摘要:The funding programs on polymer science have been briefly introduced. The frontiers,trends in the discipline of polymer science as well as the scope of the funding programs of the division of polymer science have been overviewed.
关键词:Grant of National Natural Science Foundation;Polymer science;Project application
摘要:The recent progress in design and synthesis of macromolecular architecture via living anionic polymerization has been reviewed in this article, including π-shaped copolymer, H-shaped polymer, dumbbell copolymer, ABC miktoarm star copolymer, hyperbranched polymer, cyclic polymer, tadpole polymer, centipede copolymer, and barbwire copolymer.
摘要:In recent years,protein and peptides have been extensive applied in various treatment of disease. This paper reviewed the protein and peptides PEGlations and the controlled release system. Furthermore,prospected the advanced targeted and more absorbable protein and peptides system.
摘要:Influencing factor of PET crystallization behavior are reviewed in this paper,including the content of diethylene glycol,catalysts,physical aging,and reinforcing fiber. And the ways of increasing crystallization rate of PET are discussed too.
摘要:This paper introduced the synthesis and application of microporous polymer,mesoporous polymer,and macroporous polymer. A wide range of porous polymer synthesis techniques were summarized,including colloidal crystal templates,track-etch membrance templates,suspension polymerization,as well as supercritical fluid. The potential uses of porous polymer in the field of surface functionalization and sensing were also reviewed.
摘要:Enantioselective epoxidation of olefins catalyzed by polymer-supported metal complex was reviewed recently. We emphatically set forth the catalytic activities of organic and inorganic polymeric metal catalysis and put forward some advices on how to design polymer-supported metal catalysis having high catalytic activities and high enantioselectivities.
摘要:In this paper,the research of the polymer montmorillonite nanocomposites (PMN) in recent years were reviewed. The crystal property,mechanical property and rheological property were discussed in detail. At the same time,the thermodynamics,dynamics and medial field theories in the synthesizing process were expounded. In the end,this paper put forward some novel methods for synthesizing this sort of stuff.
摘要:Under the impacting stress,the pressure on the surface of the bulk is almost infinite and toughenment is based on the localized displacement of material. Any material can be toughened by the measurement that enhances the shift ability of the sample. Between the particle and the bulk,transition area is critical in the particle toughening system,and a new mechanism is postulated "cracking-wedging-compressing-altering the direction of the impacting force" ,which can explain all the phenomena in the experiment.
摘要:With the improved demands on material properties,researches on N-substituted maleimides become more and more popular because their polymers show high thermal properties. In this paper,progress on polymerization of N-substituted maleimides by free radical polymerization,anionic polymerization and coordination polymerization are reviewed.
摘要:Research progress in synthesis of block copolymer by transformation polymerization of living cationic polymerization into other kinds of polymerizations was summarized.
摘要:The relationships of extrudate distortion and the non -linear viscoelasticity for HDPE, POE, EPDM etc were studied by capillary rheometer. It is indicated that the melt slip at wall and the extrusion pressure oscillation were easy occurred in linear macromolecule melts and difficulter occurred in polymer melts having biger side-group or broader molecule weight distribution, or having a lot of short side-chain. More the chain entanglement, andmore the shear stress between melts and the wall of capillary, the melt slip at wall and the pressure oscillation became stronger. The melts fracture behaviors were influenced more by the extensional viscosity, but less by the steady shear viscosity of melt.
关键词:Linear PE melts;Extrudate distortion;Melt slip at wall;Pressure oscillation;Non-linear viscoelasticity
摘要:A novel method of concentrated emulsion biphasic polymerization was proposed to prepare the poly- (butyl acrylate) (PBA) nonspherical particles. The effects of the types of polymer interlayer between PBA particles, the volume fraction of dispersed phase and the content of crosslinking agent on the heteromorphic extent of PBA particles were investigated. The results showed that the higher the volume fraction of dispersed phase and the content of divinyl benzene (DVB) crosslinking agent,the more heteromorphic the PBA particles,and the more the content of the DVB crosslinking agent,the more uniform of the PBA particles.
摘要:A catalyst was synthesized for propene polymerization using SiO2_MgCl2 composite as carrier. The effect of activation condition of SiO2, SiO2 MgCl2 mass ratio and different manufacture process of this catalyst was tested. It was found that the isotactic index of resin could be achieved without addition of ex_donor in propene polymerization using this catalyst through a test of hydrogen adjusting and polymerization time.
关键词:Composite carrier;Polypropylene;Donor compound;Catalyst;Isotactic index
摘要:This paper studies the synthesis and characterization of the polymer (CAANA) which is composed of acrylamide,3-acrylamide-3-methyl-butyric sodium and N-alkyl acrylamide. By the pyrene fluorenetry and laser light scattering,the determinations show that inter-molecular hydrophobic association is formed and get the bigger hydrodynamic radius. The CAANA is better temperature-tolence and salt-resistence than the HPAM. In definite range,the hydrophobic association is more stronger,the characters of temperature-tolence and salt-resisitence is more better.
关键词:Water-soluble polymer;Copolymer;Hydrophobic association;Temperature-tolence and saltresisitence;Enhanced oil recovery
摘要:Molecularly imprinted polymers (MIPs) have attracted many attentions from chemists and biologists. Their fairly high affinity and selectivity to the print molecules made them potential materials that might be widely used in many different disciplines. In this article, a brief review over the development of molecular imprinting technology was given, and special attentions were gone to both the preparation of biological macromolecule imprinted polymers and the phenomenon of molecular recognition happened in aqueous media with imprinted polymer. Although some difficulties still existed in the study of molecularly imprinted polymer, more achievements would be made in the near future.
摘要:Chitin and chitosan are paid more and more attention in the field of wound dressing as their excellent properties of biocompatibility, biodegradability, nontoxicity, hemostasis, acesodyne, sterilization, accelerating the healing up of the wound and reducing the scar. In this paper, the mechanism of chitin and chitosan in accelerating wound healing are discussed, and the research progress of the wound dressing with excellent property prepared via chitin, chitosan and their derivant are reviewed.
摘要:Proton exchange membrane (PEM) is one of the key parts of the proton exchange membrane fuel cell (PEMFC) ; its properties determine the main properties of the PEMFC in the great sense. This paper reviews the characterization of the membrane material; and discusses the characterization of porosity,density,viscosity, sulfonation,selective permeation,conductivity and so on.
摘要:Microfluidic deivices have increasing application as analytical systems,biomedical devices,tools for chemistry and biochemistry,and systems for fundamental research. Conventional methods of fabricating microfluidic devices have focused on etching in glass and silicon. Fabrication of microfluidic devices in poly (dimethylsiloxane) (PDMS) by soft lithography provides faster,less expensive routes than these conventional methods. These softlithographic methods are based on rapid prototyping and replica molding. At the same time,they are also more accessible for chemists and biologists to work under benchtop conditions because devices do not need to be fabricated in a cleanroom using soft lithography. This paper describes devices fabricated in PDMS for separations and patterning of biological material.