FAN Zheng-ming, YANG Yang, GUO Rong-xin, LIU Xing-yao, LIU Hui, YAN Hong-yuan. The Strain Sensing Properties of Multi-walled Carbon Nanotube/Chloroprene Rubber Composites[J]. Polymer Bulletin, 2023,36(4):466-480.
FAN Zheng-ming, YANG Yang, GUO Rong-xin, LIU Xing-yao, LIU Hui, YAN Hong-yuan. The Strain Sensing Properties of Multi-walled Carbon Nanotube/Chloroprene Rubber Composites[J]. Polymer Bulletin, 2023,36(4):466-480. DOI: 10.14028/j.cnki.1003-3726.2023.04.006.
A composite with resistance-strain response characteristics was obtained by blending multi-walled carbon nanotube (MWCNT) to modify chloroprene rubber (CR). With the increase of carbon nanotube content
the strength and stiffness of the material increased significantly. The conductive percolation threshold of MWCNT content is 4.75 wt%
and if the content exceeds this value
the MWCNT form a tunneling conductive network inside the rubber matrix
and thus the material has conductive ability. The resistance-strain response test analysis of the material under static and cyclic loading shows that when the content of MWCNT is 8 wt%
the resistance-strain response gauge factor GF>418
showing good strain sensing characteristics. With the increase of MWCNT content
GF value decreases gradually
and the stability of resistance-strain response decreases
and shoulder peak effect appears
which proves that excessive carbon nanotube content has an adverse effect on the damage and reconstruction of conductive network with deformation. Finally
the mechanism of above resistancestrain response was analyzed by digital image correlation (DIC) method and the theoretical model of electron tunneling effect.