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1.中国工程物理研究院化工材料研究所,绵阳 621900
2.西南科技大学材料科学与工程学院,绵阳 621010
3.中国工程物理研究院激光聚变研究中心,绵阳 621900
张国艳(1986-),女,硕士研究生,主要从事聚合物基导电复合材料的研究;
*E-mail:he_jiangping@yahoo.com;
mahanbing@163.com.
纸质出版日期:2013-07,
收稿日期:2013-01-01,
修回日期:2013-04-18,
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张国艳, 刘涛, 易勇, 刘黎明, 罗江山, 谭秀兰, 芦艾, 贺江平, 马寒冰. 低熔点金属/聚合物复合材料的研究现状[J]. 高分子通报, 2013,26(7):77-83.
Guo-yan ZHANG, Tao LIU, Yong YI, Li-ming LIU, Jiang-shan LUO, Xiu-lan TAN, Ai LU, Jiang-ping HE, Han-bing MA. Present Situation of Studying LMPM/Polymer Composites[J]. Polymer Bulletin, 2013,26(7):77-83.
张国艳, 刘涛, 易勇, 刘黎明, 罗江山, 谭秀兰, 芦艾, 贺江平, 马寒冰. 低熔点金属/聚合物复合材料的研究现状[J]. 高分子通报, 2013,26(7):77-83. DOI:
Guo-yan ZHANG, Tao LIU, Yong YI, Li-ming LIU, Jiang-shan LUO, Xiu-lan TAN, Ai LU, Jiang-ping HE, Han-bing MA. Present Situation of Studying LMPM/Polymer Composites[J]. Polymer Bulletin, 2013,26(7):77-83. DOI:
聚合物基导电复合材料在电磁屏蔽、导电、抗静电、自限温加热、甚至导热等领域
具有广泛的用途。这类复合材料中所用的填料主要有金属、炭黑、石墨、石墨烯等。这些填料在加工过程中处于固态。与之不同的是
低熔点金属熔点低
在加工过程中处于液态
从而可以降低复合体系粘度、提高加工性能、降低设备磨损;还可以实现加工过程中填料原位细化和原位纤维化
以及形成双连续相结构。本文概述了低熔点金属填充聚合物复合材料的制备方法
以及复合材料结构、导电性、流变性和力学性能的主要特点
分析了与其它聚合物基导电复合材料相比LMPM/聚合物复合材料的优势
指出了该领域需要进一步研究的方向。
Polymer-based conductive composites were broadly applied in many fields
such as electromagnetic shielding
electric conduction
antistatic materials
self-limiting temperature heating
heat conduction and so on. Currently
the fillers used in electrically conductive polymer composites are in solid state during the processing
including metal
carbon black
graphite and graphene. In contrast to this
the low melting point metals are in liquid state as conductive fillers during the processing
which allows to reduce the viscosity of the composites
improve the processability
reduce the wear on equipment
reduce the particle size of fillers and increase the length-diameter ratio of particle. In this paper
LMPM/polymer composites’ preparation methods
and the main features of composite’s structure
conductivity
rheology and mechanical properties were reviewed
LMPM/polymer conductive composite’s superiority compared with other polymer-based conductive composites were introduced
and some deficiencies in this field were pointed out.
低熔点金属聚合物导电性流变性力学性能
Low melting point metalPolymerConductivityRheologyMechanical properties
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