Molecular Design of Polymer Surfactants

Jian Xu

doi:10.14028/j.cnki.1003-3726.1997.02.004

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Molecular Design of Polymer Surfactants

更新时间：2022-09-18

- Molecular Design of Polymer Surfactants
- Polymer Bulletin Vol. 10, Issue 2, Pages: 90-94,121(1997)
- 作者机构：
  
  中国科学院化学研究所高分子物理联合开放实验室，北京，100080
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.1997.02.004
  CLC：
- Published：1997-06，
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Jian Xu. Molecular Design of Polymer Surfactants. [J]. Polymer Bulletin 10(2):90-94,121(1997)
DOI：

Jian Xu. Molecular Design of Polymer Surfactants. [J]. Polymer Bulletin 10(2):90-94,121(1997) DOI： 10.14028/j.cnki.1003-3726.1997.02.004.

摘要

简要讨论高分子表面活性剂的合成和表征方法

分析了在水溶液中两亲性聚合物分子形态与表面活性的关系。单分子/多分子胶束的形成是导致聚合物表面活性变差的主要因素

提出了高分子表面活性剂的分子设计原则

设计了多种在高分子量下将能够保持优良表面活性的高分子表面活性剂分子结构模型。

Abstract

Approaches fo r preparat ion and characterization of the polymer surfactants are briefly described. The relationship between surface activity and conformation of polymer surfactant in aqueous solution is emphatically discussed. It is thought that the formation of mono-/multi-molecular micelle for polymer surfactant will loss its surface activity in aqueous solution. The design principles of polymer surfactant are suggested. Several struture models of polymer surfactant with both high molecular weight and high surface activity are designed.

关键词

高分子表面活性剂单分子/多分子胶束表面活性

Keywords

Polymer surfactantMono-/multi-mlecular micelleSurface activity

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