Application of Ionic Liquids as Solvents for Radical Polymerization

Da LI; Yu-mei ZHANG; Fang-liang ZHU; Hua-ping WANG; Biao WANG

doi:10.14028/j.cnki.1003-3726.2006.07.006

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Application of Ionic Liquids as Solvents for Radical Polymerization

更新时间：2022-09-18

- Application of Ionic Liquids as Solvents for Radical Polymerization
- Polymer Bulletin Vol. 19, Issue 7, Pages: 38-46(2006)
- 作者机构：
  
  东华大学纤维材料改性国家重点实验室，上海　200051
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2006.07.006
  CLC：
- Published：2006-07，
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Da LI, Yu-mei ZHANG, Fang-liang ZHU, Hua-ping WANG, Biao WANG. Application of Ionic Liquids as Solvents for Radical Polymerization. [J]. Polymer Bulletin 19(7):38-46(2006)
DOI：

Da LI, Yu-mei ZHANG, Fang-liang ZHU, Hua-ping WANG, Biao WANG. Application of Ionic Liquids as Solvents for Radical Polymerization. [J]. Polymer Bulletin 19(7):38-46(2006) DOI： 10.14028/j.cnki.1003-3726.2006.07.006.

摘要

室温离子液体是完全由离子构成的液体

具有几乎没有蒸汽压、溶解度大、溶解范围广、易于回收利用、稳定性好等特点

广泛应用于电化学、有机反应、分离萃取、复合材料等各个领域。近年来已成为各种聚合反应研究的重要课题

且主要集中于自由基聚合反应。作为聚合反应的溶剂

离子液体对聚合反应速率、分子量、聚合物的结构性能都有一定影响。本文根据近几年的文献

归纳分析了离子液体中的常规自由基聚合和活性自由基聚合的反应动力学、反应机理、聚合产物的结构和性能以及离子液体的回收利用等问题。

Abstract

Ionic liquids are organic salts that are liquid at ambient temperature .They have attracted much attention in both academia and industry as nonvolatile

recyclable media for a wide range of chemical processes including extraction

electro-chemistry and organic reaction .As a reaction media

their ion structure

high polar and viscosity properties have leaded to significant improvements in rate and yield in many polymerizations .These also have a influence in molecular weight and polymer structure .In this work

the free radical polymerization and the atom transfer radical polymerization ( ATRP) in which ionic liquids were used as solvents are discussed mainly on the basis of the kinetics

mechanism and the polymer structure as well as the recycle of the ionic liquids according to the results published in recent years .

关键词

离子液体常规自由基聚合活性自由基聚合

Keywords

Ionic liquidRadical polymerizationATRP

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