Komiyama, T. ; Minami, Y. ; Hiyama, T . Recent advances in transition-metal-catalyzed synthetic transformations of organosilicon reagents . ACS Catal. , 2017 , 7 ( 1 ), 631 – 651 .

张柯 , 陈祝安 , 黄光英 , 晏彩先 , 常桥稳 , 左川 . 硅氢加成反应用均相铂催化剂研究进展 . 贵金属 , 2024 , 45 ( 3 ), 93 – 101 .

Ye, F. ; Xu, Z. ; Xu, L. W . The discovery of multifunctional chiral P ligands for the catalytic construction of quaternary carbon/silicon and multiple stereogenic centers . Acc. Chem. Res. , 2021 , 54 ( 2 ), 452 – 470 .

黄伟升 , 徐利文 . 高效构建四取代双硅基联烯的1,3-烯炔类1,4-硅氢化反应 . 有机化学 , 2021 , 41 ( 11 ), 4515 – 4516 .

Wang, H. L. ; Zhang, X. G. ; Li, Y. ; Xu, L. W . Siloxane-based organosilicon materials in electrochemical energy storage devices . Angew. Chem. Int. Ed. , 2022 , 61 ( 49 ), e202210851 .

Rémond, E. ; Martin, C. ; Martinez, J. ; Cavelier, F . Silicon-containing amino acids: synthetic aspects, conformational studies, and applications to bioactive peptides . Chem. Rev. , 2016 , 116 ( 19 ), 11654 – 11684 .

Ramesh, R. ; Reddy, D. S . Quest for novel chemical entities through incorporation of silicon in drug scaffolds . J. Med. Chem. , 2018 , 61 ( 9 ), 3779 – 3798 .

Marciniec, B . Hydrosilylation: a comprehensive review on recent advances . Springer , 2009 .

Reboli, M. ; Durandetti, M . A comprehensive review of intramolecular hydrosilylation of alkynes and alkenes . ChemCatChem , 2025 , 17 ( 10 ), e202402136 .

Yang, H. ; Zhou, Z. J. ; Tang, C. H. ; Chen, F . Recent advances in heterogeneous hydrosilylation of unsaturated carbon-carbon bonds . Chin. Chem. Lett. , 2024 , 35 ( 6 ), 109257 .

Behera, R. R. ; Saha, R. ; Kumar, A. A. ; Sethi, S. ; Jana, N. C. ; Bagh, B . Hydrosilylation of terminal alkynes catalyzed by an air-stable manganese–NHC complex . J. Org. Chem. , 2023 , 88 ( 13 ), 8133 – 8149 .

Zhang, J. Y. ; Lu, B. ; Meng, L. P. ; Li, X. Y . Theoretical investigations on reactivity influencing factors of ˙Mn(CO) 5 catalyzed alkyne hydrosilylation and hydrogermylation . New J. Chem. , 2023 , 47 ( 5 ), 2436 – 2443 .

Li, Q. Q. ; Huo, S. H. ; Meng, L. P. ; Li, X. Y . Mechanism and origin of the stereoselectivity of manganese-catalyzed hydrosilylation of alkynes: a DFT study . Catal. Sci. Technol. , 2022 , 12 ( 8 ), 2649 – 2658 .

Liang, H. ; Ji, Y. X. ; Wang, R. H. ; Zhang, Z. H. ; Zhang, B . Visible-light-initiated manganese-catalyzed E-selective hydrosilylation and hydrogermylation of alkynes . Org. Lett. , 2019 , 21 ( 8 ), 2750 – 2754 .

Ghaffari, B. ; Mendes-Burak, J. ; Chan, K. W. ; Copéret, C . Silica-supported MnII sites as efficient catalysts for carbonyl hydroboration, hydrosilylation, and transesterification . Chem. Eur. J. , 2019 , 25 ( 61 ), 13869 – 13873 .

Mukhopadhyay, T. K. ; Ghosh, C. ; Flores, M. ; Groy, T. L. ; Trovitch, R. J . Hydrosilylation of aldehydes and formates using a dimeric manganese precatalyst . Organometallics , 2017 , 36 ( 18 ), 3477 – 3483 .

Sommer, L. H. ; Pietrusza, E. W. ; Whitmore, F. C . Peroxide-catalyzed addition of trichlorosilane to 1-octene . J. Am. Chem. Soc. , 1947 , 69 ( 1 ), 188 .

Mirghaffari, L. ; Hosseininezhad, S. ; Seydi, M. ; Ramazani, A. ; Ahankar, H. ; Zhang, G. Y . Recent progress of platinum and rhodium catalysts in hydrosilylation reactions . ChemistrySelect , 2025 , 10 ( 18 ), e202501079 .

Troegel, D. ; Stohrer, J . Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view . Coord. Chem. Rev. , 2011 , 255 ( 13-14 ), 1440 – 1459 .

Liu, D. S. ; Liu, B. Y. ; Pan, Z. X. ; Li, J. F. ; Cui, C. M . Rare-earth metal catalysts for alkene hydrosilylation . Sci. China Chem. , 2019 , 62 ( 5 ), 571 – 582 .

Katayama, N. ; Obora, Y . Recent developments in alkene hydrosilylation utilizing manganese catalysts . Tetrahedron Lett. , 2023 , 132 , 154798 .

熊竹君 , 李凤仪 , 邓锋杰 . 硅氢加成反应催化机理的研究进展 . 有机硅材料 , 2006 , 20 ( 6 ), 312 – 318 .

