Synthesis and Morphology Characterization of PMMA/PAN-PMMA Nano Composite Particles

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- Synthesis and Morphology Characterization of PMMA/PAN-PMMA Nano Composite Particles
- Polymer Bulletin Vol. 17, Issue 3, Pages: 84-88(2004)
- 作者机构：
  
  东华大学材料学院　纤维材料改性国家重点实验室，上海　200051
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2004.03.012
  CLC：
- Published：2004-06，
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Song SONG, Wen-ping CHEN, Mei-fang ZHU, Yan-mo CHEN, Yu ZHANG. Synthesis and Morphology Characterization of PMMA/PAN-PMMA Nano Composite Particles. [J]. Polymer Bulletin 17(3):84-88(2004)
DOI：

Song SONG, Wen-ping CHEN, Mei-fang ZHU, Yan-mo CHEN, Yu ZHANG. Synthesis and Morphology Characterization of PMMA/PAN-PMMA Nano Composite Particles. [J]. Polymer Bulletin 17(3):84-88(2004) DOI： 10.14028/j.cnki.1003-3726.2004.03.012.

采用种子乳液聚合的方法制备PMMA／P（AN-MMA）纳米复合粒子，在第二阶段聚合过程中分别采用水溶性引发剂、油溶性引发剂以及氧化还原引发体系，通过透射电子显微镜（TEM）来观察复合乳胶粒子的形态结构，得到的PMMA／P（AN-MMA）纳米复合粒子为半球形结构，与热力学理论预测结果一致。

Study on the effect of different initiators on the structure of PMMA/P (AN-MMA) nano composite particles.Three types of initiators

potassium persulfate (KPS)

azobisiobutyrinitrile (AIBN) and textbutyl hydroperoxide (C

) /FeSO

were used in the second-stage polymerization

the results showed that the morphology structure of PMMA/P (AN-MMA) nano composite particles by seeded emulsion polymerization

at the thermodynamics equilibrium condition

was hemisphere structure in line with the thermodynamics analysis.

纳米乳胶粒子纳米复合粒子种子乳液聚合形态结构

Nano latexNano composite particlesSeeded emulsion polymerizationMorphology structure

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