Progress on Synthesis and Applications of Redox Poly (hydroquinone)

Ai-juan ZHANG; Wen-jing ZHANG; Yong-jun ZHANG; Ying GUAN

doi:10.14028/j.cnki.1003-3726.2011.05.001

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Progress on Synthesis and Applications of Redox Poly (hydroquinone)

更新时间：2022-09-18

- Progress on Synthesis and Applications of Redox Poly (hydroquinone)
- Polymer Bulletin Vol. 24, Issue 5, Pages: 17-26(2011)
- 作者机构：
  
  功能高分子材料教育部重点实验室，南开大学化学学院高分子化学研究所，天津　300071
- 作者简介：
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2011.05.001
  CLC：
- Published：2011-05，
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Ai-juan ZHANG, Wen-jing ZHANG, Yong-jun ZHANG, Ying GUAN. Progress on Synthesis and Applications of Redox Poly (hydroquinone). [J]. Polymer Bulletin 24(5):17-26(2011)
DOI：

Ai-juan ZHANG, Wen-jing ZHANG, Yong-jun ZHANG, Ying GUAN. Progress on Synthesis and Applications of Redox Poly (hydroquinone). [J]. Polymer Bulletin 24(5):17-26(2011) DOI： 10.14028/j.cnki.1003-3726.2011.05.001.

摘要

聚对苯二酚是一类主链完全由醌和氢醌组成的氧化还原聚合物

保持了醌、酚的性质

具有良好的氧化还原可逆性

并能进行二电子的氧化还原；同时

与醌和酚相比

热稳定性高。该聚合物氧化还原电位低

电子转移速率快

可应用于生物传感器中的电子媒介体。此外

该聚合物还能快速捕获自由基

可做为抗氧化剂和高分子氧化还原试剂等。本文综述了聚对苯二酚的制备方法

结构特征

可逆氧化还原电化学性质及其在生物传感器、抗氧化剂等领域的应用。

Abstract

Polyhydroquione (PHQ) is a polymer that only contains quinone and hydroquinone groups in its main chain.PHQ retain the characters of quinones

such as redox activity and reversibility consisting of two electron transfer.Compared with monomer

the polymer PHQ has shown improved heat-resistance.As a redox polymer

PHQ has a low redox potential and a fast electron transfer rate

and has been used as an electron mediator for bio-sensors and as an antioxidant or a redox polymer agent since it can capture radicals quickly.The progress on the preparation of PHQ

and on the study of their structure and redox properties and applications is summarized.

关键词

聚对苯二酚氧化聚合可逆氧化还原电子媒介体抗氧化剂

Keywords

Poly(hydroquinone) (PHQ)Oxidative polymerizationReversibile redoxElectron mediatorAntioxidant

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