刘珠 , 刘晓暄 , 洪鹏 , 丁小卫 , 黄梓英 , 杨先君 , 李卓尘 , 向洪平 . 硅氢加成用铂催化剂的研究进展 . 有机硅材料 , 2019 , 33 ( 3 ), 202 – 214 .

Zhang, X. P. ; Fang, J. K. ; Cai, C. ; Lu, G. P . Recent advances in synthesis of organosilicons via radical strategies . Chin. Chem. Lett. , 2021 , 32 ( 4 ), 1280 – 1292 .

Cruz, T. F. C. ; Veiros, L. F. ; Gomes, P. T . Hydrosilylation of aldehydes and ketones catalyzed by a 2-iminopyrrolyl alkyl-manganese(Ⅱ) complex . Inorg. Chem. , 2022 , 61 ( 2 ), 1195 – 1206 .

Putzien, S. ; Nuyken, O. ; Kühn, F. E . Functionalized polysilalkylene siloxanes (polycarbosiloxanes) by hydrosilylation: catalysis and synthesis . Prog. Polym. Sci. , 2010 , 35 ( 6 ), 687 – 713 .

Sabourault, N. ; Mignani, G. ; Wagner, A. ; Mioskowski, C . Platinum oxide (PtO 2 ): a potent hydrosilylation catalyst . Org. Lett. , 2002 , 4 ( 13 ), 2117 – 2119 .

Tian, D. L. ; Wang, J. ; Huang, X. H. ; Ding, Y. ; Hu, A. G . Understanding broad polydispersity in step-growth polymerization via catalyst competition mechanism . Chinese J. Polym. Sci. , 2024 , 42 ( 12 ), 1897 – 1904 .

Abdellah, L. ; Boutevin, B. ; Youssef, B . Synthesis and applications of photocrosslinkable poly(siloxanes) . Prog. Org. Coat. , 1994 , 23 ( 3 ), 201 – 236 .

Naga, N. ; Oda, E. ; Toyota, A. ; Horie, K. ; Furukawa, H . Tailored synthesis and fundamental characterization of organic-inorganic hybrid gels by means of a hydrosilylation reaction . Macromol. Chem. Phys. , 2006 , 207 ( 6 ), 627 – 635 .

Naga, N. ; Kihara, Y. ; Miyanaga, T. ; Furukawa, H . Synthesis of organic-inorganic hybrid gels from siloxane or silsesquioxane and α , ω -nonconjugated dienes by means of a photo hydrosilylation reaction . Macromolecules , 2009 , 42 ( 10 ), 3454 – 3462 .

Lligadas, G. ; Callau, L. ; Ronda, J. C. ; Galià, M. ; Cádiz, V . Novel organic-inorganic hybrid materials from renewable resources: hydrosilylation of fatty acid derivatives . J. Polym. Sci. Part A Polym. Chem. , 2005 , 43 ( 24 ), 6295 – 6307 .

Hofmann, R. J. ; Vlatković, M. ; Wiesbrock, F . Fifty years of hydrosilylation in polymer science: a review of current trends of low-cost transition-metal and metal-free catalysts, non-thermally triggered hydrosilylation reactions, and industrial applications . Polymers , 2017 , 9 ( 10 ), 534 .

Tondreau, A. M. ; Atienza, C. C. H. ; Weller, K. J. ; Nye, S. A. ; Lewis, K. M. ; Delis, J. G. P. ; Chirik, P. J . Iron catalysts for selective anti-Markovnikov alkene hydrosilylation using tertiary silanes . Science , 2012 , 335 ( 6068 ), 567 – 570 .

Sunada, Y. ; Noda, D. ; Soejima, H. ; Tsutsumi, H. ; Nagashima, H . Combinatorial approach to the catalytic hydrosilylation of styrene derivatives: catalyst systems composed of organoiron (0) or (Ⅱ) precursors and isocyanides . Organometallics , 2015 , 34 ( 12 ), 2896 – 2906 .

Chen, C. ; Hecht, M. B. ; Kavara, A. ; Brennessel, W. W. ; Mercado, B. Q. ; Weix, D. J. ; Holland, P. L . Rapid, regioconvergent, solvent-free alkene hydrosilylation with a cobalt catalyst . J. Am. Chem. Soc. , 2015 , 137 ( 41 ), 13244 – 13247 .

Marciniec, B. ; Kownacka, A. ; Kownacki, I. ; Hoffmann, M. ; Taylor, R . Hydrosilylation vs . dehydrogenative silylation of styrene catalysed by iron(0) carbonyl complexes with multivinylsilicon ligands –mechanistic implications . J. Organomet. Chem. , 2015 , 791 , 58 – 65 .

Jakubek, V. ; Lees, A. J . Quantitative photochemistry of Cp'Pt(CH 3 ) 3 (Cp'= η 5 -C 5 H 4 CH 3 ) in solution:  a highly efficient organometallic photoinitiator for hydrosilylation . Inorg. Chem. , 2004 , 43 ( 22 ), 6869 – 6871 .

de Vekki, D. A . Hydrosilylation on photoactivated catalysts . Russ. J. Gen. Chem. , 2011 , 81 ( 7 ), 1480 – 1492 .

