基于动态化学键的脱粘可控型胶粘剂的研究进展

张紫怡; 徐海兵; 刘东; 颜春; 陈刚; 祝颖丹

doi:10.14028/j.cnki.1003-3726.2024.24.192

您当前的位置：

首页 >

文章列表页 >

基于动态化学键的脱粘可控型胶粘剂的研究进展

综述 | 更新时间：2024-12-12

- 基于动态化学键的脱粘可控型胶粘剂的研究进展
- Research Progress of Controllable Debonding Adhesives Based on Dynamic Covalent Bonds
- 高分子通报 2024年37卷第12期页码：1722-1730
- 作者机构：
  
  1.宁波大学材料科学与化学工程学院，宁波 315211
  2.中国科学院宁波材料技术与工程研究所浙江省机器人与智能制造装备技术重点实验室，宁波 315201
- 作者简介：
  
  *徐海兵，E-mail: xuhaibing@nimte.ac.cn；祝颖丹，E-mail: y.zhu@nimte.ac.cn
  *徐海兵，E-mail: xuhaibing@nimte.ac.cn；祝颖丹，E-mail: y.zhu@nimte.ac.cn
- 基金信息：
  
  国家自然科学基金(U23A2067);宁波市科技创新2025重大专项(2022Z102)
- DOI：10.14028/j.cnki.1003-3726.2024.24.192
  中图分类号：
- 纸质出版日期：2024-12-20，
  
  网络出版日期：2024-08-28，
  
  收稿日期：2024-07-01，
  
  录用日期：2024-08-07
- 稿件说明：
移动端阅览
张紫怡, 徐海兵, 刘东, 颜春, 陈刚, 祝颖丹. 基于动态化学键的脱粘可控型胶粘剂的研究进展. 高分子通报, 2024, 37(12), 1722–1730

Zhang, Z. Y.; Xu, H. B.; Liu, D.; Yan, C.; Chen, G.; Zhu, Y. D. Research progress of controllable debonding adhesives based on dynamic covalent bonds. Polym. Bull. (in Chinese), 2024, 37(12), 1722–1730
张紫怡, 徐海兵, 刘东, 颜春, 陈刚, 祝颖丹. 基于动态化学键的脱粘可控型胶粘剂的研究进展. 高分子通报, 2024, 37(12), 1722–1730 DOI： 10.14028/j.cnki.1003-3726.2024.24.192.

Zhang, Z. Y.; Xu, H. B.; Liu, D.; Yan, C.; Chen, G.; Zhu, Y. D. Research progress of controllable debonding adhesives based on dynamic covalent bonds. Polym. Bull. (in Chinese), 2024, 37(12), 1722–1730 DOI： 10.14028/j.cnki.1003-3726.2024.24.192.

摘要

热固性胶粘剂具有优异的粘接性能、电绝缘性能、耐化学、耐高温等特性，在汽车、电子、风力发电、航空航天等领域得到广泛应用，但其固化后形成的三维交联网络结构也使得粘接部件二次拆解困难，为粘接部件的快速拆解、维修、回收造成困难。在胶粘剂交联网络结构中引入动态化学键形成共价自适应网络，可在特定的条件刺激下实现胶粘剂交联网络的可逆断裂，从而实现可控脱粘。人们已经在基于动态化学键的可控脱粘型胶粘剂方面开展了大量研究工作，开发了一系列基于动态化学键的脱粘可控型胶粘剂。本文主要介绍了当前基于动态化学键的脱粘可控型胶粘剂的研究进展，重点阐述了可控拆解型胶粘剂设计制备的基本原理，总结了不同类型可控拆解型胶粘剂结构与性能的关系，并展望了脱粘可控型胶粘剂的发展趋势及面临的挑战。

Abstract

Thermosetting adhesives have the characteristics of excellent bonding properties

electrical insulation properties

chemical resistance

heat and high temperature resistance

and are widely used in automotive

electronics

power generation

aerospace and other fields. However

the three-dimensional cross-linked networks make thermosetting adhesives insoluble and non-melting

thus leading to the difficulties of rapid disassembling

maintaining and even recycling the bonded components or parts. Dynamic covalent bonds can be introduced into the cross-linked networks of adhesives to form covalent adaptable networks

which can result in reversible fracture of cross-linked networks under specific conditions

thereby achieving controllable debonding. Many studies have been carried out in the field of controllable debonding adhesives based on dynamic covalent bonds

and a series of new adhesives based on dynamic covalent bonds have been developed. This review mainly introduces the current research progress of controllable debonding adhesives based on dynamic covalent bonds

especially focuses on the basic principle of the design and preparation of these adhesives

summarizes the relationship between covalent adaptable network structures and properties of different types of controllable debonding adhesives

and looks forward to their development trends and challenges.

