A New Diagram Relating Kinetic Parameters of Free-Radical Polymerization

Zuren Pan

doi:10.14028/j.cnki.1003-3726.1992.03.009

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A New Diagram Relating Kinetic Parameters of Free-Radical Polymerization

更新时间：2022-09-18

- A New Diagram Relating Kinetic Parameters of Free-Radical Polymerization
- Polymer Bulletin Vol. 5, Issue 3, Pages: 190-192,146(1992)
- 作者机构：
  
  浙江大学聚合反应工程实验室，杭州，310027
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.1992.03.009
  CLC：
- Published：1992-09，
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Zuren Pan. A New Diagram Relating Kinetic Parameters of Free-Radical Polymerization. [J]. Polymer Bulletin 5(3):190-192,146(1992)
DOI：

Zuren Pan. A New Diagram Relating Kinetic Parameters of Free-Radical Polymerization. [J]. Polymer Bulletin 5(3):190-192,146(1992) DOI： 10.14028/j.cnki.1003-3726.1992.03.009.

摘要

在自由基聚合速率常数（

、

）与可测参数（

、

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http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34346148&type=

、 τ、〔M

•

〕）间的关系提出新图解

以加深学习时的理解。

Abstract

In the past decade the lower concentration of free radical in the polymerization systems may be measured precisely by ESR and other methods. Thus

a new diagram relating four measurable variables (

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34346154&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34346160&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34346157&type=

〔M

•

〕) and kinetic parameters (

) is extended and developed from Hiemenz's three-parameter diagram.

关键词

自由基聚合动力学参数自由基寿命

Keywords

Free-radical polymerizationKinetic parameterslife-time of free radical

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Related Institution

School of Materials Science and Engineering

The Institute of Polymer Science and Materials,Zhejiang University

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