion of segment---WLF equation and the special mechanical properties---rubber elasticity.  
      关键词:WLF equation;Segment;Free volume   
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      发布时间:2022-09-18
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