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浙江大学高分子科学与工程研究所,杭州,310027
Published:1996-03,
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Wenjun Wang, Bogeng Li, Zaizhang Yu, Zuren Pan. Mathematical Models of Kinetics for Semi - continuous Emulsion Polymerization. [J]. Polymer Bulletin 9(1):57-62(1996)
DOI:
Wenjun Wang, Bogeng Li, Zaizhang Yu, Zuren Pan. Mathematical Models of Kinetics for Semi - continuous Emulsion Polymerization. [J]. Polymer Bulletin 9(1):57-62(1996) DOI: 10.14028/j.cnki.1003-3726.1996.01.009.
介绍半连续乳液聚合动力学模型的研究进展及建模方法。归结出3种形式模型:基础模型、具体模型与通用模型。指出通常从一些假定出发
根据质量平衡、能量平衡及反应机理建立模型方程
通过模型参数估计、已有模型参数的利用及模型变量的求取
使用数值方法求解模型。
The progress in the research of kinetics modeling for the semi - continuous emulsion polymerizaiton was introduced
and the method of the modeling was discussed also. It was summed up that there exist three types of model
the fundamental model
real model
and general model. Model equations
which were set up by means of some assumptions
and according to mass balance
energy balance and polymerization rate equation
were solved by the numerical method combined with evaluation of model parameters
use of known model parameters and calculating methods of model variables.
半连续乳液聚合反应动力学数学模型
Semi - continuous emulsion polymerizationReaction kineticsMathematical model
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