Wei, Y. H. ; Han, S. B. ; Kim, J. ; Soh, S. ; Grzybowski, B. A . Photoswitchable catalysis mediated by dynamic aggregation of nanoparticles . J. Am. Chem. Soc. , 2010 , 132 ( 32 ), 11018 – 11020 .

华修芳 , 李川阳 , 崔冬梅 . 硅氢化聚合的研究进展 . 高分子通报 , 2016 , 29 ( 9 ), 203 – 226 .

Marro, E. A. ; Klausen, R. S . Conjugated polymers inspired by crystalline silicon . Chem. Mater. , 2019 , 31 ( 7 ), 2202 – 2211 .

Marciniec, B. ; Maciejewski, H. ; Pawluć, P . Hydrosilylation of carbon-carbon multiple bonds: application in synthesis and materials science . Organosilicon Compounds. , 2017 , 169 – 217 .

Nakajima, Y. ; Shimada, S . Hydrosilylation reaction of olefins: recent advances and perspectives . RSC Adv. , 2015 , 5 ( 26 ), 20603 – 20616 .

Du, X. Y. ; Huang, Z . Advances in base-metal-catalyzed alkene hydrosilylation . ACS Catal. , 2017 , 7 ( 2 ), 1227 – 1243 .

Sun, J. ; Deng, L . Cobalt complex-catalyzed hydrosilylation of alkenes and alkynes . ACS Catal. , 2016 , 6 ( 1 ), 290 – 300 .

Zaranek, M. ; Pawluc, P . Markovnikov hydrosilylation of alkenes: how an oddity becomes the goal . ACS Catal. , 2018 , 8 ( 10 ), 9865 – 9876 .

Sun, W. ; Hu, M. Y. ; Lu, Z. S. ; Huang, M. Y. ; Zhang, X. Y. ; Zhu, S. F . Iron-catalyzed stereoconvergent 1,4-hydrosilylation of conjugated dienes . Angew. Chem. Int. Ed. , 2023 , 62 ( 51 ), e202315473 .

Lai, H. W. ; Ouchi, M . Backbone degradable polymers via chain-growth radical polymerization . Chinese J. Polym. Sci. , 2025 , 43 ( 6 ), 887 – 907 .

Rubin, M. ; Schwier, T. ; Gevorgyan, V . Highly efficient B(C 6 F 5 ) 3 -catalyzed hydrosilylation of olefins . J. Org. Chem. , 2002 , 67 ( 6 ), 1936 – 1940 .

Keess, S. ; Simonneau, A. ; Oestreich, M . Direct and transfer hydrosilylation reactions catalyzed by fully or partially fluorinated triarylboranes: a systematic study . Organometallics , 2015 , 34 ( 4 ), 790 – 799 .

Simonneau, A. ; Oestreich, M . 3-silylated cyclohexa-1, 4-dienes as precursors for gaseous hydrosilanes: the B(C 6 F 5 ) 3 -catalyzed transfer hydrosilylation of alkenes . Angew. Chem. Int. Ed. , 2013 , 52 ( 45 ), 11905 – 11907 .

Holthausen, M. H. ; Mehta, M. ; Stephan, D. W . The highly lewis acidic dicationic phosphonium salt: [(SIMes)PFPh 2 ] [B(C 6 F 5 ) 4 ] 2 . Angew. Chem. , 2014 , 126 ( 25 ), 6656 – 6659 .

Mabry, J. M. ; Runyon, M. K. ; Weber, W. P . Synthesis of copoly [arylene-1, 2-dioxy/oligodimethylsiloxanylene ] by Ruthenium-Catalyzed Dehydrogenative Silylation Copolymerization of o -quinones with α, ω-dihydridooligodimethylsiloxanes . Macromolecules , 2001 , 34 ( 21 ), 7264 – 7268 .

Mabry, J. M. ; Runyon, M. K. ; Weber, W. P . Poly(silyl ether)s by ruthenium-catalyzed hydrosilylation polymerization of aliphatic ω -dimethylsilyloxy ketones and copolymerization of aliphatic α , ω -diketones with α , ω -dihydridooligodimethylsiloxanes . Macromolecules , 2002 , 35 ( 6 ), 2207 – 2211 .

Mabry, J. M. ; Paulasaari, J. K. ; Weber, W. P . Synthesis of poly(silyl ethers) by Ru-catalyzed hydrosilylation . Polymer , 2000 , 41 ( 12 ), 4423 – 4428 .

Lázaro, G. ; Iglesias, M. ; Fernández-Alvarez, F. J. ; Sanz Miguel, P. J. ; Pérez-Torrente, J. J. ; Oro, L. A . Synthesis of poly(silyl ether)s by rhodium(Ⅰ)-NHC catalyzed hydrosilylation: homogeneous versus heterogeneous catalysis . ChemCatChem , 2013 , 5 ( 5 ), 1133 – 1141 .

Lázaro, G. ; Fernández-Alvarez, F. J. ; Iglesias, M. ; Horna, C. ; Vispe, E. ; Sancho, R. ; Lahoz, F. J. ; Iglesias, M. ; Pérez-Torrente, J. J. ; Oro, L. A . Heterogeneous catalysts based on supported Rh-NHC complexes: synthesis of high molecular weight poly(silyl ether)s by catalytic hydrosilylation . Catal. Sci. Technol. , 2014 , 4 ( 1 ), 62 – 70 .

