Living Radical Polymerization with Reversible Addition-fragmentation Chain Transfer

Yan-jun WANG; Yu-xia WANG; Cai-deng YUAN; Tong-yu CAO

doi:10.14028/j.cnki.1003-3726.2003.03.007

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Living Radical Polymerization with Reversible Addition-fragmentation Chain Transfer

更新时间：2022-09-18

- Living Radical Polymerization with Reversible Addition-fragmentation Chain Transfer
- Polymer Bulletin Vol. 16, Issue 3, Pages: 57-63(2003)
- 作者机构：
  
  天津大学化工学院，天津　300072
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2003.03.007
  CLC：
- Published：2003-06，
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Yan-jun WANG, Yu-xia WANG, Cai-deng YUAN, Tong-yu CAO. Living Radical Polymerization with Reversible Addition-fragmentation Chain Transfer. [J]. Polymer Bulletin 16(3):57-63(2003)
DOI：

Yan-jun WANG, Yu-xia WANG, Cai-deng YUAN, Tong-yu CAO. Living Radical Polymerization with Reversible Addition-fragmentation Chain Transfer. [J]. Polymer Bulletin 16(3):57-63(2003) DOI： 10.14028/j.cnki.1003-3726.2003.03.007.

摘要

介绍了可逆加成－断裂链转移（Reversible addition-fragmentation chain transfer

RAFT）活性自由基聚合的反应机理、聚合动力学和特点

对RAFT试剂的选择和制备作了简要介绍

并综述了RAFT聚合的发展动态及应用状况。

Abstract

In this paper

the mechanism

kinetics and characteristics of the living radical polymerization with reversible addition-fragmentation chain transfer (RAFT) are reviewed in detail. The principles of selecting a proper RAFT agent for a given polymerization

and the synthesis process of the agent are presented briefly. Additionally

the development and application of the RAFT polymerization were summarized.

关键词

活性自由基聚合双硫酯加成－断裂链转移休眠种

Keywords

Living radical polymerizationDithioesterAddition-fragmentation chain transferDormant species

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Related Institution

The Key Laboratory of Food Colloids and Biotechnology,Ministry of Education, School of Chemical and Material Engineering,Jiangnan University

College of Chemistry and Chemical Engineering, Institute of Functional Polymer Composites, Engineering Laboratory of Flame Retardant and Functional Materials of Henan Province, Henan University

College of Chemical Engineering, Zhejiang University of Technology

Changzhou Institute of Light Industry Technology

Institute of Functional Polymers,School of Materials Science & Engineering, Tongji University

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