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高分子合成与功能构造教育部重点实验室 浙江大学高分子科学与工程学系, 杭州 310027
*E-mail:s_yh0411@zju.edu.cn;
zhengqiang1@zju.edu.cn.
纸质出版日期:2013-09,
收稿日期:2013-04-20,
修回日期:2013-05-07,
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宋义虎, 郑强. 粒子填充高分子熔体的动态流变行为[J]. 高分子通报, 2013,26(9):22-34.
Yi-hu SONG, Qiang ZHENG. Dynamic Rheologies of Particle Filled Polymer Melts[J]. Polymer Bulletin, 2013,26(9):22-34.
粒子填充高分子(Particle filled polymers
PFP)熔体流变行为是高分子科学的重要研究课题之一。PFP流变表现复杂
因粒子结构、基体化学性质、界面相互作用而异
但也具有一些普适的、一般的流变学规律。本文从PFP熔体类液-类固转变、分子弛豫特性、"零剪切"黏度与"平衡"模量、时间-浓度叠加原理、两相模型、非线性黏弹行为等6个不同角度系统介绍PFP动态流变行为的主要实验现象和理论(模型)研究结果
分析该领域已取得的研究共识和尚存的学术争议
并展望该领域今后的研究方向。
Rheology of particle filled polymer (PFP) melts is one of the most important subjects in polymer science. PFP melts exhibit diverse complicated rheological phenomena depending on the structure of filler particles
the chemical nature of the polymeric matrix and the interfacial interaction. However
there are also some universal and general rheological rules among diverse experimental systems. The main experimental phenomena and results from theoretical (model) studies involved in dynamic rheology of PFP melts are summarized in this paper. The common views achieved and the scientific controversies remained so far are pointed out after heavily analyzing extensive investigations on the liquid-to-solid transition of PFP melts
the molecular relaxations
the so-called "zero shear rate" viscosity and "equilibrium" shear modulus
the time-concentration superposition principles
the two-phase model and the nonlinear viscoelasticity. Some perspectives on further studies on rheology of PFP melts are given.
粒子填充高分子动态流变行为类液-类固转变分子弛豫特性时间-浓度叠加原理两相模型非线性黏弹行为
Particle filled polymerDynamic rheologyLiquid-to-solid like transitionMolecular relaxationTime-concentration superposition principleThe two-phase modelNonlinear viscoelasticity
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