Radical Polymerization in The Presence of Amine and Living Radical Polymerization

Xin-De FENG; Kun-Yuan QIU

doi:10.14028/j.cnki.1003-3726.2005.04.004

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Radical Polymerization in The Presence of Amine and Living Radical Polymerization

更新时间：2022-09-18

- Radical Polymerization in The Presence of Amine and Living Radical Polymerization
- Polymer Bulletin Vol. 18, Issue 4, Pages: 23-34(2005)
- 作者机构：
  
  北京大学化学与分子工程学院高分子科学与工程系，北京　100871
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2005.04.004
  CLC：
- Published：2005-08，
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Xin-De FENG, Kun-Yuan QIU. Radical Polymerization in The Presence of Amine and Living Radical Polymerization. [J]. Polymer Bulletin 18(4):23-34(2005)
DOI：

Xin-De FENG, Kun-Yuan QIU. Radical Polymerization in The Presence of Amine and Living Radical Polymerization. [J]. Polymer Bulletin 18(4):23-34(2005) DOI： 10.14028/j.cnki.1003-3726.2005.04.004.

摘要

综述了胺存在下自由基聚合

包括含胺的过氧化二酰与芳叔胺氧化还原体系、有机过氧化氢物与芳叔胺或脂肪叔胺氧化还原体系、过硫酸盐与脂肪胺氧化还原体系和极性单体的胺光诱导电荷转移引发自由基聚合

以及活性/控制自由基聚合

主要为原子转移自由基研究的成果。

Abstract

The polymerizations of vinyl monomers in the presence of amine including benzoyl peroxide-tertiary aromatic amine

organic peroxide-amine and persulfate salt-aliphatic amine redox initiation system as well as the photo-induced charge transfer polymerization of vinyl monomer as electron acceptor using amine as electron donor were reviewed.Living radical polymerization and some new initiation systems for atom transfer radical polymerization (ATRP) developed in our lab

including the C-C type compound as initiator in conjunction with Fe(Ⅲ)

Cu(Ⅱ) catalyst in reverse ATRP;the pseudo-halo transfer in normal ATRP using Cu(S

CNEt

) as catalyst or in reverse ATRP using Cu(S

CNEt

)Cl as catalyst;the in situ ATRP using S-S type compound tetraethylthiuram disulfide (TD) as initiator and FeCl

or CuBr

as catalyst were briefly summarized.

关键词

含胺氧化还原体系胺光诱导电荷转移自由基聚合活性自由基聚合原子转移自由基聚合引发聚合机理

Keywords

Amine-containing redox initiation systemPhoto-induced charge transfer polymerizationLiving radical polymerizationAtom transfer radical polymerizationInitiating polymerization mechanism

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