抗菌聚合物结构色微球的制备及性能

陶伟晗; 方寅春

doi:10.14028/j.cnki.1003-3726.2024.24.234

您当前的位置：

首页 >

文章列表页 >

抗菌聚合物结构色微球的制备及性能

研究论文 | 更新时间：2025-01-06

- 抗菌聚合物结构色微球的制备及性能
- Preparation and Properties of Antibacterial Polymer Structural Color Microspheres
- 高分子通报 2025年38卷第1期页码：109-115
- 作者机构：
  
  安徽工程大学纺织服装学院，芜湖 241000
- 作者简介：
  
  *方寅春，E-mail: fangyinchun86@163.com
- 基金信息：
  
  聚合物分子工程国家重点实验室(复旦大学)开放基金项目(K2024-12);安徽工程大学校级科研项目(Xjky2022061)
- DOI：10.14028/j.cnki.1003-3726.2024.24.234
  中图分类号：
- 收稿日期：2024-08-14，
  
  录用日期：2024-10-07，
  
  网络出版日期：2024-11-07，
  
  纸质出版日期：2025-01-20
- 稿件说明：
移动端阅览
陶伟晗, 方寅春. 抗菌聚合物结构色微球的制备及性能. 高分子通报, 2025, 38(1), 109–115.

Tao, W. H.; Fang, Y. C. Preparation and properties of antiacterial polymer structural color microspheres. Polym. Bull. (in Chinese), 2025, 38(1), 109–115.
陶伟晗, 方寅春. 抗菌聚合物结构色微球的制备及性能. 高分子通报, 2025, 38(1), 109–115. DOI： 10.14028/j.cnki.1003-3726.2024.24.234.

Tao, W. H.; Fang, Y. C. Preparation and properties of antiacterial polymer structural color microspheres. Polym. Bull. (in Chinese), 2025, 38(1), 109–115. DOI： 10.14028/j.cnki.1003-3726.2024.24.234.

摘要

采用无皂乳液聚合方法，以甲基丙烯酸甲酯(MMA)、苯乙烯(St)和丙烯酰氧乙基三甲基氯化铵(DAC)，合成不同粒径的P(St-MMA-DAC)聚合物微球，通过雾化沉积法在涤纶织物上制备结构色。对P(St-MMA-DAC)聚合物微球及结构色织物进行了红外光谱、扫描电镜、粒径、反射光谱和抗菌性能测试。结果表明，通过改变合成过程中单体比例可以得到不同粒径的P(St-MMA-DAC)聚合物微球，可在涤纶织物上形成蓝色、粉红色、绿色、青色和紫色5种不同颜色的结构色。结构色织物对大肠杆菌(

E. coli

)和金黄色葡萄球菌(

S. aureus

)的抑菌率可达到98%以上，表现出优异的抗菌性能。本文为功能性聚合物微球开发及在纺织、医疗卫生等领域的应用提供了研究基础。

Abstract

P(St-MMA-DAC) polymer microspheres with different particle sizes were synthesized by soap free emulsion polymerization using methyl methacrylate (MMA)

styrene (St) and acryloxyethyl trimethylammonium chloride (DAC). The structural colors were formed on polyester fabric by atomization deposition of these P(St-MMA-DAC) polymer microspheres. Infrared spectroscopy

scanning electron microscopy

particle size

reflectance spectroscopy

and antibacterial performance tests were conducted on P(St-MMA-DAC) polymer microspheres and structural color fabrics. The results indicate that P(St-MMA-DAC) polymer microspheres with different particle sizes can be obtained by changing the monomer ratios during the synthesis process

which can form five different structural colors of blue

pink

green

cyan

and purple on polyester fabrics. The antibacterial rates of structural c

olor fabrics against

Escherichia coli

(

E. coli

) and

Staphylococcus aureus

(

S. aureus

) can reach over 98%

showing excellent antibacterial properties. This study provides a research basis for the development of functional polymer microspheres and their application in textile

medical and health fields.

关键词

Keywords

references

谢京励 , 邓旭 . 基于裂纹生长的胶体颗粒自组装结构色纤维 . 四川轻化工大学学报(自然科学版) , 2020 , 33 ( 3 ), 7 – 12 .

郭彦丽 , 刘建才 , 王艳红 , 徐海兵 , 祝颖丹 , 陈刚 . 结构色纤维的研究进展 . 印染 , 2016 , 42 ( 14 ), 47 – 50 .

陈佳颖 , 辛斌杰 , 辛三法 , 杜卫平 , 许颖琦 , 高伟洪 . 基于光子晶体的结构色织物研究进展 . 纺织学报 , 2020 , 41 ( 4 ), 181 – 187 .

Hou, X. Y. ; Li, F. Z. ; Song, Y. L. ; Li, M. Z . Recent progress in responsive structural color . J. Phys. Chem. Lett. , 2022 , 13 ( 13 ), 2885 – 2900 .

Liu, F. F. ; Tao, C. A. ; Tang, B. T . Recent advances in environmentally friendly structural colored fabrics . Text. Res. J. , 2023 , 93 ( 7-8 ), 1861 – 1877 .

Xu, C. L. ; Huang, C. X. ; Huang, H. H . Recent advances in structural color display of cellulose nanocrystal materials . Appl. Mater. Today , 2021 , 22 , 100912 .

