四川大学高分子科学与工程学院 成都 610065
*冉蓉,E-mail: ranrong@scu.edu.cn
收稿:2025-10-20,
录用:2025-12-17,
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崔为, 黄华东, 刘正英, 肖明, 冉蓉. Lake-Thomas理论:高分子断裂能本质的教学深化与拓展. 高分子通报, doi: 10.14028/j.cnki.1003-3726.2025.25.306
Cui, W.; Huang, H. D.; Liu, Z. Y.; Xiao, M.; Ran, R. The Lake–Thomas theory: pedagogical deepening and extension on the molecular essence of polymer fracture energy. Polym. Bull. (in Chinese), doi: 10.14028/j.cnki.1003-3726.2025.25.306
崔为, 黄华东, 刘正英, 肖明, 冉蓉. Lake-Thomas理论:高分子断裂能本质的教学深化与拓展. 高分子通报, doi: 10.14028/j.cnki.1003-3726.2025.25.306 DOI:
Cui, W.; Huang, H. D.; Liu, Z. Y.; Xiao, M.; Ran, R. The Lake–Thomas theory: pedagogical deepening and extension on the molecular essence of polymer fracture energy. Polym. Bull. (in Chinese), doi: 10.14028/j.cnki.1003-3726.2025.25.306 DOI:
断裂韧性是高分子材料的重要力学性能,直接决定其在实际使用过程中的承载极限与服役寿命。Lake-Thomas理论作为高分子断裂力学中最具代表性的经典模型,从分子尺度揭示了橡胶及弹性体材料断裂韧性的物理本质。尽管该理论在高分子断裂研究中具有里程碑意义,其在现行“高分子物理”课程教学中尚鲜见系统引入,难以引导学生从化学键能和分子结构层面理解宏观断裂机理。教学实践表明,学生在学习完高分子材料的应力–应变行为后,普遍对极限断裂的分子机制产生强烈兴趣。本研究以Lake-Thomas理论为主线,系统梳理其发展脉络,重构其推导逻辑,并结合双网络水凝胶等复杂体系,探讨其适用边界与扩展模型。通过橡胶撕裂实验的教学案例,展示如何在课堂中以“发明者视角”引导学生从能量观出发理解分子链断裂的本质,从而深化其对高分子材料断裂行为的理解,促进理论与实践的有机结合,提升综合分析与创新思维能力。
Fracture toughness is a crucial mechanical property of polymer materials
directly determining their load-bearing limits and service lifetimes in practical applications. As one of the most representative classical models in polymer fracture mechanics
the Lake-Thomas theory elucidates the molecular origin of toughness in rubbers and elastomers. Despite its landmark significance in polymer fracture research
this theory has not yet been systematically incorporated into the current teaching of “Polymer Physics”
making it difficult for students to understand macroscopic fracture mechanisms from the perspective of chemical bond energy and molecular structure. Teaching practice shows that after studying the stress-strain behavior of polymers
students exhibit strong curiosity about the molecular mechanism underlying the ultimate fracture. Taking the Lake-Thomas theory as the central theme
this paper systematically reviews its historical development
reconstructs its derivation logic
and explores its application and extended models in complex polymer systems such as double-network hydrogels. Through a teaching case based on rubber-tear experiments
this study demonstrates how adopting an “inventor’s perspective” in the classroom can guide students to understand the energetic essence of molecular chain rupture
thereby deepening their comprehension of polymer fracture behavior
promoting the integration of theoretical knowledge with practical application
and enhancing their analytical and innovative thinking abilities.
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