二氧化碳基聚碳酸酯的功能化研究进展

赵晨; 王文珍; 乔红军; 刘芸; 黄庆; 李鸿玖

doi:10.14028/j.cnki.1003-3726.2024.24.009

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二氧化碳基聚碳酸酯的功能化研究进展

综述 | 更新时间：2024-09-10

- 二氧化碳基聚碳酸酯的功能化研究进展
- Research Progress on Functionalization of CO₂-based Polycarbonate
- 高分子通报 2024年37卷第9期页码：1222-1232
- 作者机构：
  
  1..陕西延长石油（集团）有限责任公司研究院，西安 710065
  2..西安石油大学化学化工学院，西安 710065
- 作者简介：
  
  *王文珍，E-mail: wzwang@xsyu.edu.cn
- 基金信息：
  
  国家自然科学基金资助项目(52073228)
- DOI：10.14028/j.cnki.1003-3726.2024.24.009
  中图分类号：
- 纸质出版日期：2024-09-20，
  
  网络出版日期：2024-04-15，
  
  收稿日期：2024-01-09，
  
  录用日期：2024-02-21
- 稿件说明：
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赵晨, 王文珍, 乔红军, 刘芸, 黄庆, 李鸿玖. 二氧化碳基聚碳酸酯的功能化研究进展. 高分子通报, 2024, 37(9), 1222–1232

Zhao, C.; Wang, W. Z.; Qiao. H. J.; Liu, Y.; Huang, Q.; Li, H. J.; Research progress on functionalization of CO₂-based polycarbonate. Polym. Bull. (in Chinese), 2024, 37(9), 1222–1232
赵晨, 王文珍, 乔红军, 刘芸, 黄庆, 李鸿玖. 二氧化碳基聚碳酸酯的功能化研究进展. 高分子通报, 2024, 37(9), 1222–1232 DOI： 10.14028/j.cnki.1003-3726.2024.24.009.

Zhao, C.; Wang, W. Z.; Qiao. H. J.; Liu, Y.; Huang, Q.; Li, H. J.; Research progress on functionalization of CO₂-based polycarbonate. Polym. Bull. (in Chinese), 2024, 37(9), 1222–1232 DOI： 10.14028/j.cnki.1003-3726.2024.24.009.

摘要

作为极具发展前景的环境友好型材料，以CO

和环氧丙烷（PO）为原料共聚制得的聚碳酸亚丙酯（PPC）已步入工业化生产，但其尚不理想的热稳定性和力学性能，很大程度上限制了该类材料的应用。另外，随着功能材料在生物学、化学、医学等领域的应用越来越广泛，人们对聚碳酸酯材料的功能性也提出了要求，对其进行功能化研究也是科学界的一个热点方向。本论文综述了具有荧光、耐紫外线老化功能、阻燃和生物特性等性能的单体作为第三单体，与CO

、PO三元共聚合成功能性聚碳酸酯的研究进展，分析了不同功能性的单体对PPC物化性能及其功能特性的影响，为丰富聚碳酸酯结构和应用领域提供重要参考。

Abstract

Polypropylene carbonate (PPC)

which is formed

via

copolymerization of carbon dioxide (CO

) and propylene oxide (PO)

is a promising environment-friendly material and is now industrially produced. However

the unsatisfactory thermal stability and mechanical properties of PPC have limited its applications. In addition

with the increased application of functional materials in biology

chemistry

medicine and other fields

the demand for the functionalization of polycarbonate materials has increased

which is a hot topic in the scientific community. This work reviews the research progress of monomers with fluorescence characteristics

UV aging resistance

flame retardant properties and biological properties

et al

. as third monomers and CO

and PO ternary copolymerization into functional polycarbonate

and analyzes the effects of different functional monomers on the physical and chemical properties and functional properties of PPC

so as to provide a reference for enriching the structure and application fields of polycarbonate.

