Polymer-supported Organocatalysts Ⅱ.Chiral Organocatalysts

A-fang ZHANG

doi:10.14028/j.cnki.1003-3726.2005.06.009

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Polymer-supported Organocatalysts Ⅱ.Chiral Organocatalysts

更新时间：2022-09-18

- Polymer-supported Organocatalysts Ⅱ.Chiral Organocatalysts
- Polymer Bulletin Vol. 18, Issue 6, Pages: 51-59(2005)
- 作者机构：
  
  郑州大学材料工程学院，郑州　450052
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2005.06.009
  CLC：
- Published：2005-12，
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A-fang ZHANG. Polymer-supported Organocatalysts Ⅱ.Chiral Organocatalysts. [J]. Polymer Bulletin 18(6):51-59(2005)
DOI：

A-fang ZHANG. Polymer-supported Organocatalysts Ⅱ.Chiral Organocatalysts. [J]. Polymer Bulletin 18(6):51-59(2005) DOI： 10.14028/j.cnki.1003-3726.2005.06.009.

摘要

对二十余年来聚合物支载的有机催化剂的合成、性能及其在催化反应中的应用，包括负载催化剂的回收和重复使用等进行了综述。用于支载体的聚合物包括交联聚合物、线型聚合物及树形聚合物；支载的有机催化剂包括手性及非手性催化剂两类。本文作为第二部分将介绍聚合物支载的手性有机催化剂，重点介绍近年来颇受重视的氨基酸及多肽类有机催化剂的研究及其应用进展。

Abstract

This review highlights synthesis

catalytic properties of polymer-supported organic catalysts in the last 25 years

with emphasizing on some recent developments in the direction.The polymer-supported catalysts were first divided into achiral and chiral catalysts

and then divided into different sections according to the chemical reactions catalyzed.Some examples were included in order to make clear comparison based on the catalytic activity and selectivity.Some comparisons were made for achievability of separation and reuse of the supported catalysts.Different kinds of polymer supports were included

e.g.crosslinked polymers

soluble linear polymers and dendrimers.In this second part chiral organic catalysts were detailed.

关键词

聚合物载体有机催化剂树形聚合物多肽

Keywords

Organic catalystPolymer supportChiral catalystAminoacidPeptide

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Institute of Nanobiotechnology,School of Materials,Tianjin University

Department of Polymer Science and Engineering,Peking University

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