Tsumura, M. ; Iwahara, T. ; Hirose, T . Synthesis and properties of polycarbosilanes by hydrosilylation polymerization . Polym. J. , 1995 , 27 ( 10 ), 1048 – 1053 .

Sanchez, J. C. ; Urbas, S. A. ; Toal, S. J. ; DiPasquale, A. G. ; Rheingold, A. L. ; Trogler, W. C . Catalytic hydrosilylation routes to divinylbenzene bridged silole and silafluorene polymers. Applications to surface imaging of explosive particulates . Macromolecules , 2008 , 41 ( 4 ), 1237 – 1245 .

管雁 , 吴清洲 , 陈关喜 , 冯建跃 , 莫卫民 . 硅氢加成反应用铂催化剂的研究进展 . 化学研究 , 2010 , 21 ( 2 ), 100 – 105 .

Speier, J. L. ; Webster, J. A. ; Barnes, G. H . The addition of silicon hydrides to olefinic double bonds. Part Ⅱ. The use of group Ⅷ metal catalysts . J. Am. Chem. Soc. , 1957 , 79 ( 4 ), 974 – 979 .

Chalk, A. J. ; Harrod, J. F . Homogeneous catalysis. Ⅱ. The mechanism of the hydrosilation of olefins catalyzed by group Ⅷ metal complexes . J. Am. Chem. Soc. , 1965 , 87 ( 1 ), 16 – 21 .

Harrod, J. F. ; Chalk, A. J . Dicobalt octacarbonyl as a catalyst for hydrosilation of olefins . J. Am. Chem. Soc. , 1965 , 87 ( 5 ), 1133 .

Harrod, J. F. ; Chalk, A. J . Homogeneous catalysis. Ⅲ. Isomerization of deuterio olefins by group Ⅷ metal complexes . J. Am. Chem. Soc. , 1966 , 88 ( 15 ), 3491 – 3497 .

Karstedt, B. D . Platinum-vinylsiloxanes . U.S. patent , 1973 , 3715334 .

Hitchcock, P. B. ; Lappert, M. F. ; Warhurst, N. J. W . Synthesis and structure of a rac-tris(divinyldisiloxane) diplatinum(0) complex and its reaction with maleic anhydride . Angew. Chem. Int. Ed. Engl. , 1991 , 30 ( 4 ), 438 – 440 .

D’Amelia, R. P. ; Mancuso, J. ; Nirode, W. F. ; Singh, S . Characterization and synthesis of functionalized polysilalkylene siloxane monomers by hydrosilylation reaction . World J. Org. Chem. , 2019 , 7 ( 1 ), 5 – 13 .

Cheng, Z. Y. ; Li, M. H. ; Zhang, X. Y. ; Sun, Y. ; Yu, Q. L. ; Zhang, X. H. ; Lu, Z . Cobalt-catalyzed regiodivergent double hydrosilylation of arylacetylenes . Angew. Chem. Int. Ed. , 2023 , 62 ( 1 ), e202215029 .

Mosley, D. W. ; Khanarian, G. ; Conner, D. M. ; Thorsen, D. L. ; Zhang, T. L. ; Wills, M . High refractive index thermally stable phenoxyphenyl and phenylthiophenyl silicones for light-emitting diode applications . J. Appl. Polym. Sci. , 2014 , 131 ( 3 ), 39824 .

Higashihara, T. ; Ueda, M . Recent progress in high refractive index polymers . Macromolecules , 2015 , 48 ( 7 ), 1915 – 1929 .

Long, X. Y. ; Zhu, D. ; Zhu, S. F . Cobalt-catalyzed chemoselective and divergent synthesis of vinylsilanes through hydrosilylation of acetylene . ACS Catal. , 2025 , 15 ( 6 ), 4429 – 4440 .

D’Ambra, C. A. ; Getty, P. T. ; Eom, T. ; Czuczola, M. ; Murphy, E. A. ; Biswas, S. ; Abdilla, A. ; Mecca, J. M. ; Bekemeier, T. D. ; Swier, S. ; Fielitz, A. ; Hawker, C. J. ; Bates, C. M . Facile preparation of tunable polyborosiloxane networks via  hydrosilylation . Chem. Mater. , 2024 , 36 ( 12 ), 5935 – 5942 .

Röttger, M. ; Domenech, T. ; van der Weegen, R. ; Breuillac, A. ; Nicolaÿ, R. ; Leibler, L . High-performance vitrimers from commodity thermoplastics through dioxaborolane metathesis . Science , 2017 , 356 ( 6333 ), 62 – 65 .

Porath, L. ; Huang, J. R. ; Ramlawi, N. ; Derkaloustian, M. ; Ewoldt, R. H. ; Evans, C. M . Relaxation of vitrimers with kinetically distinct mixed dynamic bonds . Macromolecules , 2022 , 55 ( 11 ), 4450 – 4458 .

Cromwell, O. R. ; Chung, J. ; Guan, Z. B . Malleable and self-healing covalent polymer networks through tunable dynamic boronic ester bonds . J. Am. Chem. Soc. , 2015 , 137 ( 20 ), 6492 – 6495 .

Cash, J. J. ; Kubo, T. ; Dobbins, D. J. ; Sumerlin, B. S . Maximizing the symbiosis of static and dynamic bonds in self-healing boronic ester networks . Polym. Chem. , 2018 , 9 ( 15 ), 2011 – 2020 .

