木质素基聚合物微球的制备及其光热转化性能研究

顾子龙; 王贝诺; 顾佳阳; 安志杭; 张涛; 马学所; 黄凌琪; 盛仲夷; 刘赫扬

doi:10.14028/j.cnki.1003-3726.2024.24.079

您当前的位置：

首页 >

文章列表页 >

木质素基聚合物微球的制备及其光热转化性能研究

研究论文 | 更新时间：2024-09-10

- 木质素基聚合物微球的制备及其光热转化性能研究
- Preparation of Lignin-based Polymer Microspheres and Study on Solar Photothermal Conversion Properties
- 高分子通报 2024年37卷第9期页码：1291-1299
- 作者机构：
  
  1..浙江科技大学环境与资源学院，杭州 310023
  2..浙江科技大学生物与化学工程学院，杭州 310023
  3..杭州曦茂新材料科技有限公司，杭州 311300
  4..天津大学材料与科学工程学院，天津 300072
- 作者简介：
  
  *盛仲夷，E-mail: shengzyhz@aliyun.com
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2024.24.079
  中图分类号：
- 纸质出版日期：2024-09-20，
  
  网络出版日期：2024-05-31，
  
  收稿日期：2024-03-21，
  
  录用日期：2024-05-09
- 稿件说明：
移动端阅览
顾子龙, 王贝诺, 顾佳阳, 安志杭, 张涛, 马学所, 黄凌琪, 盛仲夷, 刘赫扬. 木质素基聚合物微球的制备及其光热转化性能研究. 高分子通报, 2024, 37(9), 1291–1299

Gu, Z. L.; Wang, B. N.; Gu, J. Y.; An, Z. H.; Zhang, T.; Ma, X. S.; Huang, L. Q.; Sheng Z. Y.; Liu, H. Y. Preparation of lignin-based polymer microspheres and study on solar photothermal conversion properties. Polym. Bull. (in Chinese), 2024, 37(9), 1291–1299
顾子龙, 王贝诺, 顾佳阳, 安志杭, 张涛, 马学所, 黄凌琪, 盛仲夷, 刘赫扬. 木质素基聚合物微球的制备及其光热转化性能研究. 高分子通报, 2024, 37(9), 1291–1299 DOI： 10.14028/j.cnki.1003-3726.2024.24.079.

Gu, Z. L.; Wang, B. N.; Gu, J. Y.; An, Z. H.; Zhang, T.; Ma, X. S.; Huang, L. Q.; Sheng Z. Y.; Liu, H. Y. Preparation of lignin-based polymer microspheres and study on solar photothermal conversion properties. Polym. Bull. (in Chinese), 2024, 37(9), 1291–1299 DOI： 10.14028/j.cnki.1003-3726.2024.24.079.

摘要

利用溶剂热反应将木质素引入到四氟对苯二甲腈和咪唑反应体系中，制备了具有光热转化性能的聚合物微球材料。研究分析了材料宽共轭分子结构对光捕捉的作用。光热测试结果表明，材料在1 kW/m

太阳光辐照下30 s内升温到~58 ℃；在多次光开关响应下，光热转化性能稳定，能够实现热量的可控释放。另外，还通过对聚合物微球在细菌纤维素的负载，制备了更具实用性的光热转化材料，为水蒸发器提供了材料基础。

Abstract

Solvothermal has been used to develop lignin-based polymeric microspheres that are excellently suited for solar photothermal conversion. The materials show excellent light-absorbing performance throughout the solar spectrum

due to the large conjugated structure. As expected

the solar photothermal conversion test shows that a significant temperature increasing from room temperature to about 58 ℃ can be achieved within 30 s under simulated solar radiation (1 kW/m

). Meanwhile

the materials provide a satisfactory photothermal response during the cycling stability measurement. In addition

a composite aerogel material was prepared for practical photothermal conversion application based on solvothermal treatment in the presence of bacterial cellulose. The composite material proposed could have great potential for applications in the field of water harvesting.

关键词

木质素溶剂热反应聚合物微球光热转化

Keywords

LigninSolvothermalPolymer microspheresPhotothermal conversion

references

符林霞, 冯奕钰, 封伟. 具有光热存储与释放功能的偶氮苯侧链接枝聚降冰片烯. 高分子学报, 2019, 50(12), 1272–1279.

Xiong, Z. C.; Zhu, Y. J.; Qin, D. D.; Yang, R. L.Flexible salt-rejecting photothermal paper based on reduced graphene oxide and hydroxyapatite nanowires for high-efficiency solar energy-driven vapor generation and stable desalination. ACS Appl. Mater. Interfaces, 2020, 12(29), 32556–32565.

Yang, L.; Lu, X. L.; Wang, Z. H.; Xia, H. S.Diels-Alder dynamic crosslinked polyurethane/polydopamine composites with NIR triggered self-healing function. Polym. Chem., 2018, 9(16), 2166–2172.

Shou, Q. H.; Uto, K.; Iwanaga, M.; Ebara, M.; Aoyagi, T.Near-infrared light-responsive shape-memory poly(ɛ-caprolactone) films that actuate in physiological temperature range. Polym. J., 2014, 46(8), 492–498.

