Porous organic polymers (POPs) are a new class of porous polymer materials

which feature many excellent merits

like low skeleton density

large specific surface area

good stability. Those materials exhibit enormous potential applications in gas storage and separation

heterogeneous catalysis

biochemical sensing

and many other aspects. Meanwhile

due to its large π-conjugated skeleton

pre-designable chromophores can be introduced into the polymer networks to obtain porous materials with different luminescence. This kind of materials exhibit both porous and luminescent properties

thus it shows wide applications in energy conversion

metal ions sensing and explosives detection

etc. Herein

we summarized the design principles and construction strategies of solid-state luminescent POPs

presented their applications which have been developed

and prospect for future development in such area.