Robinson, L. L. ; Self, J. L. ; Fusi, A. D. ; Bates, M. W. ; Read de Alaniz, J. ; Hawker, C. J. ; Bates, C. M. ; Sample, C. S . Chemical and mechanical tunability of 3D-printed dynamic covalent networks based on boronate esters . ACS Macro Lett. , 2021 , 10 ( 7 ), 857 – 863 .

Li, L. Q. ; Chen, X. ; Jin, K. L. ; Torkelson, J. M . Vitrimers designed both to strongly suppress creep and to recover original cross-link density after reprocessing: quantitative theory and experiments . Macromolecules , 2018 , 51 ( 15 ), 5537 – 5546 .

Breuillac, A. ; Kassalias, A. ; Nicolaÿ, R . Polybutadiene vitrimers based on dioxaborolane chemistry and dual networks with static and dynamic cross-links . Macromolecules , 2019 , 52 ( 18 ), 7102 – 7113 .

Saed, M. O. ; Gablier, A. ; Terentejv, E. M . Liquid crystalline vitrimers with full or partial boronic-ester bond exchange . Adv. Funct. Mater. , 2020 , 30 ( 3 ), 1906458 .

Lukin, R. Y. ; Kuchkaev, A. M. ; Sukhov, A. V. ; Bekmukhamedov, G. E. ; Yakhvarov, D. G . Platinum-catalyzed hydrosilylation in polymer chemistry . Polymers , 2020 , 12 ( 10 ), 2174 .

Lewis, L. N. ; Colborn, R. E. ; Grade, H. ; Bryant, G. L. Jr. ; Sumpter, C. A. ; Scott, R. A . Mechanism of formation of platinum(0) complexes containing silicon-vinyl ligands . Organometallics , 1995 , 14 ( 5 ), 2202 – 2213 .

Sprengers, J. W. ; de Greef, M. ; Duin, M. A. ; Elsevier, C. J . Stable platinum(0) catalysts for catalytic hydrosilylation of styrene and synthesis of[Pt(Ar-Bian)( η 2 -alkene) ] complexes . Eur. J. Inorg. Chem. , 2003 , 2003 ( 20 ), 3811 – 3819 .

Dong, C. ; Yuan, Y. ; Cui, Y. M. ; Zheng, Z. J. ; Cao, J. ; Xu, Z. ; Xu, L. W . A pronounced ligand effect on platinum-catalyzed hydrosilylation of terminal alkynes . Appl. Organomet. Chem. , 2018 , 32 ( 2 ), e4037 .

Lukin, R. Y. ; Emelyanov, D. A. ; Kachmarzhik, A. D. ; Sukhov, A. V. ; Sinyashin, O. G. ; Yakhvarov, D. G . Effect of Buchwald-type ligands on platinum catalyzed hydrosilylation of vinyl terminated polydimethylsiloxane . Mendeleev Commun. , 2019 , 29 ( 4 ), 458 – 460 .

Hitchcock, P. B. ; Lappert, M. F. ; MacBeath, C. ; Scott, F. P. E. ; Warhurst, N. J. W . The synthesis and characterisation of some divinyldisiloxane: (tertiary phosphine) complexes of platinum(0) and nickel(0) . J. Organomet. Chem. , 1997 , 528 ( 1-2 ), 185 – 190 .

Chandra, G. ; Lo, P. Y. ; Hitchcock, P. B. ; Lappert, M. F . A convenient and novel route to bis( η -alkyne)platinum(0) and other platinum(0) complexes from Speier's hydrosilylation catalyst H 2 [PtCl 6 ] · x H 2 O. X-ray structure of[Pt{( η -CH 2 =CHSiMe 2 ) 2 O}(P- t -Bu 3 ) ] . Organometallics , 1987 , 6 ( 1 ), 191 – 192 .

Markó, I. ; Stérin, S. ; Buisine, O. ; Berthon, G. ; Michaud, G. ; Tinant, B. ; Declercq, J. P . Highly active and selective platinum(0)-carbene complexes. efficient, catalytic hydrosilylation of functionalised olefins . Adv. Synth. Catal. , 2004 , 346 ( 12 ), 1429 – 1434 .

Markó, I. E. ; Stérin, S. ; Buisine, O. ; Mignani, G. ; Branlard, P. ; Tinant, B. ; Declercq, J. P . Selective and efficient platinum(0)-carbene complexes as hydrosilylation catalysts . Science , 2002 , 298 ( 5591 ), 204 – 206 .

Herrmann, W. A . N-heterocyclic carbenes: a new concept in organometallic catalysis . Angew. Chem. Int. Ed. , 2002 , 41 ( 8 ), 1290 – 1309 .

Hu, J. J. ; Li, F. W. ; Andy Hor, T. S . Novel Pt(Ⅱ) mono- and biscarbene complexes: synthesis, structural characterization and application in hydrosilylation catalysis . Organometallics , 2009 , 28 ( 4 ), 1212 – 1220 .

de Bo, G. ; Berthon-Gelloz, G. ; Tinant, B. ; Markó, I. E . Hydrosilylation of alkynes mediated by N -heterocyclic carbene platinum(0) complexes . Organometallics , 2006 , 25 ( 8 ), 1881 – 1890 .

Schear, M. B. ; Neal, A. ; Clarke, J. S. ; Saab, A. P. ; Giller, C. B. ; Casalini, R. ; Laskoski, M . Aromatic bisphenol A-based elastomers via  hydrosilylation chemistry . J. Appl. Polym. Sci. , 2021 , 138 ( 12 ), 50053 .

