Propagation Rate Constants for the Cationic Polymerization of Vinyl Monomer

Ying-xin QIU; Yi-xian WU; Xu XU; Fen RAN; Guan-ying WU

doi:10.14028/j.cnki.1003-3726.2006.04.001

您当前的位置：

首页 >

文章列表页 >

Propagation Rate Constants for the Cationic Polymerization of Vinyl Monomer

更新时间：2022-09-18

- Propagation Rate Constants for the Cationic Polymerization of Vinyl Monomer
- Polymer Bulletin Vol. 19, Issue 4, Pages: 1-10,28(2006)
- 作者机构：
  
  北京化工大学教育部“可控化学反应科学与技术基础”重点实验室，北京　100029
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2006.04.001
  CLC：
- Published：2006-04，
扫描看全文
Ying-xin QIU, Yi-xian WU, Xu XU, Fen RAN, Guan-ying WU. Propagation Rate Constants for the Cationic Polymerization of Vinyl Monomer. [J]. Polymer Bulletin 19(4):1-10,28(2006)
DOI：

Ying-xin QIU, Yi-xian WU, Xu XU, Fen RAN, Guan-ying WU. Propagation Rate Constants for the Cationic Polymerization of Vinyl Monomer. [J]. Polymer Bulletin 19(4):1-10,28(2006) DOI： 10.14028/j.cnki.1003-3726.2006.04.001.

摘要

碳正离子聚合中，聚合速率常数的测定方法通常包括电导法、绝热量热法、胺抑制法、止流光谱法及扩散计时法。在烷基乙烯基醚、苯乙烯及其衍生物和异丁烯等几种常见乙烯基单体的正离子聚合中，本文介绍不同测定方法得到的不同结构碳正离子（包括自由离子和离子对）的链增长速率常数

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34365006&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34365008&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34365007&type=

和

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34365009&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34365011&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34365010&type=

）。

Abstract

The methods including conductivity

adiabatic calorimetry

amine retardation

stopped-flow spectroscopy and diffusion clock method were used to determine the propagation rate constants in cationic polymerization of vinyl monomers.The propagation rate constants (

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34365012&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34365020&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34365014&type=

and

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34365022&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34365031&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34365028&type=

) for carbocations including free ion and ion pairs with different chemical structure in the cationic polymerization of alkyl vinyl ether

isobutylene

styrene and its derivatives are introduced.

关键词

正离子聚合链增长速率常数烷基乙烯基醚苯乙烯异丁烯

Keywords

Cationic polymerizationRate constant for propagationAlkyl vinyl etherStyreneIsobutylene

references

更多指标>

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Synthesis and Structural Characterization of Highly Reactive Polyisobutylene

The Study of Epoxidation of Styrene/1,3-Pentadiene Alternating Copolymer

The Synthesis and Characteristic of Poly(styrene-co-p-^tbutyl-styrene-co-pentadiene) Terpolymer

Preparation of (PSt/OMMT)/PBA Core-shell Composite

Progress in Research of Cationic Polymerization in Aqueous Media

Related Author

No data

Related Institution

Zhejiang CENWAY Materials Co. Ltd

School of New Materials and Chemical Engineering,Beijing Key Laboratory of Special Elastomer Composites, Beijing Institute of Petrochemical Technology

China Petroleum and Chemical Corporation Baling Branch

College of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology

⁰