关键词

三元共聚聚碳酸酯功能化二氧化碳转化

Keywords

Ternary copolymerizationPolycarbonateFunctionalizationConversion of carbon dioxide

references

Andrady, A. L.; Neal, M. A.Applications and societal benefits of plastics. Philos. Trans. R. Soc. Lond. B Biol. Sci., 2009, 364(1526), 1977–1984.

郑强.塑料与 “白色污染”刍议. 高分子通报, 2022, (4), 1–10.

Ellis, W. C.; Jung, Y.; Mulzer, M.; Di Girolamo, R.; Lobkovsky, E. B.; Coates, G. W.Copolymerization of CO2 and meso epoxides using enantioselective β-diiminate catalysts: a route to highly isotactic poly-carbonates. Chem. Sci., 2014, 5(10), 4004–4011.

魏伟, 孙予罕, 闻霞, 孙楠楠.二氧化碳资源化利用的机遇与挑战. 化工进展, 2011, 30(1), 216–224.

罗婧, 孙星宇, 王霞弟, 周辉, 吕小兵.CO2/顺式-2,3-环氧丁烷交替共聚物的立体寡聚物合成及微结构分析. 科学通报, 2020, 65(31), 3418–3428.

Gao, F.; Wu, T. W.; Zhang, J.; Hu, A. X.; Meehl, G. A.Shortened duration of global warming slowdowns with elevated greenhouse gas emissions. J. Meteor. Res., 2021, 35(2), 225–237.

Ai, X. E.; Studer, A. S.; Sigman, D. M.; Martínez-García, A.; Fripiat, F.; Thöle, L. M.; Michel, E.; Gottschalk, J.; Arnold, L.; Moretti, S.; Schmitt, M.; Oleynik, S.; Jaccard, S. L.; Haug, G. H.Southern ocean upwelling, earth’s obliquity, and glacial-interglacial atmospheric CO2 change. Science, 2020, 370(6522), 1348–1352.

王霞弟, 孙星宇, 罗婧, 朱晴, 周辉, 吕小兵.聚(1,4-环己二烯碳酸酯)立体低聚物的合成及微结构分析. 高分子学报, 2021, 52(10), 1316–1322.

尹静瑶, 肖敏, 王拴紧, 孟跃中.二氧化碳基聚碳酸酯二元醇末端羟基含量的测定. 高分子通报, 2023, 36(6), 713–719.

曹晓瀚, 吕俊奇, 赵佳, 张成建, 孙悦, 虞卿磊, 侯家祥, 张兴宏.氧化异丁烯与CO2共聚物的合成及其结构与性能. 高分子学报, 2022, 53(9), 1104–1111.

Tran, D. K.; Rashad, A. Z.; Darensbourg, D. J.; Wooley, K. L.Sustainable synthesis of CO2-derived polycarbonates from d-xylose. Polym. Chem., 2021, 12(37), 5271–5278.

Inoue, S.; Koinuma, H.; Tsuruta, T.Copolymerization of carbon dioxide and epoxide. J. Polym. Sci. B Polym. Lett., 1969, 7(4), 287–292.

Kember, M. R.; Copley, J.; Buchard, A.; Williams, C. K.Triblock copolymers from lactide and telechelic poly(cyclohexene carbonate). Polym. Chem., 2012, 3(5), 1196–1201.

Sulley, G. S.; Gregory, G. L.; Chen, T. T. D.; Peña Carrodeguas, L.; Trott, G.; Santmarti, A.; Lee, K. Y.; Terrill, N. J.; Williams, C. K.Switchable catalysis improves the properties of CO2-derived polymers: poly-(cyclohexene carbonate-b-ε-decalactone-b-cyclohexene carbonate) adhesives, elastomers, and toughened plastics. J. Am. Chem. Soc., 2020, 142(9), 4367–4378.

Huang, M. Y.; Gao, L. J.; Feng, J. Y.; Huang, X. Y.; Li, Z. Q.; Huang, Z. T.; Wang, L. Y.Cross-linked networks in poly(propylene carbonate) by incorporating (maleic anhydride/cis-1,2,3,6-tetrahydrophthalic anhydride) oligomer in CO2/propylene oxide copolymerization: improving and tailoring thermal, mechanical, and di-mensional properties. ACS Omega, 2020, 5(28), 17808–17817.