Wang, X. X. ; Zhao, N. ; Qin, B. ; Xu, J. J. ; Yang, W. L. ; Li, C. S. ; Sun, L. G. ; Zhang, J. Q . Ultrasonics sonochemistry assisted preparation of polysiloxane main-chain liquid-crystalline elastomers . Macromol. Chem. Phys. , 2020 , 221 ( 11 ), 2000071 .

Wood, R. J. ; Lee, J. ; Bussemaker, M. J . A parametric review of sonochemistry: control and augmentation of sonochemical activity in aqueous solutions . Ultrason. Sonochem. , 2017 , 38 , 351 – 370 .

Li, X. D. ; Li, S. S. ; Jiang, X. B. ; Zhu, X. L. ; Kong, X. Z . Unconventional fluorescent and multi-responsive polysiloxane: Synthesis, characterization and biological applications . Chinese J. Polym. Sci. , 2024 , 42 ( 5 ), 579 – 590 .

Kamino, B. A. ; Bender, T. P . The use of siloxanes, silsesquioxanes, and silicones in organic semiconducting materials . Chem. Soc. Rev. , 2013 , 42 ( 12 ), 5119 – 5130 .

Shieh, P. ; Zhang, W. X. ; Husted, K. E. L. ; Kristufek, S. L. ; Xiong, B. Y. ; Lundberg, D. J. ; Lem, J. ; Veysset, D. ; Sun, Y. C. ; Nelson, K. A. ; Plata, D. L. ; Johnson, J. A . Cleavable comonomers enable degradable, recyclable thermoset plastics . Nature , 2020 , 583 ( 7817 ), 542 – 547 .

Minegishi, S. ; Ito, M. ; Kameyama, A. ; Nishikubo, T . Synthesis of poly(silyl ether)s containing pendant chloromethyl groups by the polyaddition of bis(oxetane)s with dichlorosilanes . J. Polym. Sci. A Polym. Chem. , 2000 , 38 ( 12 ), 2254 – 2259 .

Kawakami, Y. ; Li, Y. N . Approaches to polymers containing a silicon-oxygen bond in the main chain . Des. Monomers Polym. , 2000 , 3 ( 4 ), 399 – 419 .

Shieh, P. ; Nguyen, H. V. ; Johnson, J. A . Tailored silyl ether monomers enable backbone-degradable polynorbornene-based linear, bottlebrush and star copolymers through ROMP . Nat. Chem. , 2019 , 11 ( 12 ), 1124 – 1132 .

Nagasaki, Y. ; Matsukura, F. ; Kato, M. ; Aoki, H. ; Tokuda, T . New thermosensitive rubbery polymers. Synthesis of poly(siloxyethylene glycol) and its aqueous solution properties . Macromolecules , 1996 , 29 ( 18 ), 5859 – 5863 .

孙雪玲 , 邓玉媛 , 司薇薇 , 韩媛媛 . 聚硅醚的合成反应研究进展 . 高分子通报 , 2024 , 37 ( 9 ), 1233 – 1242 .

Ackley, B. J. ; Martin, K. L. ; Key, T. S. ; Clarkson, C. M. ; Bowen, J. J. ; Posey, N. D. ; Ponder, Apostolov, Z. D. ; Cinibulk, M. K. ; Pruyn, T. L. ; Dickerson, M. B . Advances in the synthesis of preceramic polymers for the formation of silicon-based and ultrahigh-temperature non-oxide ceramics . Chem. Rev. , 2023 , 123 ( 8 ), 4188 – 4236 .

Luleburgaz, S. ; Tunca, U. ; Durmaz, H . Poly(silyl ether)s (silyl ether copolymers) via  hydrosilylation of carbonyl compounds . Polym. Chem. , 2023 , 14 ( 25 ), 2949 – 2957 .

Li, C. Y. ; Wang, L. F. ; Wang, M. Y. ; Liu, B. ; Liu, X. L. ; Cui, D. M . Step-growth coordination polymerization of 5-hydroxymethyl furfural with dihydrosilanes: synergistic catalysis using heteroscopionate zinc hydride and B(C 6 F 5 ) 3 . Angew. Chem. Int. Ed. , 2019 , 58 ( 33 ), 11434 – 11438 .

Fouilloux, H. ; Rager, M. N. ; Ríos, P. ; Conejero, S. ; Thomas, C. M . Highly efficient synthesis of poly(silylether)s: access to degradable polymers from renewable resources . Angew. Chem. Int. Ed. , 2022 , 134 ( 7 ), e202113443 .

Wang, L. ; Lu, W. X. ; Zhang, J. W. ; Chong, Q. L. ; Meng, F. K . Cobalt-catalyzed regio-, diastereo- and enantioselective intermolecular hydrosilylation of 1, 3-dienes with prochiral silanes . Angew. Chem. Int. Ed. , 2022 , 61 ( 30 ), e202205624 .

Park, J. W . Cobalt-catalyzed alkyne hydrosilylation as a new frontier to selectively access silyl-hydrocarbons . Chem. Commun. , 2022 , 58 ( 4 ), 491 – 504 .

Chen, C. Y. ; Luo, Z. W. ; Zeng, H. ; Hao, C. W. ; Yang, K. F. ; Li, Z. ; Lai, G. Q. ; Zhang, P. L . Cobalt-catalyzed hydrosilylation polymerization for the synthesis of linear polycarbosilanes . Macromolecules , 2024 , 57 ( 16 ), 8146 – 8153 .

