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1.大连大学环境与化学工程学院,大连 116622
2.辽宁生物医学材料研发中心有限公司,大连 116100
徐立霞,女,硕士研究生,主要从事医用高分子材料的研究。E-mail: xulixia332006@126.com
*E-mail: homebox11@126.com.
纸质出版日期:2012-07,
收稿日期:2011-11-14,
修回日期:2012-02-09,
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徐立霞, 刘艳, 卢春兰, 李昕跃. 尼龙-12球囊成形过程中的材料聚集态的变化[J]. 高分子通报, 2012,25(7):104-110.
Li-xia XU, Yan LIU, Chun-lan LU, Xin-yue LI. State of Aggregation Changes of Nylon-12 Balloon in Molding Process[J]. Polymer Bulletin, 2012,25(7):104-110.
医用球囊已经广泛用于心脑血管疾病的治疗
但是国内对医用球囊加工过程的理论研究报道较少。本文首先对医用球囊的成形过程进行了简要的介绍
并以尼龙12为原料
通过一次成形、二次成形和最终成形过程中的操作条件的控制
制备出一系列球囊;然后用水压爆破仪对其在成形过程中各样品的应力-应变曲线进行了考察。利用X射线衍射分析(XRD)、差热扫描实验(DSC)和红外透射光谱实验
分别进一步考察了球囊在成形过程中材料的晶格参数、熔点与结晶度以及内部基团的变化。通过表征发现
在上述三个加工步骤中,尼龙12材料内部的高分子链间的作用力首先减弱
使材料具有更好的可塑性和可加工性能,而后的处理过程使高分子链间作用力增强
由球囊的应力-应变测试结果和球囊顺应性测试结果可知
经过上述步骤后
球囊的顺应性明显降低
而顺应性越小
则球囊在相同外力的作用下
形变越小,也就是说最终制成的球囊的强度和稳定性得到了提高。
Medical balloon has been widely used for the treatment of cardiovascular and cerebrovascular diseases
but the theoretical studies in processing process of medical balloon have reported less in the domestic. This paper introduced briefly in the processing process of medical balloon at first
and producted a series of balloon with the nylon 12 as raw materials
through first molding
second forming and final molding process of the operating conditions of control. Then the compliance change in the molding process were studied with hydraulic blasting apparatus
And the internal structure
material’s melting point
crystallinity and the change of the interior Chemical groups of the nylon 12 during the molding process were separately inspected
using X ray diffraction (XRD)
Differential Scanning Caborimetry (DSC) and infrared transmission spectroscopy experiments. The acting force between the polymeric chain of nylon 12 reduced at the first
so that the material has better plasticity and machinability
and then the acting force of polymer chain is enhanced
so that the final balloon has higher strength and stability were discovered through the characterization in three of the above processing steps.
医用球囊尼龙12聚集态变化
Medical balloonNylon 12State of aggregation changes
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