关键词

胶粘剂粘接性能动态化学键共价自适应交联网络可控脱粘

Keywords

AdhesivesAdhesive propertiesDynamic covalent bondCovalent adaptable networksControllable debonding

references

聂振宇, 韩璐, 姜政阳, 阚成友. 环氧树脂胶粘剂化学改性方法研究进展. 中国胶粘剂, 2024, 33(2), 22–27.

Xu, G.; Li, S.; Liu, C.; Wu, S. Photoswitchable adhesives using azobenzene‐containing materials. J. Chem. Asian J., 2020, 15(5), 547–554.

董忍娥, 孙琳琳, 乔勋, 马吉胜. 一种新型环保非异氰酸酯聚氨酯丙烯酸酯胶粘剂性能初探. 高分子通报, 2019, (6), 36–44.

杜郢, 周太炎, 王哲, 任筱芳, 蔡晓燕. 酚醛树脂胶粘剂的复合改性. 高分子通报, 2012, (2), 79–83.

Mazzotta, M. G.; Putnam, A. A.; North, M. A.; Wilker, J. J. Weak bonds in a biomimetic adhesive enhance toughness and performance. J. Am. Chem. Soc., 2020, 142(10), 4762–4768.

李栓, 张宝艳, 张思, 霍红宇, 王伟翰. 酚醛环氧树脂改性环氧胶粘剂的耐热性能研究. 化工新型材料, 2023, 51(1), 272–275.

赵秀丽, 周琳, 陈茂. 在温和条件下可快速拆解的热固性材料的制备及拆解方法. 中国专利, CN201710187457.1,2017-07-14.

Heinzmann, C.; Coulibaly, S.; Roulin, A.; Fiore, G. L.; Weder, C. Light-induced bonding and debonding with supramolecular adhesives. ACS Appl. Mater. Interfaces, 2014, 6(7), 4713–4719.

Caglar, H.; Idapalapati, S.; Sharma, M.; Chian, K. S. Debonding of carbon fiber veil interleaved adhesively bonded GFRP joints via Joule heating. Compos. Part B Eng., 2022, 230, 109544.

Hutchinson, A.; Liu, Y.; Lu, Y. Overview of disbonding technologies for adhesive bonded joints. J. Adhes., 2017, 93(10), 737–755.

Srinivasan, D. V.; Idapalapati, S. Review of debonding techniques in adhesively bonded composite structures for sustainability. Sustain. Mater. Technol., 2021, 30, e00345.

Bandl, C.; Kern, W.; Schlögl, S. Adhesives for “debonding-on-demand”: triggered release mechanisms and typical applications. Int. J. Adhes. Adhes., 2020, 99, 102585.

Kloxin, C. J.; Scott, T. F.; Adzima, B. J.; Bowman, C. N. Covalent adaptable networks (CANs): a unique paradigm in crosslinked polymers. Macromolecules, 2010, 43(6), 2643–2653.

帅茂兵, 郭亚昆, 赵鹏翔, 仲敬荣, 徐对功, 杨晓娇, 常凤雯, 岳国宗, 陈林. 一种可快速拆解的环氧胶粘剂及其制备和拆解方法.中国专利, CN201610113331.5, 2016-06-22.

Aubert, J. H. Note: thermally removable epoxy adhesives incorporating thermally reversible Diels-Alder adducts. J. Adhes., 2003, 79(6), 609–616.

Kavitha, A. A.; Singha, N. K. “click chemistry” in tailor-made polymethacrylates bearing reactive furfuryl functionality: a new class of self-healing polymeric material. ACS Appl. Mater. Interfaces, 2009, 1(7), 1427–1436.

Wouters, M.; Burghoorn, M.; Ingenhut, B.; Timmer, K.; Rentrop, C.; Bots, T.; Oosterhuis, G.; Fischer, H. Tuneable adhesion through novel binder technologies. Prog. Org. Coat., 2011, 72(1-2), 152–158.

Turkenburg, D. H.; van Bracht, H.; Funke, B.; Schmider, M.; Janke, D.; Fischer, H. R. Polyurethane adhesives containing Diels-Alder-based thermoreversible bonds. J. Appl. Polym. Sci., 2017, 134(26), 44972.

闵玉勤, 洪佳丽, 宋明明, 黄伟, 王浩仁, 张兴宏. 热可移除型环氧树脂胶粘剂的制备及其性能研究. 粘接, 2017, 38(6), 27–31.

