Progress in Iron Catalyst System of Atom Transfer Radical Polymerization

Li-wu ZHANG; Yuan-yuan LI; Yan ZHENG; Bang-hu XIONG

doi:10.14028/j.cnki.1003-3726.2011.03.004

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Progress in Iron Catalyst System of Atom Transfer Radical Polymerization

更新时间：2022-09-18

- Progress in Iron Catalyst System of Atom Transfer Radical Polymerization
- Polymer Bulletin Vol. 24, Issue 3, Pages: 31-35(2011)
- 作者机构：
  
  1.重庆大学化学化工学院，重庆　400044
  2.上海泰格聚合物技术有限公司　上海　201203
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2011.03.004
  CLC：
- Published：2011-03，
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Li-wu ZHANG, Yuan-yuan LI, Yan ZHENG, Bang-hu XIONG. Progress in Iron Catalyst System of Atom Transfer Radical Polymerization. [J]. Polymer Bulletin 24(3):31-35(2011)
DOI：

Li-wu ZHANG, Yuan-yuan LI, Yan ZHENG, Bang-hu XIONG. Progress in Iron Catalyst System of Atom Transfer Radical Polymerization. [J]. Polymer Bulletin 24(3):31-35(2011) DOI： 10.14028/j.cnki.1003-3726.2011.03.004.

摘要

综述了铁系催化剂在原子转移自由基聚合（atom transfer radical polymerization

ATRP）中的应用

其中着重介绍了在常规ATRP 和AGET ATRP 聚合中铁类催化体系的研究进展

并且对其它体系如反向 ATRP（R-ATRP）中的铁类催化剂的研究也作了简要介绍

同时概括了铁类催化剂的配体以及产物中残留的该类催化剂的脱除；众多的研究表明铁系催化剂在ATRP 中不仅有良好的催化作用而且易于脱除

该类催化剂在设计新型高分子材料方面也有很好的应用价值；最后总结了铁系催化剂的无毒、易脱除等优点

并对其前景进行了展望。

Abstract

This paper mainly summarized the application of iron-based catalyst in ATRP

which accentuated the development of iron catalyst system of common ATRP and AGET ATRP.Other systems such as R-ATRP of iron catalysts was also introduced briefly in this paper

including ligands of the catalyst and removal of the catalyst residue from its products.Many studies show that iron-based catalyst not only have good catalysis but also easy to remove in ATRP.It also has high value in the design of new polymer materials.At last

the advantages of iron-based catalyst system such as innocuity

easy removal

etc.were summed up and its prospect was proposed.

关键词

原子转移自由基聚合铁系催化剂配体催化剂的脱除

Keywords

Atom transfer radical polymeriationIron catalyst systemLigandRemoval of catalyst

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