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1.南京工程学院材料科学与工程学院,南京 211167
2.江苏省先进结构材料与应用技术重点实验室,南京 211167
3.上海大学材料科学与工程学院,上海 200444
* E-mail: whisun@126.com.
纸质出版日期:2020-11-20,
收稿日期:2019-09-18,
修回日期:2020-08-17,
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怀旭, 曹洋, 王华进, 张芹, 董倩, 马浩然, 梁力. 基于CQDs的真空可见光固化体系的构建与性能研究[J]. 高分子通报, 2020,33(11):50-55.
Xu HUAI, Yang CAO, Hua-jin WANG, Qin ZHANG, Qian DONG, Hao-ran MA, Li LIANG. Construction and Performance Study of Vacuum Visible Light Curing System Based on CQDs[J]. Polymer Bulletin, 2020,33(11):50-55.
怀旭, 曹洋, 王华进, 张芹, 董倩, 马浩然, 梁力. 基于CQDs的真空可见光固化体系的构建与性能研究[J]. 高分子通报, 2020,33(11):50-55. DOI: 10.14028/j.cnki.1003-3726.2020.11.006.
Xu HUAI, Yang CAO, Hua-jin WANG, Qin ZHANG, Qian DONG, Hao-ran MA, Li LIANG. Construction and Performance Study of Vacuum Visible Light Curing System Based on CQDs[J]. Polymer Bulletin, 2020,33(11):50-55. DOI: 10.14028/j.cnki.1003-3726.2020.11.006.
采用水热法制备性能良好具有蓝色荧光特性的碳量子点(CQDs)
将CQDs与丙烯酸树脂复合
在隔绝空气条件下
构建了真空可见光固化体系
制备出CQDs复合膜。通过傅里叶变换红外光谱仪、暗箱三用紫外分析仪、扫描电镜、热重分析仪、视频接触角测定仪等仪器和吸水率、耐溶剂性试验
研究了CQDs的结构与荧光性能
CQDs复合膜的形貌、结构、热稳定性和耐水耐溶剂性能。结果表明:制备得到有蓝色荧光的CQDs
当加入0.6gCQDs时
得到表面致密的CQDs复合膜
该复合膜的吸水率为0.24%
接触角为110.13°
在150℃以下的热稳定性良好
耐溶剂性良好
具有较好的疏水效果。对固化机理进行研究
认为碳量子点具有上转换性质
能够将低能波段的可见光转换为高能波段的紫外光
进而激发光引发剂产生自由基
引发体系聚合。本文的固化配方与真空可见光固化工艺在工业方面有很高的应用潜力和价值。
Carbon quantum dots (CQDs) with good blue fluorescence properties were prepared by hydrothermal method and combined with acrylic resin. Then under vacuum conditions
a visible light curing system was constructed to prepare CQDs composite films. Next
the structure and fluorescence properties of CQDs
the morphology
structure
water and solvent resistance of CQDs composite membranes were studied by using Fourier transform infrared spectrometer
dark box three-purpose ultraviolet analyzer
scanning electron microscope
thermogravimetric analyzer
video contact angle measuring instrument and relevant test. The results show that the CQDs with blue fluorescence are prepared. When 0.6g CQDs is added
a dense CQDs composite membrane is obtained. The composite membrane has a water absorption rate of 0.24%
a contact angle of 110.13°
good thermal stability below 150℃
good solvent resistance
and good hydrophobic effect. Finally
the curing mechanism was discussed. It is believed that carbon quantum dots have up-conversion properties
which can convert visible light in the low-energy band into ultraviolet light in the high-energy band
which in turn excites photoinitiators to generate free radicals to initiate polymerization. The curing formula and vacuum visible light curing process in this paper have high application potential and value in industry.
可见光固化碳量子点上转换真空氧阻聚
Visible light curingCarbon quantum dotsUp-conversionVacuumOxygen inhibition
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