聚硼硅氮烷的合成、元素掺杂及其衍生SiBCN陶瓷的应用

曾冠杰; 赵泱中; 张健宁; 宋育杰

doi:10.14028/j.cnki.1003-3726.2025.25.049

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聚硼硅氮烷的合成、元素掺杂及其衍生SiBCN陶瓷的应用

综述 | 更新时间：2025-06-25

- 聚硼硅氮烷的合成、元素掺杂及其衍生SiBCN陶瓷的应用
- Synthesis, Elemental Doping of Polyborosilazane and Applications of the Resulting SiBCN Ceramics
- 高分子通报 2025年38卷第7期页码：1073-1092
- 作者机构：
  
  1.宁波杭州湾新材料研究院，宁波 315336
  2.中国科学院宁波材料技术与工程研究所，宁波 315201
- 作者简介：
  
  songyujie@nimte.ac.cn
- 基金信息：
  
  国家自然科学基金(52203019);国家重点研发计划(2021YFB3200500)
- DOI：10.14028/j.cnki.1003-3726.2025.25.049
  中图分类号：
- 收稿日期：2025-02-14，
  
  录用日期：2025-03-25，
  
  网络出版日期：2025-05-30，
  
  纸质出版日期：2025-07-20
- 稿件说明：
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曾冠杰, 赵泱中, 张健宁, 宋育杰. 聚硼硅氮烷的合成、元素掺杂及其衍生SiBCN陶瓷的应用. 高分子通报, 2025, 38(7), 1073–1092.

Zeng, G, J.; Zhao, Y. Z.; Zhang, J. N.; Song, Y. J. Synthesis, elemental doping of polyborosilazane and applications of the resulting SiBCN ceramics. Polym. Bull. (in Chinese), 2025, 38(7), 1073–1092.
曾冠杰, 赵泱中, 张健宁, 宋育杰. 聚硼硅氮烷的合成、元素掺杂及其衍生SiBCN陶瓷的应用. 高分子通报, 2025, 38(7), 1073–1092. DOI： 10.14028/j.cnki.1003-3726.2025.25.049.

Zeng, G, J.; Zhao, Y. Z.; Zhang, J. N.; Song, Y. J. Synthesis, elemental doping of polyborosilazane and applications of the resulting SiBCN ceramics. Polym. Bull. (in Chinese), 2025, 38(7), 1073–1092. DOI： 10.14028/j.cnki.1003-3726.2025.25.049.

摘要

聚合物前驱体转化法推动了SiBCN陶瓷在高温结构材料、功能涂层、热管理材料和高温传感器等领域的应用发展。通过前驱体聚硼硅氮烷分子结构的设计改性可以实现对SiBCN陶瓷微观组分和结构的调控。本文综述了SiBCN陶瓷前驱体聚硼硅氮烷的合成方法、异质元素掺杂路线以及前驱体转化SiBCN陶瓷的成型和应用，探讨了前驱体分子结构、异质元素与SiBCN陶瓷微观结构之间的关系。最后，总结了聚硼硅氮烷及其衍生SiBCN陶瓷在现阶段研究中存在的问题，并结合未来需求展望了发展方向。

Abstract

The polymer precursor conversion method has propelled the development of SiBCN ceramics in various fields including high-temperature structural materials

functional coatings

thermal management materials

and high-temperature sensors. The design of the molecular structure of the precursor polysilazane enables the regulation of the microstructure and composition of SiBCN ceramics. This review summarizes the synthesis methods of SiBCN ceramic precursors (polysilazanes)

doping routes of heteroatoms

and processing and applications of SiBCN ceramics. It also explores the relationship between the molecular structure of the precursor

heteroatoms

and the microstructure of the resulting SiBCN ceramics. Finally

the current challenges in the research on polysilazanes and their derived SiBCN ceramics are summarized

and potential future directions are discussed in light of future demands.

关键词

Keywords

references

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