芳纶增强MXene-聚丙烯酸-无定型碳酸钙复合水凝胶的制备及性能

左红梅; 闻立冬; 郭锦涛; 董功明; 郑皓月; 王洪杰; 王赫; 阮芳涛; 邹梨花; 徐珍珍

doi:10.14028/j.cnki.1003-3726.2024.23.221

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芳纶增强MXene-聚丙烯酸-无定型碳酸钙复合水凝胶的制备及性能

研究论文 | 更新时间：2024-01-25

- 芳纶增强MXene-聚丙烯酸-无定型碳酸钙复合水凝胶的制备及性能
- Preparation and Properties of MXene-Poly(acrylic acid)-Amorphous Calcium Carbonate Composite Hydrogel Reinforced by Aramid
- 高分子通报 2024年37卷第2期页码：257-262
- 作者机构：
  
  安徽工程大学纺织服装学院，芜湖 241000
- 作者简介：
  
  *左红梅，E-mail: zuohongmei@ahpu.edu.cn
- 基金信息：
  
  安徽工程大学引进人才科研启动基金(2021YQQ041);安徽工程大学校级科研项目(Xjky2022072);安徽工程大学本科生拔尖人才培养项目(FFBK202229;FFBK202369;FFBK202370);国家自然科学基金(51903001);安徽省自然科学基金青年基金(2208085QE141)
- DOI：10.14028/j.cnki.1003-3726.2024.23.221
  中图分类号：
- 纸质出版日期：2024-02-20，
  
  收稿日期：2023-06-29，
  
  录用日期：2023-08-09
- 稿件说明：
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引用：左红梅, 闻立冬, 郭锦涛, 董功明, 郑皓月, 王洪杰, 王赫, 阮芳涛, 邹梨花, 徐珍珍. 芳纶增强MXene-聚丙烯酸-无定型碳酸钙复合水凝胶的制备及性能. 高分子通报, 2024, 37(2), 257–262

Citation: Zuo, H. M.; Wen, L. D.; Guo, J. T.; Dong, G. M.; Zheng, H. Y.; Wang, H. J.; Wang, H.; Ruan, F. T.; Zou, L. H.; Xu, Z. Z. Preparation and properties of Mxene-poly(acrylic acid)-amorphous calcium carbonate composite hydrogel reinforced by aramid. Polym. Bull. (in Chinese), 2024, 37(2), 257–262
引用：左红梅, 闻立冬, 郭锦涛, 董功明, 郑皓月, 王洪杰, 王赫, 阮芳涛, 邹梨花, 徐珍珍. 芳纶增强MXene-聚丙烯酸-无定型碳酸钙复合水凝胶的制备及性能. 高分子通报, 2024, 37(2), 257–262 DOI： 10.14028/j.cnki.1003-3726.2024.23.221.

Citation: Zuo, H. M.; Wen, L. D.; Guo, J. T.; Dong, G. M.; Zheng, H. Y.; Wang, H. J.; Wang, H.; Ruan, F. T.; Zou, L. H.; Xu, Z. Z. Preparation and properties of Mxene-poly(acrylic acid)-amorphous calcium carbonate composite hydrogel reinforced by aramid. Polym. Bull. (in Chinese), 2024, 37(2), 257–262 DOI： 10.14028/j.cnki.1003-3726.2024.23.221.

摘要

传统水凝胶存在机械性能和可加工性差的缺点，本研究制备了芳纶增强MXene-聚丙烯酸-无定型碳酸钙(ANF/MXene-PAA-ACC)复合水凝胶，并研究了其相关力学与物理性能。首先，通过氟化锂和盐酸刻蚀法，结合超声剥离工艺制备了二维MXene单层纳米片，将其应用到PAA-ACC复合水凝胶中。为了提高MXene-PAA-ACC的力学性能，进一步通过加入芳纶，制备了ANF/MXene-PAA-ACC复合水凝胶。采用扫描电镜和万能力学试验机对复合水凝胶的表观形貌、力学性能、自修复和粘附性等物理性能进行了表征和测试。结果表明：与PAA-ACC水凝胶相比，ANF/MXene-PAA-ACC水凝胶的可加工性、力学性能、粘附性、自修复性都得到了提高。

Abstract

Traditional hydrogels have the disadvantages of poor mechanical properties and machinability. In this study

aryl-reinforced MXene-poly(acrylic acid)-amorphous calcium carbonate (ANF/MXene-PAA-ACC) composite hydrogels were prepared

and the related mechanical and physical properties were studied. Firstly

two-dimensional MXene monolayer nanosheets were prepared by the method of lithium fluoride and hydrochloric acid etching combing with ultrasonic stripping process. Then

it was added into PAA-ACC composite hydrogel. In order to improve the mechanical properties of MXene-PAA-ACC hydrogel

ANF/MXene-PAA-ACC composite hydrogel was prepared by adding aryl fiber. The appearance

mechanical properties

self-healing and adhesion properties of the ANF/MXene-PAA-ACC composite hydrogels were characterized and tested by scanning electron microscopy and universal mechanical testing machine. The results showed that compared with PAA-ACC hydrogels

the machinability

mechanical properties

adhesion and self-repair performance of ANF/MXene-PAA-ACC hydrogels were all improved.

关键词

MXene聚丙烯酸-无定型碳酸钙水凝胶芳纶

Keywords

MXenePoly(acrylic acid)-amorphous calcium carbonate hydrogelAramid fiber

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