最新刊期

    卷 30 , 期 1 , 2017
    • Jian-hua DONG
      Vol. 30, Issue 1, Pages: 1-8(2017) DOI: 10.14028/j.cnki.1003-3726.2017.01.001
      摘要:An overview on the recent progress in polymer science was conducted. The funding projects in 2016 for programs on polymer science in the department of chemical science were introduced. The guide to funding program in fiscal year 2017 was provided.  
      关键词:Guide to funding of NSFC;Progress in polymer science;2016 Funding in polymer science   
      6
      |
      12
      |
      0
      <HTML>
      <L-PDF><Meta-XML>
      <引用本文> <批量引用> 29693104 false
      发布时间:2022-09-06
    • Xiao-ling KANG,Yang DU,Jin ZHAO,Xu-bo YUAN,Xin HOU
      Vol. 30, Issue 1, Pages: 9-21(2017) DOI: 10.14028/j.cnki.1003-3726.2017.01.002
      摘要:Recent years water contamination by oil and oil spill in sea are the major disasters impacting the living conditions of human beings and marine environments. Phase selective gelators are providing novel choices for oil spill remediation due to their properties of simple synthesis, environmental compatibility, efficiency and reusability. In this review, firstly, classification and self-assembly mechanism of the phase selective gelators were presented. Secondly, the development of phase selective gelators composed of low-weight molecules such as amino acids, organic acids and salts, steroids and carbohydrate moieties was mainly discussed and organic polymer gelators were briefly introduced. Finally, future development of phase selective gelators was predicted.  
      关键词:Gelator;Phase selective;Gelation;Oil spill   
      7
      |
      10
      |
      0
      <HTML>
      <L-PDF><Meta-XML>
      <引用本文> <批量引用> 29693113 false
      发布时间:2022-09-06
    • Cui-ping LI,Tian-zhu ZHOU,Tian-wen ZHU
      Vol. 30, Issue 1, Pages: 22-34(2017) DOI: 10.14028/j.cnki.1003-3726.2017.01.003
      摘要:Attractive features of radical polymerization (RP) in the presence of sulfonyl chloride include mild reaction condition, simple system composition, and great monomer versatility. This paper summarized the application of sulfonyl chloride in radical polymerization, including the initiator of atom transfer radical polymerization (ATRP), the initiator of single-electron transfer living radical polymerization (SET-LRP) and the chain transfer agent (CTA) of conversional radical polymerization. This paper gave a general overview about the applicability to different monomers for various applications, the relationship of reactivity with the structure of sulfonyl chloride and the polymer synthesis based on sulfonyl chloride (multisulfonyl chloride initiator and chain transfer monomer).  
      关键词:Sulfonyl chlorides;Initiator;Chain transfer agent (CTA);Atom transfer radical polymerization (ATRP);Single-electron transfer living radical polymerization (SET-LRP);Radical polymerization   
      6
      |
      10
      |
      1
      <HTML>
      <L-PDF><Meta-XML>
      <引用本文> <批量引用> 29693110 false
      发布时间:2022-09-06
    • Cai-xia HAO,Jing-min GAO,Yong YI,Jin WANG,Ji-dong HE
      Vol. 30, Issue 1, Pages: 35-46(2017) DOI: 10.14028/j.cnki.1003-3726.2017.01.004
      摘要:Polyimide has excellent resistance to high temperature, but poor fusion and processing properties limited its wide application. Thermoplastic polyimide synthesized by introducing flexible groups, by designing the molecular structure of isomerization and other methods will get improved processing properties, and it can be used for extrusion and injection molding processing directly. In this paper, the synthesis methods of thermoplastic polyimide resin and its monomer were summarized. Moreover preparation methods and performance properties of nylon, poly(ether ether ketone) and epoxy resin modified with polyimide were proposed. Furthermore, the future development of polyimide modified engineering plastics were prospected.  
