Progress in Catalyst Study for the Copolymerization of Carbon Dioxide with Epoxides

Zhan-wei BU; Shao-kui CAO

doi:10.14028/j.cnki.1003-3726.2006.07.001

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Progress in Catalyst Study for the Copolymerization of Carbon Dioxide with Epoxides

更新时间：2022-09-18

- Progress in Catalyst Study for the Copolymerization of Carbon Dioxide with Epoxides
- Polymer Bulletin Vol. 19, Issue 7, Pages: 1-9(2006)
- 作者机构：
  
  1.郑州大学材料科学与工程学院，郑州　450052；
  2.河南大学化学化工学院，开封　475001
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2006.07.001
  CLC：
- Published：2006-07，
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Zhan-wei BU, Shao-kui CAO. Progress in Catalyst Study for the Copolymerization of Carbon Dioxide with Epoxides. [J]. Polymer Bulletin 19(7):1-9(2006)
DOI：

Zhan-wei BU, Shao-kui CAO. Progress in Catalyst Study for the Copolymerization of Carbon Dioxide with Epoxides. [J]. Polymer Bulletin 19(7):1-9(2006) DOI： 10.14028/j.cnki.1003-3726.2006.07.001.

摘要

二氧化碳是一种廉价、低毒、资源丰富的可用于有机合成的理想原料。由二氧化碳和环氧化合物共聚合成的脂肪族聚碳酸酯具有生物可降解性。自1969年井上祥平等发现二氧化碳和环氧化合物通过共聚反应合成脂肪族聚碳酸酯以来

利用二氧化碳制备高分子材料一直备受人们注目。该过程的关键是寻找具有高选择性的高效催化剂

三十余年来通过各国科学家的不懈努力已取得了不少成果

本文对其研究的最新进展进行了综述。

Abstract

Carbon dioxide is an ideal synthetic feedstock for its non-flammability

relative non-toxicity

inexpensiveness

and abundance in nature. Also

aliphatic polycarbonates made from CO

and epoxides are biodegradable polymeric materials. Therefore

much attention has been paid to the copolymerization of carbon dioxide with epoxides to produce aliphatic polycarbonate. A significant amount of research has been directed toward the development of catalysts with improved activity and selectivity. The present paper gives an overview on the recent progress in the research of catalysts for such a copolymerization process.

关键词

二氧化碳环氧化合物脂肪族聚碳酸酯共聚合

Keywords

Carbon dioxideEpoxidesCopolymerizationAliphatic polycarbonate

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