Liu, Z. F. ; Ren, B. H. ; Fu, Y. S. ; Yang, J. ; Teng, Y. Q. ; Liu, Y. ; Lu, X. B . Installation of multiple chiral centers in aliphatic polyesters backbone enables unexpected crystallinity via asymmetric catalytic copolymerization . Chinese J. Polym. Sci. , 2025 , 43 ( 6 ), 946 – 951 .

Nakano, T. ; Okamoto, Y . Synthetic helical polymers:   conformation and function . Chem. Rev. , 2001 , 101 ( 12 ), 4013 – 4038 .

Shen, J. ; Okamoto, Y . Efficient separation of enantiomers using stereoregular chiral polymers . Chem. Rev. , 2016 , 116 ( 3 ), 1094 – 1138 .

Wang, X. Q. ; Zhai, X. Y. ; Wu, B. ; Bai, Y. Q. ; Zhou, Y. G . Synthesis of chiral poly(silyl ether)s via CuH-catalyzed asymmetric hydrosilylation polymerization of diketones with silanes . ACS Macro Lett. , 2020 , 9 ( 7 ), 969 – 973 .

Díez-González, S. ; Nolan, S. P . Copper, silver, and gold complexes in hydrosilylation reactions . Acc. Chem. Res. , 2008 , 41 ( 2 ), 349 – 358 .

Deutsch, C. ; Krause, N. ; Lipshutz, B. H . CuH-catalyzed reactions . Chem. Rev. , 2008 , 108 ( 8 ), 2916 – 2927 .

Rendler, S. ; Oestreich, M . Polishing a diamond in the rough: “Cu―H” catalysis with silanes . Angew. Chem. Int. Ed. , 2007 , 46 ( 4 ), 498 – 504 .

Wu, J. ; Ji, J. X. ; Chan, A. S. C . A remarkably effective copper(Ⅱ)-dipyridylphosphine catalyst system for the asymmetric hydrosilylation of ketones in air . Proc. Natl. Acad. Sci. U. S. A. , 2005 , 102 ( 10 ), 3570 – 3575 .

Zeng, W. J. ; Tan, X. F. ; Yu, Y. ; Chen, G. Q. ; Zhang, X. M . Copper-catalyzed asymmetric hydrosilylation of β-nitroethyl aryl ketones . Org. Lett. , 2020 , 22 ( 3 ), 858 – 862 .

Wang, X. Q. ; Wu, B. ; Bai, Y. Q. ; Zhai, X. Y. ; Zhou, Y. G . CuH-catalyzed consecutive hydrosilylation/dehydrocoupling polymerization of difunctional hydroxyketones with dihydrosilanes for syntheses of chiral poly(silyl ether)s . Eur. Polym. J. , 2022 , 177 , 111474 .

Enthaler, S . Rise of the zinc age in homogeneous catalysis? ACS Catal. , 2013 , 3 ( 2 ), 150 – 158 .

Bart, S. C. ; Lobkovsky, E. ; Chirik, P. J . Preparation and molecular and electronic structures of iron(0) dinitrogen and silane complexes and their application to catalytic hydrogenation and hydrosilation . J. Am. Chem. Soc. , 2004 , 126 ( 42 ), 13794 – 13807 .

Li, C. Y. ; Hua, X. F. ; Mou, Z. H. ; Liu, X. L. ; Cui, D. M . Zinc-catalyzed hydrosilylation copolymerization of aromatic dialdehydes with diphenylsilane . Macromol. Rapid Commun. , 2017 , 38 ( 22 ), 1700590 .

Nachtergael, A. ; Coulembier, O. ; Dubois, P. ; Helvenstein, M. ; Duez, P. ; Blankert, B. ; Mespouille, L . Organocatalysis paradigm revisited: are metal-free catalysts really harmless . Biomacromolecules , 2015 , 16 ( 2 ), 507 – 514 .

Tsarevsky, N. V. ; Matyjaszewski, K . “Green” atom transfer radical polymerization: from process design to preparation of well-defined environmentally friendly polymeric materials . Chem. Rev. , 2007 , 107 ( 6 ), 2270 – 2299 .

Parks, D. J. ; Piers, W. E . Tris(pentafluorophenyl)boron-catalyzed hydrosilation of aromatic aldehydes, ketones, and esters . J. Am. Chem. Soc. , 1996 , 118 ( 39 ), 9440 – 9441 .

Chadwick, R. C. ; Kardelis, V. ; Lim, P. ; Adronov, A . Metal-free reduction of secondary and tertiary N -phenyl amides by tris(pentafluorophenyl)boron-catalyzed hydrosilylation . J. Org. Chem. , 2014 , 79 ( 16 ), 7728 – 7733 .

Gandhamsetty, N. ; Joung, S. ; Park, S. W. ; Park, S. ; Chang, S . Boron-catalyzed silylative reduction of quinolines: selective sp 3 C―Si bond formation . J. Am. Chem. Soc. , 2014 , 136 ( 48 ), 16780 – 16783 .

Gandhamsetty, N. ; Park, J. ; Jeong, J. ; Park, S. W. ; Park, S. ; Chang, S . Chemoselective silylative reduction of conjugated nitriles under metal-free catalytic conditions: β -silyl amines and enamines . Angew. Chem. Int. Ed. , 2015 , 54 ( 23 ), 6832 – 6836 .