      关键词:Thermoplastic;Polyimide;Modification;Nylon;Poly(ether ether ketone);Epoxy resin   
      13
      |
      22
      |
      5
      <HTML>
      <L-PDF><Meta-XML>
      <引用本文> <批量引用> 29693114 false
      发布时间:2022-09-06
    • Peng DONG,Fang XU,Kun CUI,Tao JIANG
      Vol. 30, Issue 1, Pages: 47-56(2017) DOI: 10.14028/j.cnki.1003-3726.2017.01.005
      摘要:This review focuses on recent progress of self-healing polymer hydrogel. The strategies targeting self-healing polymer hydrogel, the self-healing contributions from different types of polymers, the self-healing degree of hydrogel and its verification methods were analyzed and compared. Overall, both in the molecular design of self-healing polymer and in the healing mechanism of hydrogels, new and important progress has been achieved. However, the polymer hydrogel’s self-healing ability need to be further improved. The design of novel polymer, the improvement in the fabrication method of hydrogel and the enhancement in self-healing efficiency will have a significant impact on the further application of self-healing polymer hydrogel.  
      关键词:Polymer;Self-healing;Hydrogel;Synthesis   
      5
      |
      10
      |
      0
      <HTML>
      <L-PDF><Meta-XML>
      <引用本文> <批量引用> 29693112 false
      发布时间:2022-09-06
    • Ying FENG,Tao TIAN,Chun-hua ZHOU
      Vol. 30, Issue 1, Pages: 57-65(2017) DOI: 10.14028/j.cnki.1003-3726.2017.01.006
      摘要:As a novel functional material, functionalization magnetic polymeric microspheres offer high potential application in various field. In this review, we summarize the more recent development of synthesis of functionalization magnetic polymeric microspheres, and analyze the advantages and disadvantages of these synthetic methods, and expound the applications of in bioengineering, biomedical, environment, food, and functional materials field, and comprehensively analyses the advantages in various field and achievements already made. Finally, the prospected future of magnetic polymeric microspheres are also described, the own view and four problems that needed solving were proposed.  
      关键词:Magnetic microsphere;Functionalization;Preparation;Application   
      6
      |
      9
      |
      1
      <HTML>
      <L-PDF><Meta-XML>
      <引用本文> <批量引用> 29693187 false
      发布时间:2022-09-06
    • Ting-jian LI,Hui ZHU,Li FAN,Li YANG,Jie ZHANG
      Vol. 30, Issue 1, Pages: 66-70(2017) DOI: 10.14028/j.cnki.1003-3726.2017.01.007
      摘要:As there is often a certain deviation between actual process conditions and the ideal conditions, after shaping the product there are usually some unavoidable defects, and the residual stress is the most common one. Residual stresses of injection products are the still remained inner stresses even though the outer restrictions have been removed, easily causing warpage, deformation or even crack that will mainly do harm to the parts in many cases when the products get used. So it is important to pay attention to the influence of residual stresses when designing plastic products. This article is mainly to give a relatively detailed introduction to residual stresses, surrounding by their generating, measuring, and decreasing as well as computer simulating.  
      关键词:Residual stress;Measurement of residual stress;Moldflow   
      7
      |
      9
      |
      2
      <HTML>
      <L-PDF><Meta-XML>
      <引用本文> <批量引用> 29693185 false
      发布时间:2022-09-06
    • Wei-li WU,Jiang-kun LI
      Vol. 30, Issue 1, Pages: 71-77(2017) DOI: 10.14028/j.cnki.1003-3726.2017.01.008
      摘要:Taking octadecane/poly (styrene-methyl methacrylate) (P (St-MMA)) microcapsule as phase change materials, silicone rubber as carrier, octadecane/P (St-MMA)/silicone rubber composites were prepared. The join way and the addition of microcapsule, silicone rubber coated method were studied. The structure and morphology of the composite materials were study by infrared spectrum (IR) and scanning electron microscopy (SEM). Through mechanical properties test such as tensile strength, elongation at break, determine the best processing method. The thermal properties of the composite were studied by thermogravimetric analysis (TG), differential scanning calorimetry (DSC) and thermal storage properties. Results showed that thermal and mechanical properties of octadecane/P(MMA-St) microcapsules/silicone rubber are good when the octadecane made microcapsules is added into the silicone rubber, and the amount of microcapsules is 2 phr (per hundred rubber), the mechanical properties of composites by room-temperature silicone rubber coated microcapsule are superior to those of direct hot curing after blending and hot curing after mixed daub. The enthalpy value of octadecane/P (St-MMA)/silicone rubber composites is 67.6 J/g, the energy storage effect is good.  