Zheng, L.; Liu, K. C.; Wang, Y. Q.; Fan, A.Ternary copolymerization of supercritical CO2, propylene oxide and maleic anhydride. Mater. Sci., 2017, 23(4), 350–355.

李永超, 孟祥宇, 崔学强, 王亭, 史颖, 刘立志, 宋立新.马来酸酐接枝聚乳酸增容聚碳酸亚丙酯/聚乳酸共混体系的结构与性能研究. 塑料科技, 2021, 49(6), 7–10.

翟微, 孙健健, 王博华, 滕冲, 谢时宇, 郝凤昊, 靳玉娟.胺端基型超支化乙二胺三嗪聚合物对PLA/PPC的增韧改性研究. 中国塑料, 2020, 34(6), 27–33.

Zhang, H. X.; Chen, J. W.; Cui, X. H.; Hu, Y. X.; Lei, L. C.; Zhu, Y. T.; Jiang, W.Thermal annealing induced enhancement of electrical properties of a co-continuous polymer blend filled with carbon nanotubes. Compos. Sci. Technol., 2018, 167, 522–528.

Enriquez, E.; Mohanty, A. K.; Misra, M.Biobased blends of poly(propylene carbonate) and poly(hyd-roxybutyrate-co-hydroxyvalerate): Fabrication and characterization. J. Appl. Polym. Sci., 2017, 134(5), e44420.

谢东, 张超灿, 王献红, 赵晓江, 王佛松.不同分子量聚丙撑碳酸酯的封端及热分解. 武汉理工大学学报, 2007, 29(8), 5–9.

Nörnberg, B.; Luinstra, G. A.Influence of norbornene dicarboxylic anhydride on the copolymerization of carbon dioxide and propylene oxide. Eur. Polym. J., 2015, 73, 297–307.

张亦乐, 王文珍, 李磊磊, 张凯悦.二氧化碳与环氧丙烷三元聚合研究进展. 高分子通报, 2021, (8), 19–25.

Liang, J. X.; Ye, S. X.; Wang, W. J.; Fan, C. X.; Wang, S. J.; Han, D. M.; Liu, W.; Cui, Y.; Hao, L. M.; Xiao, M.; Meng, Y. Z.Performance tailorable terpolymers synthesized from carbon dioxide, phthalic anhydride and propylene oxide using Lewis acid-base dual catalysts. J. CO2Util., 2021, 49, 101558.

樊丛笑, 梁嘉欣, 叶淑娴, 朱泳澜, 王拴紧, 孟跃中, 肖敏.不同序列结构的二氧化碳/环氧丙烷/邻苯二甲酸酐三元共聚物的可控合成及性能研究. 高分子学报, 2022, 53(5), 497–504.

朱祺东, 石佳, 宋煌旺, 赵洁, 颜慧琼, 王向辉, 史载锋, 韩艾龙, 林强, 朱林华.球磨Zn-CoDMC催化二氧化碳、环氧丙烷和琥珀酸酐的三元共聚反应及热稳定性. 功能材料, 2017, 48(8), 8175–8180.

Niu, Y. S.; Li, H. C.Terpolymerization of carbon dioxide with propylene oxide and γ-butyrolactone catalyzed by SalenCoIII(2,4-dinitrophenoxy) and Lewis-basic cocatalyst. Adv. Polym. Technol., 2018, 37(1), 230–234.

王献红.二氧化碳捕集和利用.北京: 化学工业出版社, 2016.

Luo, L.; Wang, W. Z.; Wang, L.; Li, L. L.; Zhang, Y. L.; Zhao, S. D.Copolymerization of CO2, propylene oxide, and itaconic anhydride with double metal cyanide complex catalyst to form crosslinked polypropylene carbonate. e-Polymers, 2021, 21(1), 854–868.

