The Development of Controlled/living Radical Polymerization in Aqueous Media

Hui PENG; Yan-hua SHEN; Yong KE; Shi-yuan CHENG

doi:10.14028/j.cnki.1003-3726.2003.01.006

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The Development of Controlled/living Radical Polymerization in Aqueous Media

更新时间：2022-09-18

- The Development of Controlled/living Radical Polymerization in Aqueous Media
- Polymer Bulletin Vol. 16, Issue 1, Pages: 43-52(2003)
- 作者机构：
  
  湖北大学化学与材料科学学院，武汉　430062
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2003.01.006
  CLC：
- Published：2003-02，
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Hui PENG, Yan-hua SHEN, Yong KE, Shi-yuan CHENG. The Development of Controlled/living Radical Polymerization in Aqueous Media. [J]. Polymer Bulletin 16(1):43-52(2003)
DOI：

Hui PENG, Yan-hua SHEN, Yong KE, Shi-yuan CHENG. The Development of Controlled/living Radical Polymerization in Aqueous Media. [J]. Polymer Bulletin 16(1):43-52(2003) DOI： 10.14028/j.cnki.1003-3726.2003.01.006.

摘要

综述了均相水溶液体系和分散、悬浮、乳液及微乳液等非均相水溶液体系中的可控/活性自由基聚合的研究现状。对一些最常见的可控自由基聚合方法

如氮氧调控聚合、原子转移自由基聚合和可逆加成-断裂链转移聚合方法的聚合情况进行了详细的介绍。展望了水介质中可控/活性自由基聚合的发展方向及前景。

Abstract

Controlled/living radical polymerizations carried out in the presence of water have been examined. These aqueous systems include both the homogeneous and the various heterogeneous

namely dispersion

suspension

emulsion and miniemulsion

Among them

the most common methods allowing control of the radical polymerization

such as nitroxide-mediated polymerization

atom transfer radical polymerization and reversible addition-fragmentation transfer

are presented in detail. Good prospects for controlled/living radical polymerization in aqueous media are also shown.

关键词

水溶液可控/活性自由基聚合氮氧调控原子转移自由基聚合可逆加成-断裂链转移

Keywords

Aqueous solutionControlled/living radical polymerizationNitroxideAtom transfer radical polymerizationReversible addition-fragmentation transfer

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