      关键词:Composite materials;Silicone Rubber;Energy storage microcapsule;Thermal properties   
      5
      |
      9
      |
      2
      <HTML>
      <L-PDF><Meta-XML>
      <引用本文> <批量引用> 29693188 false
      发布时间:2022-09-06
    • Ming-fei LI
      Vol. 30, Issue 1, Pages: 78-82(2017) DOI: 10.14028/j.cnki.1003-3726.2017.01.009
      摘要:Lignin is an important natural polymer and its utilization has been considered to be an hot topic in the materials field. The course of lignin and its utilization in polymer materials includes the structure and properties of lignin, lignin-based chemicals, lignin-based thermoset material, lignin-based thermoplastic material, new material of lignin, and the performance evaluation of lignin material. The course has the following characteristics:(1) knowledge points are abundant and the contents are scattered, (2) the knowledge shows a broad area, and (3) there are lots of new knowledge. Based on the above points, the teaching methods for the course were proposed as follow:(1) case teaching approach was applied and the teaching was closely related to the practice; (2) flipped classroom teaching was applied to enhance the self-learning ability of students; (3) bilingual teaching was strengthened to improve the international professional skills; and (4) flexible and effective exam was conducted to improve the comprehensive ability of students.  
      关键词:Natural polymer;Lignin;Case teaching;Flipped class   
      5
      |
      11
      |
      0
      <HTML>
      <L-PDF><Meta-XML>
      <引用本文> <批量引用> 29693186 false
      发布时间:2022-09-06
    • Jing-ru LIU,Cheng CHANG,Qiang YU
      Vol. 30, Issue 1, Pages: 83-86(2017) DOI: 10.14028/j.cnki.1003-3726.2017.01.010
      摘要:Polymer physics is an important professional basic course of students majoring in polymer materials and engineering. Rubber is a kind of polymer material with excellent properties. The structures and properties of rubber materials combine the knowledge of polymer physics from many aspects. In the teaching process of polymer physics, we inserted some concrete examples of rubbers. By introducing the structures, the molecular motion, the performance and the crosslinking of rubber materials, which can be in series with the related knowledge points of polymer physics, the students’ perceptions of knowledge points can be enhanced and the learning of the basic concepts and basic theory of polymer physics can be strengthened. Better teaching effect has been achieved.  
      关键词:Polymer physics;Rubber;Structure;Property   
      6
      |
      14
      |
      0
      <HTML>
      <L-PDF><Meta-XML>
      <引用本文> <批量引用> 29693191 false
      发布时间:2022-09-06
    • Hong-qiang LI,Li YANG,Zhong-hua CHEN
      Vol. 30, Issue 1, Pages: 87-90(2017) DOI: 10.14028/j.cnki.1003-3726.2017.01.011
      摘要:According to the requirement of the rapid development of coating industry for the professional and technical talents, the significance of training practical and application-oriented talents is put forward. In this paper, the teaching characteristics, setting and arrangement of teaching content were introduced, and the teaching methods and supplementary measures were also discussed. By fully using multimedia and material objects, strengthening comparative analysis, constructing practical teaching platform and establishing reasonable evaluation system, the teaching quality and the students’ practical and applied-oriented ability can be improved.  
      关键词:Coatings;Practical and applied-oriented;Teaching methods   
      5
      |
      11
      |
      0
      <HTML>
      <L-PDF><Meta-XML>
      <引用本文> <批量引用> 29693203 false
      发布时间:2022-09-06
    0