Progress of Atom Transfer Radical Polymerization (ATRP) Applied to the Synthesis of Multiblock Copolymers

Xin-de TANG; Xing-he FAN; Xiao-fang CHEN; Qi-feng ZHOU

doi:10.14028/j.cnki.1003-3726.2006.06.005

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Progress of Atom Transfer Radical Polymerization (ATRP) Applied to the Synthesis of Multiblock Copolymers

更新时间：2022-09-18

- Progress of Atom Transfer Radical Polymerization (ATRP) Applied to the Synthesis of Multiblock Copolymers
- Polymer Bulletin Vol. 19, Issue 6, Pages: 36-43(2006)
- 作者机构：
  
  a.北京大学化学与分子工程学院，教育部高分子化学与物理重点实验室，北京　100871；
  b.山东交通学院新材料研究所，济南　250023
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2006.06.005
  CLC：
- Published：2006-06，
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Xin-de TANG, Xing-he FAN, Xiao-fang CHEN, Qi-feng ZHOU. Progress of Atom Transfer Radical Polymerization (ATRP) Applied to the Synthesis of Multiblock Copolymers. [J]. Polymer Bulletin 19(6):36-43(2006)
DOI：

Xin-de TANG, Xing-he FAN, Xiao-fang CHEN, Qi-feng ZHOU. Progress of Atom Transfer Radical Polymerization (ATRP) Applied to the Synthesis of Multiblock Copolymers. [J]. Polymer Bulletin 19(6):36-43(2006) DOI： 10.14028/j.cnki.1003-3726.2006.06.005.

摘要

原子转移自由基聚合（ATRP）技术是合成结构规整性聚合物的有效途径。综述了近十年来采用ATRP 技术合成多嵌段共聚物的研究进展。从引发剂、共聚单体和反应条件等方面讨论了 ABA 型、ABC 型和ABCBA 型等类型多嵌段共聚物的合成、性质与潜在应用。对原子转移自由基聚合技术在合成功能性多嵌段共聚物中的应用前景进行了展望。

Abstract

Atom transfer radical polymerization (ATRP) is an effective route to synthesize polymers with well-defined structures.Multiblock copolymers synthesized by ATRP in recent ten years are reviewed.The syntheses

properties and potential applications of multiblock copolymers

such as ABA-type

ABC-type

and ABCBA-type

are discussed in terms of monomers

initiators

and polymerization condition.Application of ATRP technology to the synthesis of functional multiblock polymers is predicted.

关键词

原子转移自由基聚合（ATRP）多嵌段共聚物ABA 型三嵌段共聚物ABC 型三嵌段共聚物ABCBA 型五嵌段共聚物

Keywords

Atom transfer radical polymerization (ATRP)Multiblock copolymerABA-type triblock copolymerABC-type triblock copolymerABCBA-type pentablock copolymer

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Department of Polymer Science, Zhejiang University

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