Two kinds of RH catalysts [Rh(cod)Cl]

2

and [Rh(cod)Cl]

2

were synthesized with 1

5-cyclooctadiene(cod) and 2

5-norbornadiene(nbd) as ligands

using infrared absorption spectroscopy and nuclear magnetic resonance to characterize them

accurately determined the structure

and [Rh(cod)Cl]

2

yielded up to 79.4%. With four kinds of chiral ammonia as cocatalyst and [Rh(cod)Cl]

2

or [Rh(cod)Cl]

2

formed catalytic system to polymerize the substituted phenylacetylene monomer(

1

) that containing dodecyl

according to the helical selective polymerization mechanism induced the chain helical structure of polymer and the weight-average molecular weight up to 493.9 thousand; In addition

[Rh(cod)Cl]

2

catalyzed substituted phenylacetylene mononer(

2

3

4

) that contanis L-propane ammonia ether

L-valerian ammonia ether

and L-styrene acrylic ammonia ether for asymmetric polymerization under the action of no cocatalyst for the first time

the yield and molecular weight of three kinds of polymer are both high

in accordance with the helical selective polymerization of the ligand induced helical structure of three macromolecule main chain

and the main chain cis configuration of Poly(

2

)

Poly(

3

) and Poly(

4

) is 70%

77% and 77% respectively

thus achieved ideal catalytic effect.