million tons of polymers are produced worldwide every year
of which a large portion needs various types of stabilizers against degradation for longer service life.Atmospheric oxidation of organic materials including polymer
edible oil
food-stuff
petroleum products and lubricants occurs during their synthesis
production
storage
heat processing and end-use applications.There are many methods to prevent this oxidation
and addition of antioxidants is the most effective and convenient one.In this article we reviewed the recent study advances on acting mechanism of antioxidants
the most effective antioxidant system
optimal molecular weight MW
polymeric antioxidant
polymeric bound antioxidant
multifunctional antioxidant and bio-antioxidant.Attention is drawn to a conclusion that combination of primary antioxidant and secondary antioxidant is the most effective mode for protecting organic materials against atmospheric oxidation.This mode is not likely to be displaced by any other mode in the near future.Hindered phenol antioxidants will displace aromatic amine antioxidants which are toxic.Trends in antioxidant development are that toxic antioxidants will be displaced by non-toxic ones
and more attention will be paid to synthesis of antioxidant with optimal MW
polymeric antioxidant
polymer bound antioxidant
multifunctional antioxidants and bio-antioxidants.Applications of antioxidants in the thermal processing of polymers
lubricants
food and medicines are also disscussed.
关键词
抗氧剂受阻酚芳胺有机物氧化高分子热氧化稳定化
Keywords
AntioxidantHindered phenolAromatic amineOxidation of organic compoundsThermal oxidative stabilisation of polymers