Das, S.; Samitsu, S.; Nakamura, Y.; Yamauchi, Y.; Payra, D.; Kato, K.; Naito, M. Thermo-resettable cross-linked polymers for reusable/removable adhesives. Polym. Chem., 2018, 9(47), 5559–5565.

Sridhar, L. M.; Oster, M. O.; Herr, D. E.; Gregg, J. B. D.; Wilson, J. A.; Slark, A. T. Re-usable thermally reversible crosslinked adhesives from robust polyester and poly(ester urethane) Diels-Alder networks. Green Chem., 2020, 22(24), 8669–8679.

Cudjoe, E.; Herbert, K. M.; Rowan, S. J. Strong, rebondable, dynamic cross-linked cellulose nanocrystal polymer nanocomposite adhesives. ACS Appl. Mater. Interfaces, 2018, 10(36), 30723–30731.

Zhou, L.; Chen, M.; Zhao, X. L. Rapid degradation of disulfide-based thermosets through thiol-disulfide exchange reaction. Polymer, 2017, 120, 1–8.

Michal, B. T.; Spencer, E. J.; Rowan, S. J. Stimuli-responsive reversible two-level adhesion from a structurally dynamic shape-memory polymer. ACS Appl. Mater. Interfaces, 2016, 8(17), 11041–11049.

徐锡威. 可回收热固性环氧树脂的合成、表征及应用. 杭州: 浙江工业大学, 2020.

Montarnal, D.; Capelot, M.; Tournilhac, F.; Leibler, L. Silica-like malleable materials from permanent organic networks. Science, 2011, 334(6058), 965–968.

徐亚洲, 张海波, 毕良武, 蒋建新, 陈玉湘. 基于酯交换反应的生物基类玻璃高分子的研究进展. 热固性树脂, 2023, 38(2), 47–54.

He, M.; Huang, Y.; Sun, J.; Dan, Y.; Zhao, W.; Jiang, L. Dynamic crosslinked poly(acrylic acid-co-acrylonitrile)/polyethylene glycol networks as reworkable adhesives. J. React. Funct. Polym., 2022, 176, 105283.

刘澍鑫. 基于硼酸酯交换可逆共价网络聚合物的制备及性能. 桂林: 桂林理工大学, 2020.

Zeng, Y. N.; Liu, S. X.; Xu, X. M.; Chen, Y.; Zhang, F. A. Fabrication and curing properties of o-cresol formaldehyde epoxy resin with reversible cross-links by dynamic boronic ester bonds. Polymer, 2020, 211, 123116.

Li, C.; Chen, Y. Z.; Zeng, Y.; Wu, Y. C.; Liu, W. D.; Qiu, R. H. Strong and recyclable soybean oil-based epoxy adhesives based on dynamic borate. Eur. Polym. J., 2022, 162, 110923.

王署亮. 高强度、可拆卸、自修复的动态交联聚肟氨酯热熔胶. 上海: 东华大学, 2020.

周雅维, 李平, 韩金石, 魏玮, 李小杰, 刘晓亚. 基于氨基甲酸肟酯键制备可拆卸UV固化胶黏剂. 功能高分子学报, 2022, 35(3), 252–260.

Wang, S. L.; Liu, Z. H.; Zhang, L. Z.; Guo, Y. F.; Song, J. C.; Lou, J. M.; Guan, Q. B.; He, C. L.; You, Z. W. Strong, detachable, and self-healing dynamic crosslinked hot melt polyurethane adhesive. Mater. Chem. Front., 2019, 3(9), 1833–1839.

Liu, W. W.; Zhang, C.; Bai, Y. P. Reversible adhesive based on self-repair behavior. J. Adhes. Sci. Technol., 2021, 35(2), 111–132.

Wang, R. M.; Xie, T. Shape memory- and hydrogen bonding-based strong reversible adhesive system. Langmuir, 2010, 26(5), 2999–3002.

Yang, Z. Y.; Bai, T. T.; Li, T.; Sha, X. L.; Ji, X. T.; Yang, Y. X.; Wang, P. G.; Zhang, H. M.; Wang, Y. Q. Dense H-bonding enhanced bio-based supramolecular adhesive: high adhesive strength and multi-reusability. ACS Appl. Polym. Mater., 2024, 6(14), 8142–8149.

Liu, J. H.; Huang, Y. S.; Liu, Y. Z.; Zhang, D. C.; Koynov, K.; Butt, H. J.; Wu, S. Reconfiguring hydrogel assemblies using a photocontrolled metallopolymer adhesive for multiple customized functions. Nat. Chem., 2024, 16(6), 1024–1033.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

贻贝仿生胶粘剂研究进展