Gui-hua LI, Jun-shen LIU, Shuo YANG, Yi LIU, Qing-qing LIU, Xun-yong LIU, Qiao-feng YANG, Yi-zheng LIU. Preparation of Emulsion Acrylate with High Solid Content and Low Viscosity and its Use in Sealants[J]. Polymer Bulletin, 2014,27(7):51-60.
Gui-hua LI, Jun-shen LIU, Shuo YANG, Yi LIU, Qing-qing LIU, Xun-yong LIU, Qiao-feng YANG, Yi-zheng LIU. Preparation of Emulsion Acrylate with High Solid Content and Low Viscosity and its Use in Sealants[J]. Polymer Bulletin, 2014,27(7):51-60.DOI:
The poly (ethyl acrylate/2-ethylhexyl acylate/acrylic acid/methyl methacrylate) seed emulsion with solid content at 55% was prepared by ammonium persulfate-sodium bisulfite redox reaction. Then
a high solid content and low viscosity emulsion in which the solid content from 70% to 74% was obtained using the seeded emulsion as medium
sodium dodecyl sulfate and octylphenol polyoxyethylene ether as emulsifier
sodium bicarbonate as buffer and potassium persulfate as initiator to polymerize the target emulsion at 80 ℃. The results indicated that the obtained seed emulsion was broad peak in particle size
the particle diameter was 150〜300nm
which led to its low viscosity. The high solid content emulsion with a viscosity of 300〜900mPa•s at a shear rate of 20s
-1
was still wide distribution and the particle diameter was 350〜600nm. The sealant was made from the high solid content emulsion having advantages of short curing time
small shrinkage
great intensity.
关键词
高固含量低黏度种子乳液密封胶
Keywords
High solid contentLow viscositySeed emulsionSealant