Wen, K. K.; Wu, L. F.; Wu, X. X.; Lu, Y.; Duan, T.; Ma, H.; Peng, A. D.; Shi, Q. Q.; Huang, H.Precisely tuning photothermal and photodynamic effects of polymeric nanoparticles by controlled copolymerization. Angew. Chem. Int. Ed., 2020, 59(31), 12756–12761.

Hao, C. B.; Wei, C.; Wang, Y. J.; Sun, Z. C.; Liu, H.; Dai, R. X.; Huang, M. M.; He, S. Q.; Liu, W. T.; Zhu, C. S.Thermal/near-infrared light dual-responsive reversible two-way shape memory cEVA/2D-MoO2 composite for multifunctional applications. Macromol. Rapid Commun., 2021, 42(11), 2100056.

陈宇超, 沙畅畅, 王心妤, 王文举. 基于光热转换的吸收材料与转换机理研究进展. 能源研究与利用, 2019, 55(4), 23–31.

Cui, X. M.; Ruan, Q. F.; Zhuo, X. L.; Xia, X. Y.; Hu, J. T.; Fu, R. F.; Li, Y.; Wang, J. F.; Xu, H. X.Photothermal nanomaterials: a powerful light-to-heat converter. Chem. Rev., 2023, 123(11), 6891–6952.

Liu, D. N.; Li, W.; Jiang, X. Y.; Bai, S. J.; Liu, J. Y.; Liu, X. T.; Shi, Y. H.; Kuai, Z. Y.; Kong, W.; Gao, R. J.; Shan, Y. M.Using near-infrared enhanced thermozyme and scFv dual-conjugated Au nanorods for detection and targeted photothermal treatment of Alzheimer's disease. Theranostics, 2019, 9(8), 2268–2281.

Chen, J. Y.; Cao, M. L.; Yue, Y. Y.A lignin-based carbonized electrospinning membrane with strong light absorption and hierarchical superhydrophilicity for seawater desalination. Sci. China Mater., 2024, 67(3), 954–964.

Li, J.; Zou, S. F.; Deng, C.; Na, B.; Zhang, S.; Lin, S.; Wang, B.A supramolecular polymer hybrid membrane with superior photothermal properties for local heating applications. Polymer, 2021, 213, 123211.

Hu, X.; Zheng, X. J.; Li, Y.; Zhang, J.; Ma, D. K.Cu2PO4OH: controlled synthesis of various architectures and morphology-dependent 808 nm laser-driven photothermal performance. J. Alloys Compd., 2017, 695, 561–566.

Fan, Q. P.; Su, W. Y.; Guo, X.; Zhang, X.; Xu, Z.; Guo, B.; Jiang, L.; Zhang, M.; Li, Y.A 1,1’-vinylene-fused indacenodithiophene-based low bandgap polymer for efficient polymer solar cells. J. Mater. Chem. A, 2017, 5(10), 5106–5114.

Lei, J. J.; Chen, L. H.; Lin, J. X.; Liu, W. F.; Xiong, Q. G.; Qiu, X. Q.Mechanism study of the photothermal function of lignin: the effect of electron-withdrawing groups. Green Chem., 2024, 26(4), 2143–2156.

Liu, H. Y.; Chen, H. S.; Shi, K. Y.; Zhang, F.; Xiao, S. W.; Huang, L. Q.; Zhu, H.Lignin-derived porous carbon for zinc-ion hybrid capacitor. Ind. Crops Prod., 2022, 187, 115519.

Huang, L. Q.; Gu, Z. L.; He, W. Q.; Shi, K. Y.; Peng, L. F.; Sheng, Z. Y.; Zhang, F.; Feng, W.; Liu, H. Y.Solvothermal synthesis and pyrolysis toward heteroatom-doped carbon microspheres for zinc-ion hybrid capacitors. Small, 2024, 20(14), e2308788.

Zhang, M.; Zhou, Q. Y.; Luo, H.; Tang, Z. L.; Xu, X. F.; Wang, X. C.C3-cyanation of pyridines: Constraints on electrophiles and determinants of regioselectivity. Angew. Chem. Int. Ed., 2023, 62(6), e202216894.

Huerta, E. R.; Muddasar, M.; Collins, M. N.Enzymatic hydrolysis lignin and kraft lignin from birch wood: a source of functional bio-based materials. Wood Sci. Technol., 2024, 58(2), 423–440.

Dong, S. S.; Shao, W. Z.; Yang, L.; Ye, H. J.; Zhen, L.Surface characterization and degradation behavior of polyimide films induced by coupling irradiation treatment. RSC Adv., 2018, 8(49), 28152–28160.

Casalongue, H. S.; Kaya, S.; Viswanathan, V.; Miller, D. J.; Friebel, D.; Hansen, H. A.; Nørskov, J. K.; Nilsson, A.; Ogasawara, H.Direct observation of the oxygenated species during oxygen reduction on a platinum fuel cell cathode. Nat. Commun., 2013, 4, 2817.

Jia, J.; Liang, W. D.; Sun, H. X.; Zhu, Z. Q.; Wang, C. J.; Li, A.Fabrication of bilayered attapulgite for solar steam generation with high conversion efficiency. Chem. Eng. J., 2019, 361, 999–1006.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

木质素碳纤维研究进展

纺丝法制备木质素基碳纤维的研究进展

木质素及其在高分子材料方面的利用课程教学方法与实践

微波辅助高效降解木质素转化酚类化合物的研究进展

木质素模型化合物的裂解工艺及机理的研究进展