Research Progress of Ionic Liquids in Atom Transfer Radical Polymerization

Dong TIAN; Cheng-long XIAO; Zeng-jiang WEI; Ping CHEN; Wei-liang LIU

doi:10.14028/j.cnki.1003-3726.2009.11.005

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Research Progress of Ionic Liquids in Atom Transfer Radical Polymerization

更新时间：2022-09-18

- Research Progress of Ionic Liquids in Atom Transfer Radical Polymerization
- Polymer Bulletin Vol. 22, Issue 11, Pages: 28-31(2009)
- 作者机构：
  
  1.∙山东轻工业学院，材料科学与工程学院，济南　250353
  2.∙中国石化中原油田分公司，濮阳　457001
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2009.11.005
  CLC：
- Published：2009-11，
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Dong TIAN, Cheng-long XIAO, Zeng-jiang WEI, Ping CHEN, Wei-liang LIU. Research Progress of Ionic Liquids in Atom Transfer Radical Polymerization. [J]. Polymer Bulletin 22(11):28-31(2009)
DOI：

Dong TIAN, Cheng-long XIAO, Zeng-jiang WEI, Ping CHEN, Wei-liang LIU. Research Progress of Ionic Liquids in Atom Transfer Radical Polymerization. [J]. Polymer Bulletin 22(11):28-31(2009) DOI： 10.14028/j.cnki.1003-3726.2009.11.005.

摘要

主要阐述了近年来离子液体作为溶剂、单体或者配位剂在原子转移自由基聚合中的应用研究情况。从对聚合反应速率的大小的影响，聚合产物分子量多分散系数的变化，聚合物分子链功能性的设计，以及反应体系中催化体系的分离与循环使用等方面总结了离子液体的参与对原子转移自由基聚合的影响，并简要总结了导致各种变化的原因。最后展望了离子液体应用于原子转移自由基聚合技术的前景，并指出离子液体自身研究的发展是二者结合的关键问题。

Abstract

Recent developments on the application of ionic liquids (ILs) in atom transfer radical polymerization (ATRP) are reviewed. Particular emphasis is placed on the significant effect on the performance of the polymers

including well-controlled process with predictable molecular weight

narrow polydispersity

and well-defined architecture

if the ionic liquids were used as solvent

initiator

ligand or monomer. And a discussion on the opportunities of ionic liquids used in atom transfer radical polymerization for the future concludes this review as well.

关键词

离子液体原子转移自由基聚合溶剂单体配位剂

Keywords

Ionic liquidsAtom transfer radical polymerizationSolventMonomerLigand

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