Research and Development in Addition Polymerization of Cycloolef ins

Zhong-wen DIAO; Qing WU

doi:10.14028/j.cnki.1003-3726.2001.01.008

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Research and Development in Addition Polymerization of Cycloolef ins

更新时间：2022-09-18

- Research and Development in Addition Polymerization of Cycloolef ins
- Polymer Bulletin Vol. 14, Issue 1, Pages: 53-59(2001)
- 作者机构：
  
  中山大学高分子研究所，广州　510275
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2001.01.008
  CLC：
- Published：2001-02，
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Zhong-wen DIAO, Qing WU. Research and Development in Addition Polymerization of Cycloolef ins. [J]. Polymer Bulletin 14(1):53-59(2001)
DOI：

Zhong-wen DIAO, Qing WU. Research and Development in Addition Polymerization of Cycloolef ins. [J]. Polymer Bulletin 14(1):53-59(2001) DOI： 10.14028/j.cnki.1003-3726.2001.01.008.

摘要

综述了环烯烃加成聚合的催化剂体系及其聚合物的研究和开发状况。主要介绍了催化剂种类，包括传统的齐格勒-纳塔（Ziegler-Natta）催化剂、茂金属催化剂、钯、镍等后过渡金属催化剂，及其催化环烯烃均聚合以及与T-烯烃共聚合的特性。也描述了用不同催化体系进行环烯烃聚合的机理以及环烯烃加成聚合物及其与T-烯烃共聚物的性能及应用前景。

Abstract

The research and development of addition polymerization of cycloolefins and the properties of polycycloolefins are reviewed. This paper mainly describes the typies of the catalysts

including typical Ziegler-Natta catalysts

metallocene catalysts and posttransition metals such as Pd and Ni complexes

and their catalyzing specificity for the cycloolefins homopolymerization and copolymerization with T-olefins. Mechanism of the polymerization with different catalysts and properties and applications of the cycloolefin polymers and the cycloolefin-T-olefin copolymers are also introduced.

关键词

环烯烃催化剂聚合

Keywords

CycloolefineCatalystPolymerization

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