The synthesis of insect sex pheromones on solid phase

Jiawei Chen

doi:10.14028/j.cnki.1003-3726.1990.01.004

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The synthesis of insect sex pheromones on solid phase

更新时间：2022-09-18

- The synthesis of insect sex pheromones on solid phase
- Polymer Bulletin Vol. 3, Issue 1, Pages: 19-26,33(1990)
- 作者机构：
  
  湖北大学化学系，武汉
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.1990.01.004
  CLC：
- Published：1990，
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Jiawei Chen. The synthesis of insect sex pheromones on solid phase. [J]. Polymer Bulletin 3(1):19-26,33(1990)
DOI：

Jiawei Chen. The synthesis of insect sex pheromones on solid phase. [J]. Polymer Bulletin 3(1):19-26,33(1990) DOI： 10.14028/j.cnki.1003-3726.1990.01.004.

摘要

本综述阐明昆虫性信息素固相合成的最新成就。C.C.Leznoff开创了昆虫性信息素的固相合成，并合成了一系列信息素。他以二醇为原料，以聚合物三苯甲基氯为保护剂。陈德恒等将保护剂改成聚合物三苯甲基氯硅烷，产率比前人有所提高。陈家成等大大改进了前两人的线路，简化了歩骤，只抓住关键的一步进行固相合成，总产率比前人提高得更多。

Abstract

This review covers the development

recent research progress about the synthesis of insect sex pheromones on solid phase. C. C. Leznoff

et. al. have synthesized a large scale of insect sex pheromones on solid phase. He used polymeric trityl chloride as monofunctional protecting reagent of diol.But Chan Tak Hang

et. al. changed the polymeric protecting reagent into polymer -bound triphenyl chlorosilane. Its yield is higher than before. Ghen Jia Wei

et. al. modified above two methods: simplified the steps

only seized the key step on solid phase. The yield also increased much more than above route.

关键词

聚合物支体固相合成聚合物维获希试剂聚合物保护剂昆虫性信息索

Keywords

polymer-supportsolid phase synthesispolymeric wittig reagentpolymeric protecting reagentinsect sex pheromone

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