Progress in Synthesizing Special Structure Polymers via Combination of Reversible Addition-Fragmentation Chain Transfer Polymerization with Click Chemistry

Peng-yu CHEN; Ya CAO

doi:10.14028/j.cnki.1003-3726.2011.01.005

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Progress in Synthesizing Special Structure Polymers via Combination of Reversible Addition-Fragmentation Chain Transfer Polymerization with Click Chemistry

更新时间：2022-09-18

- Progress in Synthesizing Special Structure Polymers via Combination of Reversible Addition-Fragmentation Chain Transfer Polymerization with Click Chemistry
- Polymer Bulletin Vol. 24, Issue 1, Pages: 24-32(2011)
- 作者机构：
  
  高分子材料工程国家重点实验室，四川大学高分子研究所，成都　610065
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2011.01.005
  CLC：
- Published：2011-01，
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Peng-yu CHEN, Ya CAO. Progress in Synthesizing Special Structure Polymers via Combination of Reversible Addition-Fragmentation Chain Transfer Polymerization with Click Chemistry. [J]. Polymer Bulletin 24(1):24-32(2011)
DOI：

Peng-yu CHEN, Ya CAO. Progress in Synthesizing Special Structure Polymers via Combination of Reversible Addition-Fragmentation Chain Transfer Polymerization with Click Chemistry. [J]. Polymer Bulletin 24(1):24-32(2011) DOI： 10.14028/j.cnki.1003-3726.2011.01.005.

摘要

可逆加成－断裂链转移（RAFT）聚合作为一种新型活性自由基聚合方法

由于其具有单体适用面广、聚合条件温和、不受聚合方法的限制等优点

已经成为聚合物分子设计的有效手段之一。点击化学（Click chemistry）是近几年发展起来的一种快速合成的新方法

是指选用易得原料

通过可靠、高效而又具有选择性的化学反应来实现碳杂原子连接

低成本、快速合成大量新化合物的一种强大且实用的合成方法。两者相结合可以制备多种具有特殊结构的聚合物

这一联用技术也越来越引起研究者们的重视。本文综述了近几年来采用 RAFT 和点击化学方法结合制备特殊结构聚合物的研究进展。

Abstract

As a new method of living radical polymerization

reversible addition-fragmentation chain transfer (RAFT) polymerization has a lot of advantages.It can apply to a wide range of monomers in a mild reaction condition.Besides

RAFT polymerization can proceed in bulk

solution

emulsion and suspension polymerization.So RAFT polymerization appears to be one of the most promising techniques of macromolecular design.Click chemistry develops in recent years and it is an approach through which large numbers of new compounds can be quickly synthesized by utilizing reliable

efficient and selective chemical reactions.The Combination of RAFT polymerization with click chemistry can be used to synthesize various special structure polymers

which induces more attention of many researchers.This review deals with recent progress in synthesizing special structure polymer via the combination of RAFT polymerization with click chemistry.

关键词

可逆加成－断裂链转移（RAFT）聚合点击化学（Click chemistry）特殊结构结构可控

Keywords

Reversible addition-fragmentation chain transfer (RAFT) PolymerizationClick chemistrySpecial structureControllable architecture

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