Research Progress in Radical Helical Polymerization

Shi WU; Sheng-tang HUANG; Jia-an ZHANG; Gang YAO; Xiao-hong JIN

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Research Progress in Radical Helical Polymerization

更新时间：2022-09-18

- Research Progress in Radical Helical Polymerization
- Polymer Bulletin Vol. 26, Issue 7, Pages: 11-14(2013)
- 作者机构：
  
  湖北科技学院药学院，咸宁　437100
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：2013-07，
  
  Received：11 December 2012，
  
  Revised：26 March 2013，
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Shi WU, Sheng-tang HUANG, Jia-an ZHANG, Gang YAO, Xiao-hong JIN. Research Progress in Radical Helical Polymerization. [J]. Polymer Bulletin 26(7):11-14(2013)
DOI：

Shi WU, Sheng-tang HUANG, Jia-an ZHANG, Gang YAO, Xiao-hong JIN. Research Progress in Radical Helical Polymerization. [J]. Polymer Bulletin 26(7):11-14(2013) DOI：

摘要

螺旋聚合物是一类在不对称领域具有特殊用途的高分子

可用于对映体分离、不对称催化和不对称光学等领域。其合成方法的研究一直是合成高分子科学的研究热点。自由基螺旋聚合以其大量优点备受人们重视

但受自由基聚合的自身缺陷影响

在螺旋聚合物合成上成功的例子较少。本文对自由基螺旋聚合的自身缺陷进行探讨

对各种方法进行综述

介绍了手性单体聚合、手性引发剂聚合、手性链转移聚合、手性模板控制聚合和手性溶剂聚合等各种自由基螺旋聚合方法

并对其前景进行了展望。

Abstract

Helical polymer was a polymer that had special application in asymmetric fields

can be used for the separation of enantiomers

asymmetric catalysis and asymmetric optical fields

etc. The synthesis of helical polymer has been the research focus of the synthetic polymer science. Free radical polymerization with many advantages has attracted much attention in synthesis of helical polymer

but there are few successful examples because of defects of the free radical polymerization. In this paper

the defects of free radical helix polymerization are discussed

various methods are summarized and introduced including chiral monomers

free radical polymerization

the chiral initiator polymerization

chiral chain transfer polymerization

chiral template controling polymerization and chiral solvent polymerization

etc. Moreover

the future study prospect were proposed.

关键词

螺旋聚合物自由基聚合聚合方法研究进展

Keywords

Helical polymerRadical polymerizationPolymerization methodResearch progress

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