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重庆理工大学化学化工学院,重庆 400054
朱久进(1967-),女,博士,副教授,主要从事有机合成、高分子合成研究,E-mail: zhujiujin@163.com.
纸质出版日期:2013-03,
收稿日期:2012-09-12,
修回日期:2012-10-11,
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朱久进, 陈志, 张晓凤, 桑雪梅. 环糊精功能化单体制备的研究现状[J]. 高分子通报, 2013,26(3):25-29.
Jiu-jin ZHU, Zhi CHEN, Xiao-feng ZHANG, Xue-mei SANG. Review on Synthesis of Functional β-Cyclodextrin Monomer[J]. Polymer Bulletin, 2013,26(3):25-29.
朱久进, 陈志, 张晓凤, 桑雪梅. 环糊精功能化单体制备的研究现状[J]. 高分子通报, 2013,26(3):25-29. DOI:
Jiu-jin ZHU, Zhi CHEN, Xiao-feng ZHANG, Xue-mei SANG. Review on Synthesis of Functional β-Cyclodextrin Monomer[J]. Polymer Bulletin, 2013,26(3):25-29. DOI:
环糊精聚合物是含有多个环糊精单元的高分子衍生物
兼具环糊精和高聚物二者良好的性能
在分子识别、分离分析技术、生物医学工程、环境等领域得到广泛的应用。环糊精聚合物的合成得到广泛关注
将环糊精单体功能化是制备环糊精聚合物的关键步骤。本文综述了
β
-环糊精单体功能化的几种制备方法
包括将环糊精修饰成带高反应活性的官能团、修饰成含乙烯基环糊精单体以及多取代官能团环糊精单体等。
Cyclodextrin polymers are polymeric derivatives which have multiple cyclodextrins
and they have the high performance of both
-cyclodextrin and polymers
so they are widely used in the areas including molecular recognition
separation and analytical techniques
biomedical engineering
environmental protection
etc. The synthesis of cyclodextrin polymers has been given abroad attention
and the functionalization of
-cyclodextrin monomer is the key step of synthesis of
-cyclodextrin polymers. The synthesis methods of
-cyclodextrin monomer with functional groups were reviewed
including modifying it to
-cyclodextrin monomer with highly active functional groups
to cyclodextrin monomers carrying vinyl group and to cyclodextrin monomers with multiple substituted functional groups
etc.
β-环糊精功能化制备
β-CyclodextrinFunctionalizationSynthesis
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