Liu, D. G. ; Wang, S. ; Ma, Z. S. ; Tian, D. L. ; Gu, M. Y. ; Lin, F. Y . Structure-color mechanism of iridescent cellulose nanocrystal films . RSC Adv. , 2014 , 4 ( 74 ), 39322 – 39331 .

吴玉江 , 刘国金 , 李义臣 , 邵建中 , 周岚 . 二氧化硅光子晶体在涤纶织物上的结构生色 . 纺织学报 , 2015 , 36 ( 10 ), 62 – 66 .

Liu, G. J. ; Zhou, L. ; Wang, C. C. ; Wu, Y. J. ; Li, Y. C. ; Fan, Q. G. ; Shao, J. Z . Study on the high hydrophobicity and its possible mechanism of textile fabric with structural colors of three-dimensional poly(styrene-methacrylic acid) photonic crystals . RSC Adv. , 2015 , 5 ( 77 ), 62855 – 62863 .

Yavuz, G. ; Felgueiras, H. P. ; Ribeiro, A. I. ; Seventekin, N. ; Zille, A. ; Souto, A. P . Dyed poly(styrene-methyl methacrylate-acrylic acid) photonic nanocrystals for enhanced structural color . ACS Appl. Mater. Interfaces , 2018 , 10 ( 27 ), 23285 – 23294 .

Yu, C. Y. ; Wang, X. R. ; Wang, Y. ; Shi, D. J. ; Dong, W. F. ; Zhou, L. ; Liu, G. J. ; Zhang, H. J . Patternable structural color prepared by using photonic crystal paints with high solid content . Colloids Surf. A Physicochem. Eng. Aspects , 2021 , 627 , 127212 .

Liu, Y. ; Hu, J . Investigation of polystyrene-based microspheres from different copolymers and their structural color coatings on wood surface . Coatings , 2020 , 11 ( 1 ), 14 .

张之悦 , 高伟洪 , 朱婕 , 杨树 , 辛斌杰 , 杜卫平 . 功能性结构色纳米纺织材料的研究进展 . 毛纺科技 , 2022 , 50 ( 1 ), 118 – 124 .

Gu, Z. Z. ; Uetsuka, H. ; Takahashi, K. ; Nakajima, R. ; Onishi, H. ; Fujishima, A. ; Sato, O . Structural color and the lotus effect . Angew. Chem. Int. Ed. , 2003 , 42 ( 8 ), 894 – 897 .

Shi, X. D. ; He, J. L. ; Lu, X. H . Functional structural color dye with excellent UV protection property . Dyes Pigm. , 2020 , 175 , 108142 .

Sha, D. S. ; Sun, Y. R. ; Xing, L. L. ; Chen, X. P. ; Wang, X. Y. ; Wan, B. X. ; Wang, X. R. ; Li, Y. C. ; Chen, G. Q. ; Zhou, S. Q. ; Xing, T. L . Preparation of polyphenol-structural colored silk fabrics with bright colors . Int. J. Biol. Macromol. , 2024 , 266 , 131140 .

Wang, C. ; Liang, Z. H. ; Song, F. ; Wang, X. L. ; Wang, Y. Z . Surface engineering toward self-cleaning and color-fastness photonic textiles . J. Clean. Prod. , 2024 , 468 , 143029 .

翟丽莎 , 王宗垒 , 周敬伊 , 高冲 , 陈凤翔 , 徐卫林 . 纺织用抗菌材料及其应用研究进展 . 纺织学报 , 2021 , 42 ( 09 ): 170 – 179 .

林松 , 杨荆泉 , 田涛 , 郝丽梅 , 吴金辉 , 祁建城 . 高分子季铵盐抗菌材料研究进展 . 高分子通报 , 2012 , ( 5 ), 55 – 60 .

Gao, L. X. ; Tang, A. ; Bi, W. L. ; Zhu, Z. J. ; Tian, Y . Three-in-one: saturated, UV-protective and anti-bacterial structural colored textiles . Colloids Surf. A Physicochem. Eng. Aspects , 2024 , 684 , 133180 .

Shi, X. D. Cao, X. X. Dou, R. M. Lu, X. H . Structural color modified fabrics with excellent antibacterial property . J. Donghua Univ. (Engl. Ed.) , 2021 , 38 ( 5 ), 404 – 411 .

王晓辉 , 刘国金 , 邵建中 . 纺织品仿生结构生色 . 纺织学报 , 2021 , 42 ( 12 ), 1 – 14 .

Wang, C. H. ; Hou, G. G. ; Du, Z. Z. ; Cong, W. ; Sun, J. F. ; Xu, Y. Y. ; Liu, W. S . Synthesis, characterization and antibacterial properties of polyurethane material functionalized with quaternary ammonium salt . Polym. J. , 2016 , 48 ( 3 ), 259 – 265 .

Wang, Y. L. ; Du, J. ; Guo, H. Y. ; Liu, R. M. ; Li, Z. Y. ; Yang, T. Y. ; Ai, J. Z. ; Liu, C. B . The antibacterial activity and mechanism of polyurethane coating with quaternary ammonium salt . J. Polym. Res. , 2022 , 29 ( 2 ), 47 .

张智嘉 , 韩晓军 . 抗菌聚合物的研究进展 . 高分子通报 , 2018 , ( 3 ), 1 – 11 .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

功能性非异氰酸酯聚氨酯的研究进展

非异氰酸酯聚氨酯的合成与功能性研究进展

木质素基聚合物微球的制备及其光热转化性能研究

抗菌细菌纤维素功能材料的制备及应用研究进展