Sample, C. ; Lee, S. H. ; Bates, M. W. ; Ren, J. M. ; Lawrence, J. ; Lensch, V. ; Gerbec, J. A. ; Bates, C. M. ; Li, S. G. ; Hawker, C. J . Metal-free synthesis of poly(silyl ether)s under ambient conditions . Macromolecules , 2019 , 52 ( 5 ), 1993 – 1999 .

Sample, C. ; Lee, S. H. ; Li, S. G. ; Bates, M. W. ; Lensch, V. ; Versaw, B. A. ; Bates, C. M. ; Hawker, C. J . Metal-free room-temperature vulcanization of silicones via borane hydrosilylation . Macromolecules , 2019 , 52 ( 19 ), 7244 – 7250 .

Yoshida, N. ; Zhu, H. E. ; Mitsuishi, M . Metal-free synthesis of alternating silylether–carbosilane copolymers using unsaturated ketones . Polym. Chem. , 2024 , 15 ( 12 ), 1204 – 1211 .

Belay, T. A. ; Chen, J. P. ; Xu, H. ; Zhang, S. W. ; Chen, S. L. ; Li, X. F . Functionalization methodology for synthesis of silane-end-functionalized linear and star poly(aryl isocyanide)s by combination of cationic polymerization and hydrosilylation reaction . Macromolecules , 2021 , 54 ( 19 ), 9007 – 9018 .

Radchenko, A. V. ; Ganachaud, F . Photocatalyzed hydrosilylation in silicone chemistry . Ind. Eng. Chem. Res. , 2022 , 61 ( 23 ), 7679 – 7698 .

Huang, Z. J. ; Dong, J. ; Liu, K. W. ; Pan, X. C . Oxygen, light, and mechanical force mediated radical polymerization toward precision polymer synthesis . Chem. Commun. , 2025 , 61 ( 13 ), 2699 – 2722 .

Huang, Z. J. ; Chen, Z. ; Jiang, Y. ; Li, N. ; Yang, S. C. ; Wang, G. W. ; Pan, X. C . Metal-free hydrosilylation polymerization by merging photoredox and hydrogen atom transfer catalysis . J. Am. Chem. Soc. , 2021 , 143 ( 45 ), 19167 – 19177 .

List, B. ; Grimm, J. A. A . Visible-light-driven organocatalytic hydrosilylation to form polycarbosilanes with tunable structures . Synfacts , 2022 , 18 ( 1 ), 0078 .

Huang, Z. J. ; Liu, K. W. ; Liu, M. Y. ; Yun, J. ; Dong, J. ; Chen, Z. ; Xie, Z. K. ; Pan, X. C . Photocatalytic metal-free radical hydrosilylation for polymer functionalization . Chin. J. Chem. , 2023 , 41 ( 18 ), 2275 – 2281 .

Shao, S. M. ; Huang, J. X. ; Mi, H. ; Hu, J. ; Wang, M. ; Yang, H . Organosilicon liquid crystal polymers and elastomers prepared by metal-free photocatalytic hydrosilylation polymerization . Macromolecules , 2025 , 58 ( 5 ), 2736 – 2744 .

Xie, H. C. ; Xu, R. ; Huang, B. ; Lou, P. P. ; Fei, H. F. ; Zhang, Z. J . DIPEA-induced Si–H activation of siloxane for hydrosilylation polymerization via  metal-free photocatalysis . Green Chem. , 2025 , 27 ( 1 ), 155 – 162 .

Gao, R. H. ; Li, Z. ; Deng, J. X. ; Yan, X. Z. ; Tang, S . Polycarbosilanes with intact lactone ring units from CO 2 , butadiene, and silanes . Sci. China Chem. , 2025 , Doi: 10.1007/s11426-025-3035-y https://doi.org/10.1007/s11426-025-3035-y .

Du, Y. X. ; Dong, J. ; Xu, C. R. ; Pan, X. C . Organoboron chemistry towards controlled and precise polymer synthesis . Sci. China Chem. , 2023 , 66 ( 12 ), 3467 – 3483 .

Dong, J. ; He, C. Z. ; Xu, C. R. ; Yun, J. ; Pan, X. C . Vinyl boronate polymers with dynamic exchange properties . Polym. Chem. , 2022 , 13 ( 46 ), 6408 – 6414 .

Nakano, R. ; Ito, S. ; Nozaki, K . Copolymerization of carbon dioxide and butadiene via a lactone intermediate . Nat. Chem. , 2014 , 6 ( 4 ), 325 – 331 .

Hill, M. R. ; Tang, S. ; Masada, K. ; Hirooka, Y. ; Nozaki, K . Incorporation of CO 2 -derived bicyclic lactone into conventional vinyl polymers . Macromolecules , 2022 , 55 ( 8 ), 3311 – 3316 .

Haack, V. ; Dinjus, E. ; Pitter, S . Synthesis of polymers with an intact lactone ring structure in the main chain . Die Angew. Makromol. Chem. , 1998 , 257 ( 1 ), 19 – 22 .

云杰 , 徐超然 , 谢志康 , 杜昱璇 , 董进 , 潘翔城 . 基于硼酸酯标签制备具有精确侧基结构的可控聚合物 . 高分子学报 , 2024 , 55 ( 7 ), 881 – 890 .