Scharfenberg, M.; Hilf, J.; Frey, H.Functional polycarbonates from carbon dioxide and tailored epoxide monomers: degradable materials and their application potential. Adv. Funct. Mater., 2018, 28(10), 1704302.

Łukaszczyk, J.; Jaszcz, K.; Kuran, W.; Listos, T.Synthesis of functional polycarbonates by copolymerization of carbon dioxide with allyl glycidyl ether. Macromol. Rapid Commun., 2000, 21(11), 754–757.

Amsden, B.In vivo degradation mechanisms of aliphatic polycarbonates and functionalized aliphatic polycar-bonates. Macromol. Biosci., 2021, 21(7), 2100085.

武照强, 孟令芝.荧光聚合物研究进展. 化学进展, 2007, 19(9), 1381–1392.

Chen, S.; Slattum, P.; Wang, C. Y.; Zang, L.Self-assembly of perylene imide molecules into 1D nano-structures: methods, morphologies, and applications. Chem. Rev., 2015, 115(21), 11967–11998.

Franciscato Campo, L.; Severo Rodembusch, F.; Stefani, V.New fluorescent monomers and polymers displaying an intramolecular proton-transfer mechanism in the electronically excited state (ESIPT). IV. Synthesis of acryloylamide and diallylamino benzazole dyes and its copolymerization with MMA. J. Appl. Polym. Sci., 2006, 99(5), 2109–2116.

Yang, W. C.; Schmerr, M. J.; Jackman, R.; Bodemer, W.; Yeung, E. S.Capillary electrophoresis-based non-competitive immunoassay for the prion protein using fluorescein-labeled protein A as a fluorescent probe. Anal. Chem., 2005, 77(14), 4489–4494.

王文珍, 赵晨, 刘芸, 李磊磊, 贾新刚.一种用于检测Fe3+的聚合物荧光探针及其制备方法和应用. 中国专利, CN116589674A, 2023-08-15.

Wang, E. H.; Liu, S. J.; Lam, J. W. Y.; Tang, B. Z.; Wang, X. H.; Wang, F. S.Deciphering structure-functionality relationship of polycarbonate-based polyelectrolytes by AIE technology. Macromolecules, 2020, 53(14), 5839–5846.

Roy, D.; Brooks, W. L. A.; Sumerlin, B. S.New directions in thermoresponsive polymers. Chem. Soc. Rev., 2013, 42(17), 7214–7243.

Weng, C.; Fan, N. Q.; Xu, T. R.; Chen, H. D.; Li, Z. F.; Li, Y. W.; Tan, H.; Fu, Q.; Ding, M. M.FRET-based polymer materials for detection of cellular micro-environments. Chin. Chem. Lett., 2020, 31(6), 1490–1498.

Xian, C. H.; Yuan, Q. J.; Bao, Z. T.; Liu, G. T.; Wu, J.Progress on intelligent hydrogels based on RAFT polymerization: design strategy, fabrication and the applications for controlled drug delivery. Chin. Chem. Lett., 2020, 31(1), 19–27.

Zhang, Y. J.; Furyk, S.; Bergbreiter, D. E.; Cremer, P. S.Specific ion effects on the water solubility of macromolecules: PNIPAM and the Hofmeister series. J. Am. Chem. Soc., 2005, 127(41), 14505–14510.

Ramos, J.; Imaz, A.; Forcada, J.Temperature-sensitive nanogels: poly(N-vinylcaprolactam) versus poly(N-isopropylacrylamide). Polym. Chem., 2012, 3(4), 852–856.

Hwang, M. J.; Suh, J. M.; Bae, Y. H.; Kim, S. W.; Jeong, B.Caprolactonic poloxamer analog: PEG-PCL-PEG. Biomacromolecules, 2005, 6(2), 885–890.

Wang, M. L.; Wang, E. H.; Cao, H.; Liu, S. J.; Wang, X. H.; Wang, F. S.Construction of self-reporting biodegradable CO2-based polycarbonates for the visualization of thermoresponsive behavior with aggregation-induced emission technology. Chin. J. Chem., 2021, 39(11), 3037–3043.

