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1.中国科学院青海盐湖研究所,中国科学院盐湖资源综合高效利用重点实验室,西宁 810008
2.青海省盐湖资源化学重点实验室,西宁 810008
3.中国科学院大学,北京 100049
董生德(1991-),男,中国科学院青海盐湖研究所学生,硕士。E-mail:dongshengde16@mails.ucas.ac.cn
*周园(1972-),男,中国科学院青海盐湖研究所研究员,博士。E-mail:zhouy@isl.ac.cn.
海春喜(1983-),女,中国科学院青海盐湖研究所副研究员,博士。E-mail:haicx@isl.ac.cn;
纸质出版日期:2018-08-20,
收稿日期:2017-11-03,
修回日期:2018-07-02,
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董生德, 周园, 海春喜. 用于锂离子电池镍钴锰三元正极材料的改性研究进展[J]. 高分子通报, 2018,31(8):112-118.
Sheng-de DONG, Yuan ZHOU, Chun-xi HAI. Research Progress in Modification of LiNi1-x-yCoxMnyO2 Cathode Materials for Lithium-ion Battery[J]. Polymer Bulletin, 2018,31(8):112-118.
董生德, 周园, 海春喜. 用于锂离子电池镍钴锰三元正极材料的改性研究进展[J]. 高分子通报, 2018,31(8):112-118. DOI: 10.14028/j.cnki.1003-3726.2018.08.019.
Sheng-de DONG, Yuan ZHOU, Chun-xi HAI. Research Progress in Modification of LiNi1-x-yCoxMnyO2 Cathode Materials for Lithium-ion Battery[J]. Polymer Bulletin, 2018,31(8):112-118. DOI: 10.14028/j.cnki.1003-3726.2018.08.019.
镍钴锰三元材料作为一种重要的锂离子电池正极材料,与钴酸锂、镍酸锂和锰酸锂相比,因其具有循环性能好、放电容量大、热稳定性好、成本低、结构比较稳定等优点受到学术界和产业界的广泛关注。目前,镍钴锰三元正极材料已经成功地应用于锂离子电池中,但也存在许多缺点,如在首次循环过程中的不可逆容量损失严重、在镍含量较高时循环性能和热稳定性变差、表面反应不均匀等,从而在一定程度上影响了锂离子电池的性能。本文主要综述了对镍钴锰三元正极材料的掺杂、包覆等改性的研究进展,并对镍钴锰三元正极材料的未来发展趋势做了展望。
LiN
1-x-y
Co
x
Mn
y
O
2
is an important cathode material for lithium-ion batteries (LIBs). Compared with lithium cobalt oxide
lithium nickel oxide and lithium manganate
LiNi
is widely concerned by the field of academia and industry due to good cycle performance
large capacity
good thermal stability
low cost
relatively stable structure and so on. At present
cathode materials have been successfully used in lithium-ion batteries
but there are also many disadvantages
such as severe irreversible capacity loss during the first cycle
the poor cyclic performance and thermal stability when the nickel content is high
uneven surface reaction
which affected the performance of lithium-ion battery. In this review
modification methods such as doping and coating are summarized
and the future development trend of LiN
materials is discussed.
锂离子电池镍钴锰三元正极材料掺杂包覆
Lithium-ion batteriesLiN1-x-yCoxMnyO2 cathode materialsDopingCoating
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