柔性超级电容器的原位快速集成及应用——高分子综合实验项目设计

刘汉超; 单雪影; 李锦春

doi:10.14028/j.cnki.1003-3726.2026.25.329

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柔性超级电容器的原位快速集成及应用——高分子综合实验项目设计

教育与教学 | 更新时间：2026-05-11

- 柔性超级电容器的原位快速集成及应用——高分子综合实验项目设计
- In Situ Rapid Integration and Applications of Flexible Supercapacitors——Design of a Comprehensive Polymer Experiment Project
- 高分子通报 2026年
- 作者机构：
  
  常州大学材料科学与工程学院　常州 213164
  常州大学安全科学与工程学院　常州 213164
- 作者简介：
  
  lijinchun88@163.com
- 基金信息：
  
  江苏省高等学校教育信息化研究课题(2023JSETKT051)
- DOI：10.14028/j.cnki.1003-3726.2026.25.329
  中图分类号：
- 收稿：2025-11-12，
  
  录用：2026-03-16，
- 稿件说明：
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刘汉超, 单雪影, 李锦春. 柔性超级电容器的原位快速集成及应用：高分子综合实验项目设计. 高分子通报, doi: 10.14028/j.cnki.1003-3726.2026.25.329

Liu, H. C.; Shan, X. Y.; Li, J. C. In situ rapid integration and applications of flexible supercapacitors—design of a comprehensive polymer experiment project. Polym. Bull. (in Chinese), doi: 10.14028/j.cnki.1003-3726.2026.25.329
刘汉超, 单雪影, 李锦春. 柔性超级电容器的原位快速集成及应用：高分子综合实验项目设计. 高分子通报, doi: 10.14028/j.cnki.1003-3726.2026.25.329 DOI：

Liu, H. C.; Shan, X. Y.; Li, J. C. In situ rapid integration and applications of flexible supercapacitors—design of a comprehensive polymer experiment project. Polym. Bull. (in Chinese), doi: 10.14028/j.cnki.1003-3726.2026.25.329 DOI：

摘要

针对传统超级电容器制备过程复杂、耗时较长、难以在有限课时内完成的问题，设计了一项面向高分子专业的综合性实验项目——“柔性超级电容器的原位快速集成及应用”。实验利用醛胺缩合反应实现了反应体系的快速凝胶化，在室温下5 min内完成溶胶—凝胶转变，并通过原位集成构建超级电容器，最高比电容达105.4 F/g，显著提升了教学效率。实验内容涵盖水凝胶合成、器件组装、性能测试及应用演示，融合了高分子化学、高分子物理与电化学等多学科知识。通过合理的实施方案，培养了学生的动手能力、分析能力与跨学科思维，增强了学生对学科前沿的认知，取得了良好的教学效果。

Abstract

To overcome the drawbacks of conventional supercapacitor preparation

which involves complicated and time-consuming procedures that are difficult to complete within limited class hours

a comprehensive laboratory project entitled “

in situ

rapid integration and applications of flexible supercapacitors” is developed for undergraduate students majoring

in polymer science and engineering. The experiment employs aldehyde-amine condensation to achieve rapid sol-gel transition within 5 min at room temperature

and the supercapacitor is further constructed

via

in situ

integration

delivering a specific capacitance of up to 105.4 F/g

which greatly improves the efficiency of experimental teaching. The project covers hydrogel synthesis

device assembly

performance measurement and application demonstration

integrating interdisciplinary knowledge of polymer chemistry

polymer physics and electrochemistry. Through systematic implementation

students’ practical skills

analytical ability and interdisciplinary thinking are cultivated

and the understanding of cutting-edge developments in related fields is enhanced

demonstrating favorable teaching effects.

关键词

Keywords

references

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Molahalli, V. ; Chaithrashree, K. ; Singh, M. K. ; Agrawal, M. ; Krishnan, S. G. ; Hegde, G . Past decade of supercapacitor research—lessons learned for future innovations . J. Energy Storage , 2023 , 70 , 108062 .

伍红雨 , 肖海 , 曾向东 , 赵晓昱 . 导电水凝胶材料研究进展及在超级电容器的应用 . 材料导报 , 2024 , 38 ( 19 ), 238 – 245 .

Wan, X. J. ; Song, H. Q. ; Hu, F. ; Xu, B. ; Wu, Z. Y. ; Wang, J. W . Highly stable flexible supercapacitors enabled by dual-network polyampholyte hydrogel without additional electrolyte additives . Chem. Eng. J. , 2023 , 458 , 141460 .

牛丽丽 , 张丽 , 王培 , 刘彦彬 , 张彦 , 樊静 . 改进型综合化学实验设计: 聚苯胺导电水凝胶的制备与表征 . 高分子通报 , 2022 , ( 9 ), 74 – 80 .

Gao, C. X. ; Gao, Z. C. ; Wei, Y. Q. ; Luo, N. ; Liu, Y. ; Huo, P. F . Flexible wood enhanced poly(acrylic acid- co -acrylamide)/quaternized gelatin hydrogel electrolytes for high-energy-density supercapacitors . ACS Appl. Mater. Interfaces , 2023 , 15 ( 2 ), 2951 – 2960 .

Lin, X. B. ; Wang, M. Y. ; Zhao, J. C. ; Wu, X. F. ; Xie, J. X. ; Yang, J. H . Super-tough and self-healable all-cellulose-based electrolyte for fast degradable quasi-solid-state supercapacitor . Carbohydr. Polym. , 2023 , 304 , 120502 .

王萍银 , 李亮亮 , 陈涛 , 田瑶珠 . 自修复高分子材料用于柔性电子器件的研究进展 . 高分子通报 , 2020 , ( 11 ), 31 – 37 .

Chen, Y. X. ; Wu, G. C. ; Chen, B. B. ; Qu, H. ; Jiao, T. Y. ; Li, Y. T. ; Ge, C. Q. ; Zhang, C. ; Liang, L. X. ; Zeng, X. Q. ; Cao, X. Y. ; Wang, Q. ; Li, H . Self-assembly of a purely covalent cage with homochirality by imine formation in water . Angew. Chem. Int. Ed. , 2021 , 60 ( 34 ), 18815 – 18820 .

Tong, W. J. ; Gao, C. Y. ; Möhwald, H . Manipulating the properties of polyelectrolyte microcapsules by glutaraldehyde cross-linking . Chem. Mater. , 2005 , 17 ( 18 ), 4610 – 4616 .

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