Fadil, O. B.; Hashim, A.Fabrication and tailored optical characteristics of CeO2/SiO2 nanostructures doped PMMA for electronics and optics fields. Silicon, 2022, 14(15), 9845–9852.

Hashim, A.Enhanced morphological, optical and electronic characteristics of WC NPs doped PVP/PEO for flexible and lightweight optoelectronics applications. Opt. Quantum Electron., 2021, 53(8), 478.

Hashim, A.; Abbas, M. H.; Al-Aaraji, N. A. H.; Hadi, A.Controlling the morphological, optical and dielectric characteristics of PS/SiC/CeO2 nanostructures for nano-electronics and optics fields. J. Inorg. Organomet. Polym. Mater., 2023, 33(1), 1–9.

Rukmanikrishnan, B.; Ramalingam, S.; Rajasekharan, S. K.; Lee, J.; Lee, J.Binary and ternary sustainable composites of gellan gum, hydroxyethyl cellulose and lignin for food packaging applications: biocompatibility, antioxidant activity, UV and water barrier properties. Int. J. Biol. Macromol., 2020, 153, 55–62.

Obaid, W. O.; Hashim, A.Synthesis and augmented optical properties of PC/SiC/TaC hybrid nanostructures for potential and photonics fields. Silicon, 2022, 14(17), 11199–11207.

Huang, Q.; Wang, W. Z.; Liu, S.; Jia, X. G.; Xia, L.; Qin, F. L.; Wang, Q.; Liu, Y.; Li, H. J.Green fabrication of carbon dioxide-based polycarbonates with durable antimicrobial properties and UV resistance. Chem. Eng. J., 2023, 477, 147107.

蔡毅, 郭洪辰, 曹瀚, 高凤翔, 周庆海, 王献红.耐紫外光老化CO2共聚物的合成与性能. 应用化学, 2019, 36(11), 1248–1256.

Wang, W. Z.; Zhang, X. M.; Han, W. W.; Huang, J.; Zhang, Y. L.; Zhao, C.; Li, L. L.A one-pot strategy for the preparation of fire-retardant poly(propylene carbonate) by terpolymerization of CO2, propylene oxide and chlorendic anhydride. Mater. Today Commun., 2023, 34, 105179.

Liu, N. Z.; Gu, C. H.; Wang, Q. H.; Zhu, L. H.; Yan, H. Q.; Lin, Q.Fabrication and characterization of the ternary composite catalyst system of ZnGA/RET/DMC for the terpolymerization of CO2, propylene oxide and trimellitic anhydride. RSC Adv., 2021, 11(15), 8782–8792.

Beharaj, A.; McCaslin, E. Z.; Blessing, W. A.; Grinstaff, M. W.Sustainable polycarbonate adhesives for dry and aqueous conditions with thermoresponsive properties. Nat. Commun., 2019, 10(1), 5478.

Cui, S. Q.; Qin, Y. S.; Li, Y. B.Sustainable approach for the synthesis of biopolycarbonates from carbon dioxide and soybean oil. ACS Sustain. Chem. Eng., 2017, 5(10), 9014–9022.

Liu, G. L.; Wu, H. W.; Lin, Z. I.; Liao, M. G.; Su, Y. C.; Chen, C. K.; Ko, B. T.Synthesis of functional CO2-based polycarbonates via dinuclear nickel nitro-phenolate-based catalysis for degradable surfactant and drug-loaded nanoparticle applications. Polym. Chem., 2021, 12(9), 1244–1259.

Chiarioni, G.; van Duin, M.; Pescarmona, P. P.Novel elastic rubbers from CO2-based polycarbonates. Green Chem., 2023, 25(19), 7612–7626.

陆新宇, 马彬泽, 罗皓, 齐欢, 李强, 伍广朋.二氧化碳基聚碳酸环己撑酯电子束光刻胶显影工艺优化. 应用化学, 2021, 38(9), 1189–1198.

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