Development of Catalysts for Syndiotactic Polymerization of Styrene

Zhi-gang SHEN; Shang-an LIN

doi:10.14028/j.cnki.1003-3726.2002.03.007

您当前的位置：

首页 >

文章列表页 >

Development of Catalysts for Syndiotactic Polymerization of Styrene

更新时间：2022-09-18

- Development of Catalysts for Syndiotactic Polymerization of Styrene
- Polymer Bulletin Vol. 15, Issue 3, Pages: 45-51,68(2002)
- 作者机构：
  
  1.中山大学高分子研究所，广州　510275；
  2.上海石油化工研究院，上海　201208
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2002.03.007
  CLC：
- Published：2002-06，
扫描看全文
Zhi-gang SHEN, Shang-an LIN. Development of Catalysts for Syndiotactic Polymerization of Styrene. [J]. Polymer Bulletin 15(3):45-51,68(2002)
DOI：

Zhi-gang SHEN, Shang-an LIN. Development of Catalysts for Syndiotactic Polymerization of Styrene. [J]. Polymer Bulletin 15(3):45-51,68(2002) DOI： 10.14028/j.cnki.1003-3726.2002.03.007.

摘要

综述了苯乙烯间规聚合主催化剂的研究和开发状况。主要介绍茂、茚、多元稠合环、氟和非茂钛等较高活性催化剂的催化特性。从取代基的电子效应和空间效应以及活性种稳定性等方面阐述了不同催化剂的聚合活性差异。

Abstract

The current development of catalysts used for syndiotactic polymerization of styrene has been reviewed.This paper focused on some high active catalysts including cyclopentadienyltitanium

indenyltitanium

fused-ring titanium

fluorinated-titanium and non-metallocene titanium.The different activity of catalysts was explained with the electron and steric effect of substitunents and the stability of active species.

关键词

苯乙烯间规聚合催化剂茂钛综述

Keywords

Syndiotactic polystyreneCatalystsMetallocene-titaniumReview

references

更多指标>

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

A Review on Improvement and Devolvement of Blood Compatibility

The Synthesis of Functionalized Polyolefin Materials and Research on Material Properties

Protein Resistant Materials and Their Applications in Biomedical Field

Research Advances of Polyethyleneimine in Adsorption Heavy Metal Ions

The Development of Syndiospecific Polypropylene Prepared by Metallocene Catalysts

Related Author

No data

Related Institution

National and Local Joint Engineering Research Center of Biomedical Functional Materials, Nanjing Normal University

Jiangsu Engineering Research Center of Interfacial Chemistry, Nanjing University

Department of Polymer Science and Engineering, University of Science and Technology of China

School of Chemical Engineering and Technology , Tianjin University

Technical Center for Safety of Industrial Products of Tianjin Entry-Exit Inspection and Quarantine Bureau of P. R. China

⁰