Progress in the Self-Assembled Morphologies of the Block Copolymers in Bulk

Mei-shun LI; Zai-jun LU; Ying LIU

doi:10.14028/j.cnki.1003-3726.2007.11.002

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Progress in the Self-Assembled Morphologies of the Block Copolymers in Bulk

更新时间：2022-09-18

- Progress in the Self-Assembled Morphologies of the Block Copolymers in Bulk
- Polymer Bulletin Vol. 20, Issue 11, Pages: 6-16(2007)
- 作者机构：
  
  山东大学化学与化工学院高分子所，济南　250100
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2007.11.002
  CLC：
- Published：2007-11，
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Mei-shun LI, Zai-jun LU, Ying LIU. Progress in the Self-Assembled Morphologies of the Block Copolymers in Bulk. [J]. Polymer Bulletin 20(11):6-16(2007)
DOI：

Mei-shun LI, Zai-jun LU, Ying LIU. Progress in the Self-Assembled Morphologies of the Block Copolymers in Bulk. [J]. Polymer Bulletin 20(11):6-16(2007) DOI： 10.14028/j.cnki.1003-3726.2007.11.002.

摘要

综述了两嵌段和三嵌段共聚物在本体中自组装形态的研究进展

主要包括由两嵌段共聚物形成的螺旋状形态;由三嵌段共聚物形成的CsCl 晶格型排列的球状形态、立方体心堆积的同心球状形态、层-球形态、柱-球形态、柱-环形态、同轴柱状形态、六角排列的柱状形态、层-柱形态、层-柱-Ⅱ 形态、有序三连续双金刚石状形态、核-壳双螺旋状形态、层状形态

以及更加复杂的蘑菇状形态、球嵌球形态、编织图案形态等。并对其发展前景进行了展望。

Abstract

A series of morphologies based on the self-assembly of diblock and triblock copolymers in the bulk are summarized in this article.They include (1) the gyriod morphologies formed from diblock copolymers

(2) some morphologies formed from triblock copolymers

such as spherical domains in a CsCl-type structure

cocentric spherical domains in the bcc structure

lamella-sphere

cylinder-sphere

lamella-cylinder

coaxial cylinder

cylindrical domains in a hexagonal lattice structure

lamella-cylinder

lamella-cylinder-Ⅱ

ordered tricontinuous doublediamond

core-shell double gyroid

lamellar

(3) some complex morphologies

such as mushroom

sphere on sphere

knitting-pattern

et al.Furthermore

their advance in the future was also introduced briefly.

关键词

嵌段共聚物自组装形态

Keywords

Block copolymersSelf-assemblyMorphologies

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