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1.河北工业大学化工学院,天津 300130
2.中国科学院长春应用化学研究所高分子物理与化学国家重点实验室,长春 130023
李贵芳(1985-),女,硕士研究生,主要从事有机光伏研究;E-mail: liguifang85@163.com, Tel: 022-60204297;
*E-mail: qindashan@yahoo.com.cn, Tel: 022-60204297.
纸质出版日期:2012-08,
收稿日期:2012-01-12,
修回日期:2012-02-22,
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李贵芳, 全威, 刘金锁, 陈磊, 张吉东, 闫东航, 秦大山. 加入NPB提高P3HT:PCBM聚合物太阳能电池光伏性能[J]. 高分子通报, 2012,25(8):92-97.
Gui-fang LI, Wei QUAN, Jin-suo LIU, Lei CHEN, Ji-dong ZHANG, Dong-hang YAN, Da-shan QIN. Photovoltaic Performance Improvement of P3HT: PCBM Polymer Solar Cells by Adding NPB[J]. Polymer Bulletin, 2012,25(8):92-97.
李贵芳, 全威, 刘金锁, 陈磊, 张吉东, 闫东航, 秦大山. 加入NPB提高P3HT:PCBM聚合物太阳能电池光伏性能[J]. 高分子通报, 2012,25(8):92-97. DOI:
Gui-fang LI, Wei QUAN, Jin-suo LIU, Lei CHEN, Ji-dong ZHANG, Dong-hang YAN, Da-shan QIN. Photovoltaic Performance Improvement of P3HT: PCBM Polymer Solar Cells by Adding NPB[J]. Polymer Bulletin, 2012,25(8):92-97. DOI:
研究了在聚3-己基噻吩(P3HT)和[6
6]-苯基-C61-丁酸甲酯(PCBM)共混薄膜中加入第三组分N
N’-二苯基-N
N’-(1-萘基)-1
1’-联苯-4
4’-二胺(NPB)对器件性能的影响。实验发现:加入NPB可以促进P3HT:PCBM本体异质结的生长
进而提高器件的光伏性能
当NPB浓度为0.4mg/mL时
能量转换效率(PCE)从1.05%提高到1.64%。NPB的加入使P3HT在可见光范围内吸收增强
特别是在560nm和610nm处的吸收强度明显增大;扫描电子显微镜(SEM)研究结果表明
NPB的加入增大了P3HT与PCBM的相分离程度
提高了激子分离的几率;空穴单极性电流-电压曲线证明适量NPB的加入改善了薄膜空穴传输性能。
Organic and polymer photovoltaic cells are becoming an extremely active research area to meet the urgent need for clean and renewable energy managements due to their potential applications as flexible
low cost and solution processable energy sources. In this article
the influence of introducing a small amount of NPB into the mixed P3HT:PCBM solution on the performance of the polymer solar cells was investigated. It was found that adding NPB improved bulk heterojunction grown which enhanced the photovoltaic performance. When NPB content is 0.4mg/mL
PCE increased from 1.05% to 1.64%. The UV-Vis absorption spectra showed that the intensities of the absorption peaks at 560 and 610 nm increased because of the increased absorption π→π* transition of P3HT after adding NPB. SEM results also showed that the P3HT:PCBM phase separation increased markedly after adding NPB which is valuable for exciton dissociation. It was found that the hole mobility could be pronouncedly influenced by adding NPB.
聚合物太阳能电池本体异质结NPB三组分共混薄膜
Polymer solar cellBulk heterojunctionNPBTernary blend films
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