聚乙炔导电材料的研究进展

程渝斐; 范望喜

doi:10.14028/j.cnki.1003-3726.2025.25.190

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聚乙炔导电材料的研究进展

综述 | 更新时间：2025-10-30

- 聚乙炔导电材料的研究进展
- Research Progress of Polyacetylene Conductive Materials
- 高分子通报 2025年38卷第11期页码：1591-1603
- 作者机构：
  
  江苏理工学院化学化工学院，常州 213001
- 作者简介：
  
  E-mail: fwx@jsut.edu.cn
- 基金信息：
  
  江苏省大学生创新创业训练项目(S202511463034)
- DOI：10.14028/j.cnki.1003-3726.2025.25.190
  中图分类号：
- 收稿：2025-07-17，
  
  录用：2025-08-31，
  
  网络出版：2025-10-14，
  
  纸质出版：2025-11-20
- 稿件说明：
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程渝斐, 范望喜. 聚乙炔导电材料的研究进展. 高分子通报, 2025, 38(11), 1591-1603.

Cheng, Y. F.; Fan, W. X. Research progress of polyacetylene conductive materials. Polym. Bull. (in Chinese), 2025, 38(11), 1591-1603.
程渝斐, 范望喜. 聚乙炔导电材料的研究进展. 高分子通报, 2025, 38(11), 1591-1603. DOI： 10.14028/j.cnki.1003-3726.2025.25.190.

Cheng, Y. F.; Fan, W. X. Research progress of polyacetylene conductive materials. Polym. Bull. (in Chinese), 2025, 38(11), 1591-1603. DOI： 10.14028/j.cnki.1003-3726.2025.25.190.

摘要

聚乙炔(polyacetylene，PA)是首个被发现的导电聚合物，其衍生物在有机电子领域一直占据重要地位。为了弥补PA在应用中存在的稳定性差与导电性低的缺陷，近年来研究人员创造了许多共聚、催化的新方法和改性手段，有效降低了其在空气中的降解速率，使其热稳定性得到了显著提高(其分解温度由80 ℃提高到了150 ℃)。同时，掺杂体系从传统的无机掺杂体系拓展到新型有机-无机掺杂体系，将掺杂聚乙炔的电导率由1.7×10

−9

S/cm提高到了1.8×10

S/cm，使其后续在新能源电池材料、智能穿戴、机器人传感等领域的应用具有广阔的市场前景。

Abstract

Polyacetylene (PA)

the first discovered conductive polymer

and its derivatives have long held a significant position in organic electronics. To address the shortcomings of poor stability and low electrical conductivity that limit PA applications

researchers have developed numerous novel copolymerization

catalysis

and modification techniques in recent years. These methods effectively reduced the degradation rate of polyacetylene in air and significantly improved its thermal stability (its decomposition temperature increased from 80 ℃ to 150 ℃). Meanwhile

the doping system has expanded from traditional inorganic doping systems to new organic-inorganic doping systems

increasing the conductivity of doped polyacetylene from 1.7×10

−9

S/cm to 1.8×10

S/cm

making its subsequent applications in new energy battery materials

intelligent wearables

robot sensing

and other fields have broad market prospects.

关键词

Keywords

references

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